A New Derivation of Post Gel Properties of Network Polymers

Douglas R. Miller; Christopher W. Macosko

doi:10.1021/ma60050a004

A New Derivation of Post Gel Properties of Network Polymers

Douglas R. Miller
, Christopher W. Macosko

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

560 Scopus citations

Abstract

A simple recursive method is presented which can be used to derive the probability of a finite or dangling chain in a polymer network. Finite chain probabilities are derived for a variety of networks as a function of type and extent of reaction. From these probabilities useful properties such as sol fraction, cross-link density, and the number of elastically effective network chains can be readily developed.

Original language	English (US)
Pages (from-to)	206-211
Number of pages	6
Journal	Macromolecules
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/ma60050a004
State	Published - Mar 1 1976

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title = "A New Derivation of Post Gel Properties of Network Polymers",

abstract = "A simple recursive method is presented which can be used to derive the probability of a finite or dangling chain in a polymer network. Finite chain probabilities are derived for a variety of networks as a function of type and extent of reaction. From these probabilities useful properties such as sol fraction, cross-link density, and the number of elastically effective network chains can be readily developed.",

author = "Miller, \{Douglas R.\} and Macosko, \{Christopher W.\}",

year = "1976",

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T1 - A New Derivation of Post Gel Properties of Network Polymers

AU - Miller, Douglas R.

AU - Macosko, Christopher W.

PY - 1976/3/1

Y1 - 1976/3/1

N2 - A simple recursive method is presented which can be used to derive the probability of a finite or dangling chain in a polymer network. Finite chain probabilities are derived for a variety of networks as a function of type and extent of reaction. From these probabilities useful properties such as sol fraction, cross-link density, and the number of elastically effective network chains can be readily developed.

AB - A simple recursive method is presented which can be used to derive the probability of a finite or dangling chain in a polymer network. Finite chain probabilities are derived for a variety of networks as a function of type and extent of reaction. From these probabilities useful properties such as sol fraction, cross-link density, and the number of elastically effective network chains can be readily developed.

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UR - https://www.scopus.com/pages/publications/0001249653#tab=citedBy

U2 - 10.1021/ma60050a004

DO - 10.1021/ma60050a004

M3 - Article

AN - SCOPUS:0001249653

SN - 0024-9297

VL - 9

SP - 206

EP - 211

JO - Macromolecules

JF - Macromolecules

IS - 2

ER -

A New Derivation of Post Gel Properties of Network Polymers

Abstract

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