A bicontinuous double gyroid hybrid solar cell

Edward J W Crossland; Marleen Kamperman; Mihaela Nedelcu; Caterina Ducati; Ulrich Wiesner; Detlef M. Smilgies; Gilman E S Toombes; Marc A. Hillmyer; Sabine Ludwigs; Ullrich Steiner; Henry J. Snaith

doi:10.1021/nl803174p

A bicontinuous double gyroid hybrid solar cell

Edward J W Crossland
, Marleen Kamperman
, Mihaela Nedelcu
, Caterina Ducati
, Ulrich Wiesner
, Detlef M. Smilgies
, Gilman E S Toombes
, Marc A. Hillmyer
, Sabine Ludwigs
, Ullrich Steiner
, Henry J. Snaith

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

455 Scopus citations

Abstract

We report the first successful application of an ordered bicontinuous gyroid semiconducting network in a hybrid bulk heterojunction solar cell. The freestanding gyroid network is fabricated by electrochemical deposition into the 10 nm wide voided channels of a self-assembled, selectively degradable block copolymer film. The highly ordered pore structure is ideal for uniform infiltration of an organic hole transporting material, and solid-state dye-sensitized solar cells only 400 nm thick exhibit up to 1.7% power conversion efficiency. This patterning technique can be readily extended to other promising heterojunction systems and is a major step toward realizing the full potential of self-assembly in the next generation of device technologies.

Original language	English (US)
Pages (from-to)	2807-2812
Number of pages	6
Journal	Nano letters
Volume	9
Issue number	8
DOIs	https://doi.org/10.1021/nl803174p
State	Published - Aug 12 2009

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title = "A bicontinuous double gyroid hybrid solar cell",

abstract = "We report the first successful application of an ordered bicontinuous gyroid semiconducting network in a hybrid bulk heterojunction solar cell. The freestanding gyroid network is fabricated by electrochemical deposition into the 10 nm wide voided channels of a self-assembled, selectively degradable block copolymer film. The highly ordered pore structure is ideal for uniform infiltration of an organic hole transporting material, and solid-state dye-sensitized solar cells only 400 nm thick exhibit up to 1.7\% power conversion efficiency. This patterning technique can be readily extended to other promising heterojunction systems and is a major step toward realizing the full potential of self-assembly in the next generation of device technologies.",

author = "Crossland, \{Edward J W\} and Marleen Kamperman and Mihaela Nedelcu and Caterina Ducati and Ulrich Wiesner and Smilgies, \{Detlef M.\} and Toombes, \{Gilman E S\} and Hillmyer, \{Marc A.\} and Sabine Ludwigs and Ullrich Steiner and Snaith, \{Henry J.\}",

year = "2009",

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doi = "10.1021/nl803174p",

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AU - Crossland, Edward J W

AU - Kamperman, Marleen

AU - Nedelcu, Mihaela

AU - Ducati, Caterina

AU - Wiesner, Ulrich

AU - Smilgies, Detlef M.

AU - Toombes, Gilman E S

AU - Hillmyer, Marc A.

AU - Ludwigs, Sabine

AU - Steiner, Ullrich

AU - Snaith, Henry J.

PY - 2009/8/12

Y1 - 2009/8/12

N2 - We report the first successful application of an ordered bicontinuous gyroid semiconducting network in a hybrid bulk heterojunction solar cell. The freestanding gyroid network is fabricated by electrochemical deposition into the 10 nm wide voided channels of a self-assembled, selectively degradable block copolymer film. The highly ordered pore structure is ideal for uniform infiltration of an organic hole transporting material, and solid-state dye-sensitized solar cells only 400 nm thick exhibit up to 1.7% power conversion efficiency. This patterning technique can be readily extended to other promising heterojunction systems and is a major step toward realizing the full potential of self-assembly in the next generation of device technologies.

AB - We report the first successful application of an ordered bicontinuous gyroid semiconducting network in a hybrid bulk heterojunction solar cell. The freestanding gyroid network is fabricated by electrochemical deposition into the 10 nm wide voided channels of a self-assembled, selectively degradable block copolymer film. The highly ordered pore structure is ideal for uniform infiltration of an organic hole transporting material, and solid-state dye-sensitized solar cells only 400 nm thick exhibit up to 1.7% power conversion efficiency. This patterning technique can be readily extended to other promising heterojunction systems and is a major step toward realizing the full potential of self-assembly in the next generation of device technologies.

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EP - 2812

JO - Nano letters

JF - Nano letters

IS - 8

ER -

A bicontinuous double gyroid hybrid solar cell

Abstract

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