A simple electrostatic model for trisilylamine: Theoretical examinations of the n→σ* negative hyperconjugation, p(π)→d(π) bonding, and stereoelectronic interaction

Keyphrases

• Bonding Interactions 100%
• Electrostatic Model 100%
• Trimethylamine 100%
• Stereoelectronic Effects 100%
• Negative Hyperconjugation 100%
• Silylamine 66%
• D-orbital 33%
• Wave Function 33%
• Structural Difference 33%
• Repulsion 33%
• Electronegative 33%
• Bonding Character 33%
• X-ray Structure 33%
• Wavefunction Methods 33%
• Long-range Electrostatics 33%
• Block-localized Wavefunction 33%
• Electron Pairing 33%
• Electrostatic Repulsion 33%
• Polar Effect 33%
• N-Si 33%
• High Basicity 33%
• Charge Delocalization 33%
• Silyl Group 33%
• Natural Population Analysis 33%
• Electronegativity 33%
• Electronic Delocalization 33%
• Delocalization Energy 33%
• Planar Geometry 33%
• Valence Shells 33%
• SiH3 33%

Chemistry

• Hyperconjugation 100%
• Trimethylamine 100%
• Silicon 66%
• Wave Function 66%
• Alkalinity 33%
• Polar Effect 33%
• Silyl Group 33%
• Electronegativity 33%
• Delocalization Energy 33%
• Stereoelectronic Effect 33%
• electronics 33%