A statistical mechanical theory of transport processes in charged particle solutions and electrophoretic fluctuation dynamics

Andrzej R. Altenberger; John S. Dahler; Matthew Tirrell

doi:10.1063/1.452730

A statistical mechanical theory of transport processes in charged particle solutions and electrophoretic fluctuation dynamics

Andrzej R. Altenberger, John S. Dahler, Matthew Tirrell

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Formally exact, linearized constitutive relations are derived for the charged particle currents of an electrolyte solution acted upon by an electric field. A new analysis of electrophoretic dynamic light scattering experiments is presented and deficiencies of the traditional, phenomenological irreversible thermodynamics of ionic solutions are pointed out.

Original language	English (US)
Pages (from-to)	4541-4547
Number of pages	7
Journal	The Journal of chemical physics
Volume	86
Issue number	8
DOIs	https://doi.org/10.1063/1.452730
State	Published - 1987
Externally published	Yes

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10.1063/1.452730

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title = "A statistical mechanical theory of transport processes in charged particle solutions and electrophoretic fluctuation dynamics",

abstract = "Formally exact, linearized constitutive relations are derived for the charged particle currents of an electrolyte solution acted upon by an electric field. A new analysis of electrophoretic dynamic light scattering experiments is presented and deficiencies of the traditional, phenomenological irreversible thermodynamics of ionic solutions are pointed out.",

author = "Altenberger, {Andrzej R.} and Dahler, {John S.} and Matthew Tirrell",

year = "1987",

doi = "10.1063/1.452730",

language = "English (US)",

volume = "86",

pages = "4541--4547",

journal = "The Journal of chemical physics",

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T1 - A statistical mechanical theory of transport processes in charged particle solutions and electrophoretic fluctuation dynamics

AU - Altenberger, Andrzej R.

AU - Dahler, John S.

AU - Tirrell, Matthew

PY - 1987

Y1 - 1987

N2 - Formally exact, linearized constitutive relations are derived for the charged particle currents of an electrolyte solution acted upon by an electric field. A new analysis of electrophoretic dynamic light scattering experiments is presented and deficiencies of the traditional, phenomenological irreversible thermodynamics of ionic solutions are pointed out.

AB - Formally exact, linearized constitutive relations are derived for the charged particle currents of an electrolyte solution acted upon by an electric field. A new analysis of electrophoretic dynamic light scattering experiments is presented and deficiencies of the traditional, phenomenological irreversible thermodynamics of ionic solutions are pointed out.

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U2 - 10.1063/1.452730

DO - 10.1063/1.452730

M3 - Article

AN - SCOPUS:36549093672

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VL - 86

SP - 4541

EP - 4547

JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 8

ER -

A statistical mechanical theory of transport processes in charged particle solutions and electrophoretic fluctuation dynamics

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