A comparison of isomers: Trans- And cis-dicyanobis(para- ethylisocyanobenzene)platinum

Anthony G. Dylla; Daron E. Janzen; Marie K. Pomije; Kent R. Mann

doi:10.1021/om7008167

A comparison of isomers: Trans- And cis-dicyanobis(para- ethylisocyanobenzene)platinum

Anthony G. Dylla, Daron E. Janzen, Marie K. Pomije, Kent R. Mann

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

We report the synthesis and characterization of trans-Pt(p-CN-C ₆H ₄-C ₂H ₅) ₂(CN) ₂ and compare the properties to the previously reported cis isomer, cis-Pt(p-CN-C ₆H ₄-C ₂H ₅) ₂(CN) ₂. These geometric isomers exhibit textbook differences in spectroscopic and vapochromic properties, especially in the solid-state.

Original language	English (US)
Pages (from-to)	6243-6247
Number of pages	5
Journal	Organometallics
Volume	26
Issue number	25
DOIs	https://doi.org/10.1021/om7008167
State	Published - Dec 3 2007

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title = "A comparison of isomers: Trans- And cis-dicyanobis(para- ethylisocyanobenzene)platinum",

abstract = "We report the synthesis and characterization of trans-Pt(p-CN-C 6H 4-C 2H 5) 2(CN) 2 and compare the properties to the previously reported cis isomer, cis-Pt(p-CN-C 6H 4-C 2H 5) 2(CN) 2. These geometric isomers exhibit textbook differences in spectroscopic and vapochromic properties, especially in the solid-state.",

author = "Dylla, {Anthony G.} and Janzen, {Daron E.} and Pomije, {Marie K.} and Mann, {Kent R.}",

year = "2007",

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T2 - Trans- And cis-dicyanobis(para- ethylisocyanobenzene)platinum

AU - Dylla, Anthony G.

AU - Janzen, Daron E.

AU - Pomije, Marie K.

AU - Mann, Kent R.

PY - 2007/12/3

Y1 - 2007/12/3

N2 - We report the synthesis and characterization of trans-Pt(p-CN-C 6H 4-C 2H 5) 2(CN) 2 and compare the properties to the previously reported cis isomer, cis-Pt(p-CN-C 6H 4-C 2H 5) 2(CN) 2. These geometric isomers exhibit textbook differences in spectroscopic and vapochromic properties, especially in the solid-state.

AB - We report the synthesis and characterization of trans-Pt(p-CN-C 6H 4-C 2H 5) 2(CN) 2 and compare the properties to the previously reported cis isomer, cis-Pt(p-CN-C 6H 4-C 2H 5) 2(CN) 2. These geometric isomers exhibit textbook differences in spectroscopic and vapochromic properties, especially in the solid-state.

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JF - Organometallics

IS - 25

ER -

A comparison of isomers: Trans- And cis-dicyanobis(para- ethylisocyanobenzene)platinum

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