A simple and convenient method for the synthesis of cyclobutenediones from alkynes using new Fe(CO)5/NaH/MeI reagent system

Mariappan Periasamy; Mallesh Beesu; D. Shyam Raj

doi:10.1016/j.jorganchem.2008.05.033

A simple and convenient method for the synthesis of cyclobutenediones from alkynes using new Fe(CO)₅/NaH/MeI reagent system

Mariappan Periasamy, Mallesh Beesu, D. Shyam Raj

Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Iron carbonyl complexes prepared in situ using the Fe(CO)₅/NaH/MeI reagent combination and alkynes at 25 °C give the corresponding cyclobutenediones in 50-65% yields after CuCl₂ · 2H₂O oxidation.

Original language	English (US)
Pages (from-to)	2843-2846
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	17
DOIs	https://doi.org/10.1016/j.jorganchem.2008.05.033
State	Published - Aug 15 2008

Bibliographical note

Funding Information:
We are thankful to the CSIR (New Delhi) for financial support. Support of the UGC under “University of Potential for Excellence” programme is gratefully acknowledged. The award of the JC Bose Fellowship grant to M.P. gratefully acknowledged.

Keywords

Alkynes
Cyclobutenediones
Iron pentacarbonyl
Sodium hydride

Publisher link

10.1016/j.jorganchem.2008.05.033

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title = "A simple and convenient method for the synthesis of cyclobutenediones from alkynes using new Fe(CO)5/NaH/MeI reagent system",

abstract = "Iron carbonyl complexes prepared in situ using the Fe(CO)5/NaH/MeI reagent combination and alkynes at 25 °C give the corresponding cyclobutenediones in 50-65% yields after CuCl2 · 2H2O oxidation.",

keywords = "Alkynes, Cyclobutenediones, Iron pentacarbonyl, Sodium hydride",

author = "Mariappan Periasamy and Mallesh Beesu and {Shyam Raj}, D.",

note = "Funding Information: We are thankful to the CSIR (New Delhi) for financial support. Support of the UGC under “University of Potential for Excellence” programme is gratefully acknowledged. The award of the JC Bose Fellowship grant to M.P. gratefully acknowledged.",

year = "2008",

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doi = "10.1016/j.jorganchem.2008.05.033",

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journal = "Journal of Organometallic Chemistry",

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T1 - A simple and convenient method for the synthesis of cyclobutenediones from alkynes using new Fe(CO)5/NaH/MeI reagent system

AU - Periasamy, Mariappan

AU - Beesu, Mallesh

AU - Shyam Raj, D.

N1 - Funding Information: We are thankful to the CSIR (New Delhi) for financial support. Support of the UGC under “University of Potential for Excellence” programme is gratefully acknowledged. The award of the JC Bose Fellowship grant to M.P. gratefully acknowledged.

PY - 2008/8/15

Y1 - 2008/8/15

N2 - Iron carbonyl complexes prepared in situ using the Fe(CO)5/NaH/MeI reagent combination and alkynes at 25 °C give the corresponding cyclobutenediones in 50-65% yields after CuCl2 · 2H2O oxidation.

AB - Iron carbonyl complexes prepared in situ using the Fe(CO)5/NaH/MeI reagent combination and alkynes at 25 °C give the corresponding cyclobutenediones in 50-65% yields after CuCl2 · 2H2O oxidation.

KW - Alkynes

KW - Cyclobutenediones

KW - Iron pentacarbonyl

KW - Sodium hydride

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U2 - 10.1016/j.jorganchem.2008.05.033

DO - 10.1016/j.jorganchem.2008.05.033

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EP - 2846

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 17

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