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2018

Activated Polyacrylamides as Versatile Substrates for Postpolymerization Modification

Larsen, M. B., Herzog, S. E., Quilter, H. C. & Hillmyer, M. A. Jan 16 2018 In : ACS Macro Letters. 7, 1, p. 122-126 5 p.

Research output: Contribution to journalArticle

Acrylamide
Free radical polymerization
Polyacrylates
Amines
Substrates

Computational Design of High-χ Block Oligomers for Accessing 1 nm Domains

Chen, Q. P., Barreda, L., Oquendo, L. E., Hillmyer, M. A., Lodge, T. P. & Siepmann, J. I. May 22 2018 In : ACS Nano. 12, 5, p. 4351-4361

Research output: Contribution to journalArticle

Editorial

Hillmyer, M. A. Jan 9 2018 In : Macromolecules. 51, 1, p. 1-2 2 p.

Research output: Contribution to journalEditorial

Editorial

Hillmyer, M. A. Feb 27 2018 In : Macromolecules. 51, 4, p. 1249-1250 2 p.

Research output: Contribution to journalEditorial

Multiblock Polyesters Demonstrating High Elasticity and Shape Memory Effects

Zhu, Y., Radlauer, M. R., Schneiderman, D. K., Shaffer, M. S. P., Hillmyer, M. A. & Williams, C. K. Apr 10 2018 In : Macromolecules. 51, 7, p. 2466-2475 10 p.

Research output: Contribution to journalArticle

Shape memory effect
Polyesters
Elasticity
Elastomers
Reheat cycle

Poly(alkyl methacrylate)-Grafted Polyolefins as Viscosity Modifiers for Engine Oil: A New Mechanism for Improved Performance

Savoji, M. T., Zhao, D., Muisener, R. J., Schimossek, K., Schoeller, K., Lodge, T. P. & Hillmyer, M. A. Feb 14 2018 In : Industrial and Engineering Chemistry Research. 57, 6, p. 1840-1850 11 p.

Research output: Contribution to journalArticle

Methacrylates
Graft copolymers
Polyolefins
Diesel engines
Viscosity
1 Citations

Reprocessable Acid-Degradable Polycarbonate Vitrimers

Snyder, R. L., Fortman, D. J., De Hoe, G. X., Hillmyer, M. A. & Dichtel, W. R. Jan 23 2018 In : Macromolecules. 51, 2, p. 389-397 9 p.

Research output: Contribution to journalArticle

Reheat cycle
Accessories
Stress relaxation
Polycarbonates
Stress analysis
1 Citations

Revisiting the Anionic Polymerization of Methyl Ethacrylate

Kennemur, J. G., Bates, F. S. & Hillmyer, M. A. Jan 5 2018 In : Macromolecular Chemistry and Physics. 219, 1, 1700282

Research output: Contribution to journalArticle

Anionic polymerization
Molar mass
polymerization
Polystyrenes
X ray scattering

Sustainable Polyester Elastomers from Lactones: Synthesis, Properties, and Enzymatic Hydrolyzability

De Hoe, G. X., Zumstein, M. T., Tiegs, B. J., Brutman, J. P., McNeill, K., Sander, M., Coates, G. W. & Hillmyer, M. A. Jan 24 2018 In : Journal of the American Chemical Society. 140, 3, p. 963-973 11 p.

Research output: Contribution to journalArticle

Subjective testing
Elastomers
Polyesters
Enzymatic hydrolysis
Lactones
2017
31 Citations

50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers

Schneiderman, D. K. & Hillmyer, M. A. May 23 2017 In : Macromolecules. 50, 10, p. 3733-3749 17 p.

Research output: Contribution to journalArticle

Polymers
Thermosets
Feedstocks
Recycling
Industry
4 Citations

Anhydride-Additive-Free Nickel-Catalyzed Deoxygenation of Carboxylic Acids to Olefins

John, A., Hillmyer, M. A. & Tolman, W. B. Feb 13 2017 In : Organometallics. 36, 3, p. 506-509 4 p.

Research output: Contribution to journalArticle

deoxygenation
Anhydrides
Reducing Agents
Alkenes
anhydrides
12 Citations

Conformational Asymmetry and Quasicrystal Approximants in Linear Diblock Copolymers

Schulze, M. W., Lewis, R. M., Lettow, J. H., Hickey, R. J., Gillard, T. M., Hillmyer, M. A. & Bates, F. S. May 16 2017 In : Physical Review Letters. 118, 20, 207801

Research output: Contribution to journalArticle

copolymers
asymmetry
minorities
x ray scattering
self consistent fields
1 Citations

Controlled synthesis of ABCA' tetrablock terpolymers

Radlauer, M. R., Fukuta, S., Matta, M. E. & Hillmyer, M. A. Aug 25 2017 In : Polymer (United Kingdom). 124, p. 60-67 8 p.

Research output: Contribution to journalArticle

Terpolymers
Polymers
Polystyrenes
Polyisoprenes
Molar mass

Degradable Thermosets Derived from an Isosorbide/Succinic Anhydride Monomer and Glycerol

Wilbon, P. A., Swartz, J. L., Meltzer, N. R., Brutman, J. P., Hillmyer, M. A. & Wissinger, J. E. Oct 2 2017 In : ACS Sustainable Chemistry and Engineering. 5, 10, p. 9185-9190 6 p.

Research output: Contribution to journalArticle

Isosorbide
Thermosets
Glycerol
Monomers
Polyethylene oxides
4 Citations

Direct Observation of Nanostructures during Aqueous Dissolution of Polymer/Drug Particles

Ricarte, R. G., Li, Z., Johnson, L. M., Ting, J. M., Reineke, T. M., Bates, F. S., Hillmyer, M. A. & Lodge, T. P. Apr 25 2017 In : Macromolecules. 50, 8, p. 3143-3152 10 p.

Research output: Contribution to journalArticle

hydroxypropylmethylcellulose acetate succinate
Nanostructures
Dispersions
Polymers
Dissolution
4 Citations

Effect of homopolymer in polymerization-induced microphase separation process

Park, J., Saba, S. A., Hillmyer, M. A., Kang, D. C. & Seo, M. Sep 22 2017 In : Polymer (United Kingdom). 126, p. 338-351 14 p.

Research output: Contribution to journalArticle

Microphase separation
Homopolymerization
Polymerization
Phase separation
Polymers
5 Citations

Enhanced Performance of Blended Polymer Excipients in Delivering a Hydrophobic Drug through the Synergistic Action of Micelles and HPMCAS

Li, Z., Johnson, L. M., Ricarte, R. G., Yao, L. J., Hillmyer, M. A., Bates, F. S. & Lodge, T. P. Mar 21 2017 In : Langmuir. 33, 11, p. 2837-2848 12 p.

Research output: Contribution to journalArticle

hydroxypropylmethylcellulose acetate succinate
Excipients
Micelles
acetates
Supersaturation
11 Citations

Impact of Polymer Excipient Molar Mass and End Groups on Hydrophobic Drug Solubility Enhancement

Johnson, L. M., Li, Z., LaBelle, A. J., Bates, F. S., Lodge, T. P. & Hillmyer, M. A. Feb 14 2017 In : Macromolecules. 50, 3, p. 1102-1112 11 p.

Research output: Contribution to journalArticle

Molar mass
Excipients
Polymers
Solubility
Dispersions
3 Citations

Intrinsically Hierarchical Nanoporous Polymers via Polymerization-Induced Microphase Separation

Larsen, M. B., Van Horn, J. D., Wu, F. & Hillmyer, M. A. Jun 13 2017 In : Macromolecules. 50, 11, p. 4363-4371 9 p.

Research output: Contribution to journalArticle

Microphase separation
Polymers
Monomers
Microporosity
Polymerization
5 Citations

Morphological consequences of frustration in ABC triblock polymers

Radlauer, M. R., Sinturel, C., Asai, Y., Arora, A., Bates, F. S., Dorfman, K. D. & Hillmyer, M. A. Jan 1 2017 In : Macromolecules. 50, 1, p. 446-458 13 p.

Research output: Contribution to journalArticle

Polymers
Thin films
Isoprene
Terpolymers
Styrene

Nanoporous Thermosets with Percolating Pores from Block Polymers Chemically Fixed above the Order-Disorder Transition

Vidil, T., Hampu, N. & Hillmyer, M. A. Oct 25 2017 In : ACS Central Science. 3, 10, p. 1114-1120 7 p.

Research output: Contribution to journalArticle

Order disorder transitions
Composite membranes
Thermosets
Ultrafiltration
X ray scattering
1 Citations

Oxidatively Stable Polyolefin Thermoplastics and Elastomers for Biomedical Applications

Wang, Y. & Hillmyer, M. A. Jun 20 2017 In : ACS Macro Letters. 6, 6, p. 613-618 6 p.

Research output: Contribution to journalArticle

Elastomers
Polyolefins
Thermoplastics
Ethylene
Urethane
2 Citations

POLYMER day: Outreach experiments for high school students

Ting, J. M., Ricarte, R. G., Schneiderman, D. K., Saba, S. A., Jiang, Y., Hillmyer, M. A., Bates, F. S., Reineke, T. M., Macosko, C. W. & Lodge, T. P. Nov 14 2017 In : Journal of Chemical Education. 94, 11, p. 1629-1638 10 p.

Research output: Contribution to journalArticle

Polymers
Students
experiment
school
student
8 Citations

Robust Polymer Electrolyte Membranes with High Ambient-Temperature Lithium-Ion Conductivity via Polymerization-Induced Microphase Separation

Chopade, S. A., Au, J. G., Li, Z., Schmidt, P. W., Hillmyer, M. A. & Lodge, T. P. May 3 2017 In : ACS Applied Materials and Interfaces. 9, 17, p. 14561-14565 5 p.

Research output: Contribution to journalArticle

Microphase separation
Lithium
Electrolytes
Polymers
Polymerization
3 Citations

Selective Decarbonylation of Fatty Acid Esters to Linear α-Olefins

John, A., Dereli, B., OrtunÌo, M. A., Johnson, H. E., Hillmyer, M. A., Cramer, C. J. & Tolman, W. B. Aug 14 2017 In : Organometallics. 36, 15, p. 2956-2964 9 p.

Research output: Contribution to journalArticle

Alkenes
fatty acids
alkenes
esters
Esters

Self-Supporting, Hydrophobic, Ionic Liquid-Based Reference Electrodes Prepared by Polymerization-Induced Microphase Separation

Chopade, S. A., Anderson, E. L., Schmidt, P. W., Lodge, T. P., Hillmyer, M. A. & Buhlmann, P. Oct 27 2017 In : ACS Sensors. 2, 10, p. 1498-1504 7 p.

Research output: Contribution to journalArticle

Ionic Liquids
Microphase separation
Ionic liquids
polymerization
Polymerization
8 Citations

Strong, Resilient, and Sustainable Aliphatic Polyester Thermoplastic Elastomers

Watts, A., Kurokawa, N. & Hillmyer, M. A. Jun 12 2017 In : Biomacromolecules. 18, 6, p. 1845-1854 10 p.

Research output: Contribution to journalArticle

Thermoplastic elastomers
Polyesters
Elastomers
Styrene
Molar mass
5 Citations

Structural effects on the reprocessability and stress relaxation of crosslinked polyhydroxyurethanes

Fortman, D. J., Brutman, J. P., Hillmyer, M. A. & Dichtel, W. R. Dec 5 2017 In : Journal of Applied Polymer Science. 134, 45, 44984

Research output: Contribution to journalArticle

Carbonates
Stress relaxation
Polymers
Compression molding
Thermosets
Ring opening polymerization
Hydrogenation
Ethylene
Methacrylates
Copolymers
8 Citations

The promise of plastics from plants

Hillmyer, M. A. Nov 17 2017 In : Science. 358, 6365, p. 868-870 3 p.

Research output: Contribution to journalShort survey

environmental technology
industrial production
polymer
plastic
22 Citations

Thermal processing of diblock copolymer melts mimics metallurgy

Kim, K., Schulze, M. W., Arora, A., Lewis, R. M., Hillmyer, M. A., Dorfman, K. D. & Bates, F. S. May 5 2017 In : Science. 356, 6337, p. 520-523 4 p.

Research output: Contribution to journalArticle

Metallurgy
Hot Temperature
Temperature
Transition Temperature
History

Tricontinuous Nanostructured Polymers via Polymerization-Induced Microphase Separation

Saba, S. A., Lee, B. & Hillmyer, M. A. Nov 21 2017 In : ACS Macro Letters. 6, 11, p. 1232-1236 5 p.

Research output: Contribution to journalArticle

divinyl benzene
Microphase separation
Block copolymers
Polymers
Polymerization
6 Citations

Tuning Mesoporosity in Cross-Linked Nanostructured Thermosets via Polymerization-Induced Microphase Separation

Schulze, M. W. & Hillmyer, M. A. Feb 14 2017 In : Macromolecules. 50, 3, p. 997-1007 11 p.

Research output: Contribution to journalArticle

divinyl benzene
Microphase separation
Thermosets
Macros
Tuning
2016
14 Citations

Acrylic Triblock Copolymers Incorporating Isosorbide for Pressure Sensitive Adhesives

Gallagher, J. J., Hillmyer, M. A. & Reineke, T. M. Jun 6 2016 In : ACS Sustainable Chemistry and Engineering. 4, 6, p. 3379-3387 9 p.

Research output: Contribution to journalArticle

Isosorbide
Block copolymers
Acrylics
Adhesives
polymerization
34 Citations

Aliphatic Polyester Block Polymer Design

Schneiderman, D. K. & Hillmyer, M. A. Apr 26 2016 In : Macromolecules. 49, 7, p. 2419-2428 10 p.

Research output: Contribution to journalArticle

Polyesters
Block copolymers
Polymerization
Molar mass
Enthalpy
13 Citations

Anhydrous Proton Conducting Polymer Electrolyte Membranes via Polymerization-Induced Microphase Separation

Chopade, S. A., So, S., Hillmyer, M. A. & Lodge, T. P. Mar 9 2016 In : ACS Applied Materials and Interfaces. 8, 9, p. 6200-6210 11 p.

Research output: Contribution to journalArticle

Microphase separation
Conducting polymers
Ionic Liquids
Electrolytes
Protons
5 Citations

Avoiding Errors in Electrochemical Measurements: Effect of Frit Material on the Performance of Reference Electrodes with Porous Frit Junctions

Mousavi, M. P. S., Saba, S. A., Anderson, E. L., Hillmyer, M. A. & Buhlmann, P. Sep 6 2016 In : Analytical Chemistry. 88, 17, p. 8706-8713 8 p.

Research output: Contribution to journalArticle

Glass
Electrodes
Electrostatics
Screening
Ions
3 Citations

Branched Diol Monomers from the Sequential Hydrogenation of Renewable Carboxylic Acids

Spanjers, C. S., Schneiderman, D. K., Wang, J. Z., Wang, J., Hillmyer, M. A., Zhang, K. & Dauenhauer, P. J. Oct 6 2016 In : ChemCatChem. 8, 19, p. 3031-3035 5 p.

Research output: Contribution to journalArticle

Lactones
Carboxylic Acids
Carboxylic acids
triols
carboxylic acids
21 Citations

Chemically Recyclable Biobased Polyurethanes

Schneiderman, D. K., Vanderlaan, M. E., Mannion, A. M., Panthani, T. R., Batiste, D. C., Wang, J. Z., Bates, F. S., Macosko, C. W. & Hillmyer, M. A. Apr 19 2016 In : ACS Macro Letters. 5, 4, p. 515-518 4 p.

Research output: Contribution to journalArticle

Polyurethanes
Petroleum
Foams
Recycling
Crude oil
18 Citations

Controlled chain walking for the synthesis of thermoplastic polyolefin elastomers: Synthesis, structure, and properties

O'Connor, K. S., Watts, A., Vaidya, T., LaPointe, A. M., Hillmyer, M. A. & Coates, G. W. Sep 27 2016 In : Macromolecules. 49, 18, p. 6743-6751 9 p.

Research output: Contribution to journalArticle

Elastomers
Polyolefins
Thermoplastics
Thermoplastic elastomers
Copolymers
3 Citations
Refuse compaction
Compatibilizers
Polymethyl methacrylates
Grafts
Polyethylenes
16 Citations

Design of Graft Block Polymer Thermoplastics

Zhang, J., Schneiderman, D. K., Li, T., Hillmyer, M. A. & Bates, F. S. Dec 13 2016 In : Macromolecules. 49, 23, p. 9108-9118 11 p.

Research output: Contribution to journalArticle

Graft copolymers
Grafts
Thermoplastics
Block copolymers
Crystallization
7 Citations

Diels-Alder Reactions of Furans with Itaconic Anhydride: Overcoming Unfavorable Thermodynamics

Pehere, A. D., Xu, S., Thompson, S. K., Hillmyer, M. A. & Hoye, T. R. Jun 3 2016 In : Organic Letters. 18, 11, p. 2584-2587 4 p.

Research output: Contribution to journalArticle

Furans
Diels-Alder reactions
Anhydrides
furans
Cycloaddition Reaction
6 Citations

Discussion on "aperiodic Copolymers"

Rowan, S. J., Barner-Kowollik, C., Klumperman, B., Gaspard, P., Grubbs, R. B., Hillmyer, M. A., Hutchings, L. R., Mahanthappa, M. K., Moatsou, D., O'Reilly, R. K., Ouchi, M., Sawamoto, M. & Lodge, T. P. Jan 19 2016 In : ACS Macro Letters. 5, 1, p. 1-3 3 p.

Research output: Contribution to journalReview article

Terminology
Copolymers
Macromolecules
Macros
Monomers
2 Citations

Filler-Reinforced Elastomers Based on Functional Polyolefin Prepolymers

Ren, N., Matta, M. E., Martinez, H., Walton, K. L., Munro, J. C., Schneiderman, D. K. & Hillmyer, M. A. Jun 1 2016 In : Industrial and Engineering Chemistry Research. 55, 21, p. 6106-6112 7 p.

Research output: Contribution to journalArticle

Elastomers
Polyolefins
Fillers
Soot
Mechanical properties
2 Citations

High surface area carbon black (BP-2000) as a reinforcing agent for poly[(−)-lactide]

Delgado, P. A., Brutman, J. P., Masica, K., Molde, J., Wood, B. & Hillmyer, M. A. Dec 5 2016 In : Journal of Applied Polymer Science. 133, 45, 43926

Research output: Contribution to journalArticle

Soot
Carbon black
Composite materials
Crystallization
Heat resistance
5 Citations

Lightweight micro-cellular plastics from polylactide/polyolefin hybrids

Xu, Y., Delgado, P., Todd, A. D., Loi, J., Saba, S. A., McEneany, R. J., Tower, T., Topolkaraev, V., Macosko, C. W. & Hillmyer, M. A. Oct 12 2016 In : Polymer (United Kingdom). 102, p. 73-83 11 p.

Research output: Contribution to journalArticle

Foamed plastics
Polyolefins
Polypropylenes
Elastomers
Homopolymerization
24 Citations

Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a Predictive Model for Cyclic Ester Polymerizations

Marlier, E. E., MacAranas, J. A., Marell, D. J., Dunbar, C. R., Johnson, M. A., DePorre, Y., Miranda, M. O., Neisen, B. D., Cramer, C. J., Hillmyer, M. A. & Tolman, W. B. Feb 5 2016 In : ACS Catalysis. 6, 2, p. 1215-1224 10 p.

Research output: Contribution to journalArticle

Ring opening polymerization
Esters
Polymerization
Carbon
Ligands
4 Citations

Multicompartment Micelles by Aqueous Self-Assembly of μ-A(BC)n Miktobrush Terpolymers

Moughton, A. O., Sagawa, T., Yin, L., Lodge, T. P. & Hillmyer, M. A. Nov 30 2016 In : ACS Omega. 1, 5, p. 1027-1033 7 p.

Research output: Contribution to journalArticle

Terpolymers
Micelles
Self assembly
Poly C
Molar mass
3 Citations

Nanoscale Concentration Quantification of Pharmaceutical Actives in Amorphous Polymer Matrices by Electron Energy-Loss Spectroscopy

Ricarte, R. G., Lodge, T. P. & Hillmyer, M. A. Jul 26 2016 In : Langmuir. 32, 29, p. 7411-7419 9 p.

Research output: Contribution to journalArticle

hydroxypropylmethylcellulose acetate succinate
Electron energy loss spectroscopy
Phenytoin
Polymer matrix
Dispersions