A 1,2,4-Triazole-based Polynuclear Mixed-valence MnIIMnIII Complex: Synthesis, Characterization, and Magnetic Property

Hui Liu; Xin Sui; Jingyan Zhang

doi:10.1002/zaac.201500160

A 1,2,4-Triazole-based Polynuclear Mixed-valence Mn^IIMn^III Complex: Synthesis, Characterization, and Magnetic Property

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Abstract

A mixed-valence Mn complex {[Mn^IIMn^III(HL)₂(4,4′-bpy)(H₂O)₂]·(ClO₄)(DMF)₃(4,4′-bpy)_0.5}_n (1) [H₂L = 3-(2-phenol)-5-(pyridin-2-yl)-1,2,4-triazole] was synthesized and characterized by X-ray single-crystal structure analysis and magnetic susceptibility. Single-crystal X-ray analysis revealed that complex 1 has a dinuclear core, in which adjacent central Mn^III atoms are linked by 4,4′-bipyridine to form an infinite one-dimensional (1D) molecular configuration. According to the Mn surrounding bond lengths and bond valence sum (BVS) calculations, we demonstrated that the Mn atom coordinated to the pyridine N atoms is in the +2 oxidation state, while another Mn atom coordinated to the phenolic oxygen atoms is in the +3 oxidation state. Magnetic susceptibility data of the complex 1 indicate that the ferromagnetic interaction dominates in this complex.

Original language	English (US)
Pages (from-to)	2511-2514
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	641
Issue number	14
DOIs	https://doi.org/10.1002/zaac.201500160
State	Published - Nov 1 2015
Externally published	Yes

Bibliographical note

Funding Information:
This work was supported by National Natural Science Foundation China (No. 21001044, 31070742) and the State Key Laboratory of Bioreactor Engineering (No. 2060204).

Keywords

1,2,4-Triazole
Crystal structure
Magnetic property
Manganese
Mixed-valence MnMn complex

Publisher link

10.1002/zaac.201500160

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@article{540ad48821ac49b1b44068a60a70a452,

title = "A 1,2,4-Triazole-based Polynuclear Mixed-valence MnIIMnIII Complex: Synthesis, Characterization, and Magnetic Property",

abstract = "A mixed-valence Mn complex {[MnIIMnIII(HL)2(4,4′-bpy)(H2O)2]·(ClO4)(DMF)3(4,4′-bpy)0.5}n (1) [H2L = 3-(2-phenol)-5-(pyridin-2-yl)-1,2,4-triazole] was synthesized and characterized by X-ray single-crystal structure analysis and magnetic susceptibility. Single-crystal X-ray analysis revealed that complex 1 has a dinuclear core, in which adjacent central MnIII atoms are linked by 4,4′-bipyridine to form an infinite one-dimensional (1D) molecular configuration. According to the Mn surrounding bond lengths and bond valence sum (BVS) calculations, we demonstrated that the Mn atom coordinated to the pyridine N atoms is in the +2 oxidation state, while another Mn atom coordinated to the phenolic oxygen atoms is in the +3 oxidation state. Magnetic susceptibility data of the complex 1 indicate that the ferromagnetic interaction dominates in this complex.",

keywords = "1,2,4-Triazole, Crystal structure, Magnetic property, Manganese, Mixed-valence MnMn complex",

author = "Hui Liu and Xin Sui and Jingyan Zhang",

note = "Funding Information: This work was supported by National Natural Science Foundation China (No. 21001044, 31070742) and the State Key Laboratory of Bioreactor Engineering (No. 2060204).",

year = "2015",

month = nov,

day = "1",

doi = "10.1002/zaac.201500160",

language = "English (US)",

volume = "641",

pages = "2511--2514",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "14",

}

TY - JOUR

T1 - A 1,2,4-Triazole-based Polynuclear Mixed-valence MnIIMnIII Complex

T2 - Synthesis, Characterization, and Magnetic Property

AU - Liu, Hui

AU - Sui, Xin

AU - Zhang, Jingyan

N1 - Funding Information: This work was supported by National Natural Science Foundation China (No. 21001044, 31070742) and the State Key Laboratory of Bioreactor Engineering (No. 2060204).

PY - 2015/11/1

Y1 - 2015/11/1

N2 - A mixed-valence Mn complex {[MnIIMnIII(HL)2(4,4′-bpy)(H2O)2]·(ClO4)(DMF)3(4,4′-bpy)0.5}n (1) [H2L = 3-(2-phenol)-5-(pyridin-2-yl)-1,2,4-triazole] was synthesized and characterized by X-ray single-crystal structure analysis and magnetic susceptibility. Single-crystal X-ray analysis revealed that complex 1 has a dinuclear core, in which adjacent central MnIII atoms are linked by 4,4′-bipyridine to form an infinite one-dimensional (1D) molecular configuration. According to the Mn surrounding bond lengths and bond valence sum (BVS) calculations, we demonstrated that the Mn atom coordinated to the pyridine N atoms is in the +2 oxidation state, while another Mn atom coordinated to the phenolic oxygen atoms is in the +3 oxidation state. Magnetic susceptibility data of the complex 1 indicate that the ferromagnetic interaction dominates in this complex.

AB - A mixed-valence Mn complex {[MnIIMnIII(HL)2(4,4′-bpy)(H2O)2]·(ClO4)(DMF)3(4,4′-bpy)0.5}n (1) [H2L = 3-(2-phenol)-5-(pyridin-2-yl)-1,2,4-triazole] was synthesized and characterized by X-ray single-crystal structure analysis and magnetic susceptibility. Single-crystal X-ray analysis revealed that complex 1 has a dinuclear core, in which adjacent central MnIII atoms are linked by 4,4′-bipyridine to form an infinite one-dimensional (1D) molecular configuration. According to the Mn surrounding bond lengths and bond valence sum (BVS) calculations, we demonstrated that the Mn atom coordinated to the pyridine N atoms is in the +2 oxidation state, while another Mn atom coordinated to the phenolic oxygen atoms is in the +3 oxidation state. Magnetic susceptibility data of the complex 1 indicate that the ferromagnetic interaction dominates in this complex.

KW - 1,2,4-Triazole

KW - Crystal structure

KW - Magnetic property

KW - Manganese

KW - Mixed-valence MnMn complex

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