A new route to substituted vanadium carbonyl anions. Syntheses of alkyl and aryl isocyanidepentacarbonylvanadate(1-) complexes, V(CO)5CNR-

John E. Ellis; Kristi Lenz Fjare

doi:10.1016/S0022-328X(81)80016-2

A new route to substituted vanadium carbonyl anions. Syntheses of alkyl and aryl isocyanidepentacarbonylvanadate(1-) complexes, V(CO)₅CNR^-

John E. Ellis, Kristi Lenz Fjare

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Aminepentacarbonylvanadate(1-) ion undergoes thermal substitution in the presence of π acceptor ligands to provide high yields (65-85%) of V(CO)₅L^-. By this method [Et₄N][V(CO)₅Ph₂PCH₂PPh₂], containing an unligated PPh₂, [Et₄N] [V(CO)₅ ((p-ClC₆H₄)₃P)] and the first examples of the isocyanide substituted anions [V(CO)₅CNR]^-, where R=Me, t-Bu, cyclohexyl and phenyl have been prepared. This new method provides only monosubstituted carbonylvanadate(1-) ions and is especially important when such products are unavailable or not readily preparable by photochemical means.

Original language	English (US)
Pages (from-to)	C33-C35
Journal	Journal of Organometallic Chemistry
Volume	214
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(81)80016-2
State	Published - Jul 14 1981

Bibliographical note

Funding Information:
We acknowledge support of this work by the National Science Foundation (CHE79-12159). 'We also thank Professor M.Y. Darensbourg for a discussion and preprint concerning the infrared spectra of V(CO)s L species.

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10.1016/S0022-328X(81)80016-2

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@article{601d140b8a05484888d19657219a56a5,

title = "A new route to substituted vanadium carbonyl anions. Syntheses of alkyl and aryl isocyanidepentacarbonylvanadate(1-) complexes, V(CO)5CNR-",

abstract = "Aminepentacarbonylvanadate(1-) ion undergoes thermal substitution in the presence of π acceptor ligands to provide high yields (65-85%) of V(CO)5L-. By this method [Et4N][V(CO)5Ph2PCH2PPh2], containing an unligated PPh2, [Et4N] [V(CO)5 ((p-ClC6H4)3P)] and the first examples of the isocyanide substituted anions [V(CO)5CNR]-, where R=Me, t-Bu, cyclohexyl and phenyl have been prepared. This new method provides only monosubstituted carbonylvanadate(1-) ions and is especially important when such products are unavailable or not readily preparable by photochemical means.",

author = "Ellis, {John E.} and Fjare, {Kristi Lenz}",

note = "Funding Information: We acknowledge support of this work by the National Science Foundation (CHE79-12159). 'We also thank Professor M.Y. Darensbourg for a discussion and preprint concerning the infrared spectra of V(CO)s L species.",

year = "1981",

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doi = "10.1016/S0022-328X(81)80016-2",

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volume = "214",

pages = "C33--C35",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - A new route to substituted vanadium carbonyl anions. Syntheses of alkyl and aryl isocyanidepentacarbonylvanadate(1-) complexes, V(CO)5CNR-

AU - Ellis, John E.

AU - Fjare, Kristi Lenz

N1 - Funding Information: We acknowledge support of this work by the National Science Foundation (CHE79-12159). 'We also thank Professor M.Y. Darensbourg for a discussion and preprint concerning the infrared spectra of V(CO)s L species.

PY - 1981/7/14

Y1 - 1981/7/14

N2 - Aminepentacarbonylvanadate(1-) ion undergoes thermal substitution in the presence of π acceptor ligands to provide high yields (65-85%) of V(CO)5L-. By this method [Et4N][V(CO)5Ph2PCH2PPh2], containing an unligated PPh2, [Et4N] [V(CO)5 ((p-ClC6H4)3P)] and the first examples of the isocyanide substituted anions [V(CO)5CNR]-, where R=Me, t-Bu, cyclohexyl and phenyl have been prepared. This new method provides only monosubstituted carbonylvanadate(1-) ions and is especially important when such products are unavailable or not readily preparable by photochemical means.

AB - Aminepentacarbonylvanadate(1-) ion undergoes thermal substitution in the presence of π acceptor ligands to provide high yields (65-85%) of V(CO)5L-. By this method [Et4N][V(CO)5Ph2PCH2PPh2], containing an unligated PPh2, [Et4N] [V(CO)5 ((p-ClC6H4)3P)] and the first examples of the isocyanide substituted anions [V(CO)5CNR]-, where R=Me, t-Bu, cyclohexyl and phenyl have been prepared. This new method provides only monosubstituted carbonylvanadate(1-) ions and is especially important when such products are unavailable or not readily preparable by photochemical means.

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SP - C33-C35

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JF - Journal of Organometallic Chemistry

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