A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores

Dawei Feng; Kecheng Wang; Jie Su; Tian Fu Liu; Jihye Park; Zhangwen Wei; Mathieu Bosch; Andrey Yakovenko; Xiaodong Zou; Hong Cai Zhou

doi:10.1002/anie.201409334

A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores

Dawei Feng
, Kecheng Wang
, Jie Su
, Tian Fu Liu
, Jihye Park
, Zhangwen Wei
, Mathieu Bosch
, Andrey Yakovenko
, Xiaodong Zou
, Hong Cai Zhou

Research output: Contribution to journal › Article › peer-review

300 Scopus citations

Abstract

Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm³ g^-1among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN- 777 and different guests can be varied to realize efficient immobilization.

Original language	English (US)
Pages (from-to)	149-154
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	1
DOIs	https://doi.org/10.1002/anie.201409334
State	Published - Jan 2 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords

Carboxylate ligands
Host-guest systems
Mesoporous materials
Metal-organic frameworks
Zirconium

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10.1002/anie.201409334

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title = "A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores",

abstract = "Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm3 g-1among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN- 777 and different guests can be varied to realize efficient immobilization.",

keywords = "Carboxylate ligands, Host-guest systems, Mesoporous materials, Metal-organic frameworks, Zirconium",

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note = "Publisher Copyright: {\textcopyright} 2015 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

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TY - JOUR

T1 - A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores

AU - Feng, Dawei

AU - Wang, Kecheng

AU - Su, Jie

AU - Liu, Tian Fu

AU - Park, Jihye

AU - Wei, Zhangwen

AU - Bosch, Mathieu

AU - Yakovenko, Andrey

AU - Zou, Xiaodong

AU - Zhou, Hong Cai

PY - 2015/1/2

Y1 - 2015/1/2

N2 - Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm3 g-1among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN- 777 and different guests can be varied to realize efficient immobilization.

AB - Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm3 g-1among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN- 777 and different guests can be varied to realize efficient immobilization.

KW - Carboxylate ligands

KW - Host-guest systems

KW - Mesoporous materials

KW - Metal-organic frameworks

KW - Zirconium

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DO - 10.1002/anie.201409334

M3 - Article

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SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 1

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A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores

Abstract

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