A concise total synthesis of (±)- and (-)-okilactomycin D

Dawen Niu; Thomas R. Hoye

doi:10.1021/ol203355g

A concise total synthesis of (±)- and (-)-okilactomycin D

Dawen Niu, Thomas R. Hoye

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels - Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.

Original language	English (US)
Pages (from-to)	828-831
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	3
DOIs	https://doi.org/10.1021/ol203355g
State	Published - Feb 3 2012

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abstract = "The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels - Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.",

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AB - The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels - Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.

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A concise total synthesis of (±)- and (-)-okilactomycin D

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