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A mechanistic study of the reaction between a diiron(II) complex [Fe
II
2
(μ-OH)
2
(6-Me
3
-TPA)
2
]
2+
and O
2
to form a diiron(III) peroxo complex
S. V. Kryatov
, E. V. Rybak-Akimova
, V. L. MacMurdo
, Jr Que
Chemistry (Twin Cities)
Research output
:
Contribution to journal
›
Article
›
peer-review
51
Scopus citations
Overview
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Dive into the research topics of 'A mechanistic study of the reaction between a diiron(II) complex [Fe
II
2
(μ-OH)
2
(6-Me
3
-TPA)
2
]
2+
and O
2
to form a diiron(III) peroxo complex'. Together they form a unique fingerprint.
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Keyphrases
2-form
25%
Acetone
25%
Acetonitrile
25%
Activation Parameters
25%
Amines
25%
Desaturase
25%
Dichloromethane
25%
Diiron
100%
Dioxygen
25%
First-order
25%
K(I)
25%
Kinetic Study
25%
Mechanistic Analysis
25%
Mechanistic Studies
100%
Methane
25%
Methyl
25%
Monoxygenase
25%
Oxygenation
50%
Peroxo Complexes
100%
Polar Solvents
25%
Rate-limiting Step
25%
Reaction Rate
25%
Steady State
25%
Stearoyl
25%
Superoxo
25%
Tris
25%
Chemistry
Acetonitrile
100%
Dichloromethane
100%
Dioxygen
100%
Kinetic Study
100%
Mechanistic Study
100%
Methane
100%
Polar Solvent
100%
Tris
100%