A promising low pressure methanol synthesis route from CO2 hydrogenation over Pd@Zn core-shell catalysts

Fenglin Liao, Xin Ping Wu, Jianwei Zheng, Molly Meng Jung Li, Anna Kroner, Ziyan Zeng, Xinlin Hong, Youzhu Yuan, Xue Qing Gong, Shik Chi Edman Tsang

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

At present, there is no low pressure methanol synthesis from CO2/H2 with high yield despite the presence of an upstream process of aqueous phase reforming (APR) of biomass derivatives on an industrial scale for CO2/H2 production at ca. 2 MPa. This is due to the intrinsic thermodynamics of the system which leads to particularly high CO levels at low pressure through reversed water gas shift reaction (RWGS) for most studied catalysts. Here we report a new Pd@Zn core-shell catalyst that offers a significantly higher kinetic barrier to CO/H2O formation in CO2 hydrogenation to reduce the CO levels but facilitates CH3OH formation at or below 2 MPa with CH3OH selectivity maintained at ca. 70% compared to ca. 10% over industrial Cu catalysts. The corresponding methanol yield at 2 MPa reaches 6.1 gmethanol gactive metal-1 h-1, which is comparable to the best reported value among a wide variety of catalysts under 5 MPa. It is thus believed that this active Pd based catalyst opens up a promising possibility for low pressure and temperature methanol production using a renewable biomass resource for fossil-fuel-starved countries.

Original languageEnglish (US)
Pages (from-to)270-280
Number of pages11
JournalGreen Chemistry
Volume19
Issue number1
DOIs
StatePublished - Jan 1 2017

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Hydrogenation
Methanol
methanol
low pressure
catalyst
shell
Carbon Monoxide
Catalysts
Biomass
Water gas shift
biomass
Reforming reactions
Fossil fuels
fossil fuel
thermodynamics
Metals
Thermodynamics
Derivatives
kinetics
Kinetics

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A promising low pressure methanol synthesis route from CO2 hydrogenation over Pd@Zn core-shell catalysts. / Liao, Fenglin; Wu, Xin Ping; Zheng, Jianwei; Li, Molly Meng Jung; Kroner, Anna; Zeng, Ziyan; Hong, Xinlin; Yuan, Youzhu; Gong, Xue Qing; Tsang, Shik Chi Edman.

In: Green Chemistry, Vol. 19, No. 1, 01.01.2017, p. 270-280.

Research output: Contribution to journalArticle

Liao, F, Wu, XP, Zheng, J, Li, MMJ, Kroner, A, Zeng, Z, Hong, X, Yuan, Y, Gong, XQ & Tsang, SCE 2017, 'A promising low pressure methanol synthesis route from CO2 hydrogenation over Pd@Zn core-shell catalysts', Green Chemistry, vol. 19, no. 1, pp. 270-280. https://doi.org/10.1039/c6gc02366e
Liao, Fenglin ; Wu, Xin Ping ; Zheng, Jianwei ; Li, Molly Meng Jung ; Kroner, Anna ; Zeng, Ziyan ; Hong, Xinlin ; Yuan, Youzhu ; Gong, Xue Qing ; Tsang, Shik Chi Edman. / A promising low pressure methanol synthesis route from CO2 hydrogenation over Pd@Zn core-shell catalysts. In: Green Chemistry. 2017 ; Vol. 19, No. 1. pp. 270-280.
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