A new one-step method for oxaadamantane synthesis

Pavel A. Krasutsky, Igor V. Kolomitsin, Robert M. Carlson, Maitland Jones

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Oxidation of 2-methyl-2-hydroxyadamantane by trifluoroperacetic acid in trifluoroacetic acid gives oxaadamantane and exo-2-oxaadamantane-4-ol in a good yield. Other 2-hydroxyadamantane derivatives do not undergo this transformation. An oxidative cleavage and subsequent cyclization mechanism is proposed.

Original languageEnglish (US)
Pages (from-to)5673-5674
Number of pages2
JournalTetrahedron Letters
Issue number32
StatePublished - Aug 5 1996

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    Krasutsky, P. A., Kolomitsin, I. V., Carlson, R. M., & Jones, M. (1996). A new one-step method for oxaadamantane synthesis. Tetrahedron Letters, 37(32), 5673-5674. https://doi.org/10.1016/0040-4039(96)01202-6