A stable open-shell redox active ditopic ligand

N. M. Bonanno, A. J. Lough, K. E. Prosser, C. J. Walsby, P. K. Poddutoori, M. T. Lemaire

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of the spectrum and is structurally set up to strongly spin couple coordinated transition metal ions in [2 × 2] grid-type structures.

Original languageEnglish (US)
Pages (from-to)5460-5463
Number of pages4
JournalDalton Transactions
Volume45
Issue number13
DOIs
StatePublished - 2016

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