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A long-lived FeIII-(hydroperoxo) intermediate in the active H200C variant of homoprotocatechuate 2,3-dioxygenase: Characterization by mössbauer, electron paramagnetic resonance, and density functional theory methods

  • Katlyn K. Meier
  • , Melanie S. Rogers
  • , Elena G. Kovaleva
  • , Michael M. Mbughuni
  • , Emile L. Bominaar
  • , John D. Lipscomb
  • , Eckard Münck

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Chemistry