A coordination network containing non-coordinating polyoxometalate clusters as counterions

Bret J.S. Johnson; Sarah A. Geers; William W. Brennessel; Victor G. Young; Andreas Stein

doi:10.1039/b309453g

A coordination network containing non-coordinating polyoxometalate clusters as counterions

Bret J.S. Johnson, Sarah A. Geers, William W. Brennessel, Victor G. Young, Andreas Stein

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

This report describes the synthesis and characterization of a 2D coordination network that directly incorporates an aniline-functionalized polyoxometalate (POM) cluster. By reacting a cobalt(ii) salt of the POM cluster [Mo₁₂O₄₆(AsC₆H₄NH₂)₄]⁴⁻ with a bifunctional ligand, 4,4′-bipyridylethylene, a 2D coordination network was synthesized through a self-assembly process. The POM behaves as a non-coordinating anion and does not interfere with the coordination network other than occupying space. Thermal analysis reveals that the structure is stable to 350 °C.

Original language	English (US)
Pages (from-to)	4678-4681
Number of pages	4
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	3
Issue number	24
DOIs	https://doi.org/10.1039/b309453g
State	Published - Dec 2 2003

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abstract = "This report describes the synthesis and characterization of a 2D coordination network that directly incorporates an aniline-functionalized polyoxometalate (POM) cluster. By reacting a cobalt(ii) salt of the POM cluster [Mo12O46(AsC6H4NH2)4]4− with a bifunctional ligand, 4,4′-bipyridylethylene, a 2D coordination network was synthesized through a self-assembly process. The POM behaves as a non-coordinating anion and does not interfere with the coordination network other than occupying space. Thermal analysis reveals that the structure is stable to 350 °C.",

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AU - Johnson, Bret J.S.

AU - Geers, Sarah A.

AU - Brennessel, William W.

AU - Young, Victor G.

AU - Stein, Andreas

PY - 2003/12/2

Y1 - 2003/12/2

N2 - This report describes the synthesis and characterization of a 2D coordination network that directly incorporates an aniline-functionalized polyoxometalate (POM) cluster. By reacting a cobalt(ii) salt of the POM cluster [Mo12O46(AsC6H4NH2)4]4− with a bifunctional ligand, 4,4′-bipyridylethylene, a 2D coordination network was synthesized through a self-assembly process. The POM behaves as a non-coordinating anion and does not interfere with the coordination network other than occupying space. Thermal analysis reveals that the structure is stable to 350 °C.

AB - This report describes the synthesis and characterization of a 2D coordination network that directly incorporates an aniline-functionalized polyoxometalate (POM) cluster. By reacting a cobalt(ii) salt of the POM cluster [Mo12O46(AsC6H4NH2)4]4− with a bifunctional ligand, 4,4′-bipyridylethylene, a 2D coordination network was synthesized through a self-assembly process. The POM behaves as a non-coordinating anion and does not interfere with the coordination network other than occupying space. Thermal analysis reveals that the structure is stable to 350 °C.

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JF - Journal of the Chemical Society. Dalton Transactions

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ER -

A coordination network containing non-coordinating polyoxometalate clusters as counterions

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