A Distinct Mode of Strain-Driven Cyclic Allene Reactivity: Group Migration to the Central Allene Carbon Atom

Keyphrases

• Carbon Atom 100%
• Strain-driven 100%
• Allenes 100%
• Group Migration 100%
• Cyclic Allenes 100%
• Diels-Alder Reaction 33%
• Potential Energy 33%
• Alkynes 33%
• Electrophilic 33%
• DFT Study 33%
• Reactive Species 33%
• Hydrogen Atom 33%
• Cycloaddition 33%
• Unimolecular 33%
• Silyl 33%
• Silyl Enol Ethers 33%
• O Atom 33%
• Acyl Groups 33%
• Enynes 33%
• Tautomerization 33%
• Molecular Complexity 33%
• Atom Migration 33%
• Silyl Group 33%
• Enol Esters 33%
• Benzenoid 33%
• Siloxy 33%
• Acyloxy 33%
• Phenolic Product 33%
• 1,3-enynes 33%
• Cyclohexa-2,4-dienones 33%
• Ester Migration 33%

Chemistry

• Carbon Atom 100%
• Allene 100%
• Enyne 33%
• Density Functional Theory 16%
• Diels-Alder Reaction 16%
• Silyl Enol Ether 16%
• Acyl Group 16%
• Silyl 16%
• Enol 16%
• Tautomerization 16%
• Silyl Group 16%
• Potential Energy 16%
• Hydrogen Atom 16%
• Alkyne 16%
• Cycloaddition 16%