Find Research Outputs

Search concepts
Selected Filters
2015
181 Citations (Scopus)

Bioinspired Nonheme Iron Catalysts for C-H and C=C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

Oloo, W. N. & Que, L., Aug 17 2015, In : Accounts of Chemical Research. 48, 9, p. 2612-2621 10 p.

Research output: Contribution to journalArticle

Oxidants
Iron
Metals
Oxidation
Catalysts
12 Citations (Scopus)

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

De Sousa, D. P., Bigelow, J. O., Sundberg, J., Que, L. & McKenzie, C. J., Feb 18 2015, In : Chemical Communications. 51, 14, p. 2802-2805 4 p.

Research output: Contribution to journalArticle

Metals
Crystals
8 Citations (Scopus)

Characterization of a heterobimetallic nonheme Fe(III)-O-Cr(III) species formed by O2 activation

Zhou, A., Kleespies, S. T., Van Heuvelen, K. M. & Que, L., Aug 5 2015, In : Chemical Communications. 51, 76, p. 14326-14329 4 p.

Research output: Contribution to journalArticle

Chemical activation
29 Citations (Scopus)

C-H bond cleavage by bioinspired nonheme oxoiron(IV) complexes, including hydroxylation of n-butane

Kleespies, S. T., Oloo, W. N., Mukherjee, A. & Que, L., Jun 1 2015, In : Inorganic Chemistry. 54, 11, p. 5053-5064 12 p.

Research output: Contribution to journalReview article

Hydroxylation
butanes
cleavage
Iron
reactivity
16 Citations (Scopus)
Oxygenases
Alkanes
Aldehydes
Paraffins
Atoms
4 Citations (Scopus)

Erratum: Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation (Nature Communications (2015) 6 (5865) DOI: 10.1038/ncomms6865)

Codolà, Z., Gómez, L., Kleespies, S. T., Que, L., Costas, M. & Lloret-Fillol, J., Feb 2015, In : Nature communications. 6, 6405.

Research output: Contribution to journalComment/debate

Cerium
cerium
Iron
communication
Oxygen
65 Citations (Scopus)

Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation

Codolà, Z., Gómez, L., Kleespies, S. T., Que, L., Costas, M. & Lloret-Fillol, J., Jan 22 2015, In : Nature communications. 6, 5865.

Research output: Contribution to journalArticle

Cerium
cerium
Iron
Oxygen
iron
17 Citations (Scopus)

Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(iv) complexes

Ye, S., Xue, G., Krivokapic, I., Petrenko, T., Bill, E., Que, L. & Neese, F., May 1 2015, In : Chemical Science. 6, 5, p. 2909-2921 13 p.

Research output: Contribution to journalArticle

Iron
Excitation energy
Electron transitions
Electronic structure
Circular dichroism spectroscopy
62 Citations (Scopus)

Modeling TauD- J: A high-spin nonheme oxoiron(IV) complex with high reactivity toward C-H bonds

Biswas, A. N., Puri, M., Meier, K. K., Oloo, W. N., Rohde, G. T., Bominaar, E. L., Münck, E. & Que, L., Feb 25 2015, In : Journal of the American Chemical Society. 137, 7, p. 2428-2431 4 p.

Research output: Contribution to journalArticle

Oxidation
Oxygenases
Taurine
Cyclohexane
Amines
12 Citations (Scopus)

Oxoiron(IV) Complex of the Ethylene-Bridged Dialkylcyclam Ligand Me2EBC

England, J., Prakash, J., Cranswick, M. A., Mandal, D., Guo, Y., Münck, E., Shaik, S. & Que, L., Aug 17 2015, In : Inorganic Chemistry. 54, 16, p. 7828-7839 12 p.

Research output: Contribution to journalArticle

ethylene
Ligands
Atoms
ligands
Hydrogen
17 Citations (Scopus)

Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate Framework

Schreiber, R. E., Cohen, H., Leitus, G., Wolf, S. G., Zhou, A., Que, L. & Neumann, R., Jul 15 2015, In : Journal of the American Chemical Society. 137, 27, p. 8738-8748 11 p.

Research output: Contribution to journalArticle

Ligands
Oxidation
Oxides
Manganese
Agglomeration
27 Citations (Scopus)

Spectroscopic Identification of an FeIII Center, not FeIV, in the Crystalline Sc-O-Fe Adduct Derived from [FeIV(O)(TMC)]2+

Prakash, J., Rohde, G. T., Meier, K. K., Jasniewski, A. J., Van Heuvelen, K. M., Münck, E. & Que, L., Mar 18 2015, In : Journal of the American Chemical Society. 137, 10, p. 3478-3481 4 p.

Research output: Contribution to journalArticle

Iron
Crystalline materials
Lewis Acids
Discrete Fourier transforms
Paramagnetic resonance
2 Citations (Scopus)

Synthetic models of 2-oxoglutarate-dependent oxygenases

Allpress, C. J., Kleespies, S. T. & Que, L., Jan 1 2015, 2-Oxoglutarate-Dependent Oxygenases. Hausinger, R. P. & Schofield, C. J. (eds.). 3 ed. Royal Society of Chemistry, p. 123-148 26 p. (RSC Metallobiology; vol. 2015-January, no. 3).

Research output: Chapter in Book/Report/Conference proceedingChapter

Oxygenases
Keto Acids
Enzymes
Oxygen
Ligands
110 Citations (Scopus)

Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes

Puri, M. & Que, L., Jul 15 2015, In : Accounts of Chemical Research. 48, 8, p. 2443-2452 10 p.

Research output: Contribution to journalArticle

Ground state
Ligands
Dioxygenases
Taurine
Electronic structure
76 Citations (Scopus)

Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C-H Bonds with Stereoretention

Serrano-Plana, J., Oloo, W. N., Acosta-Rueda, L., Meier, K. K., Verdejo, B., García-España, E., Basallote, M. G., Münck, E., Que, L., Company, A. & Costas, M., Dec 23 2015, In : Journal of the American Chemical Society. 137, 50, p. 15833-15842 10 p.

Research output: Contribution to journalArticle

Iron
Paramagnetic resonance
Peracetic Acid
Hydroxylation
Kinetics
20 Citations (Scopus)

Upside Down! Crystallographic and Spectroscopic Characterization of an [FeIV(Osyn)(TMC)]2+ Complex

Prakash, J., Rohde, G. T., Meier, K. K., Münck, E. & Que, L., Nov 24 2015, In : Inorganic Chemistry. 54, 23, p. 11055-11057 3 p.

Research output: Contribution to journalArticle

structural analysis
Structural analysis
quadrupoles
Nuclear magnetic resonance
formulations