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2017
22 Citations

50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers

Schneiderman, D. K. & Hillmyer, M. A. May 23 2017 In : Macromolecules. 50, 10, p. 3733-3749 17 p.

Research output: Research - peer-reviewArticle

Polymers
Industry
Thermosets
Feedstocks
Recycling

Anhydride-Additive-Free Nickel-Catalyzed Deoxygenation of Carboxylic Acids to Olefins

John, A., Hillmyer, M. A. & Tolman, W. B. Feb 13 2017 In : Organometallics. 36, 3, p. 506-509 4 p.

Research output: Research - peer-reviewArticle

deoxygenation
anhydrides
carboxylic acids
alkenes
nickel
6 Citations

Conformational Asymmetry and Quasicrystal Approximants in Linear Diblock Copolymers

Schulze, M. W., Lewis, R. M., Lettow, J. H., Hickey, R. J., Gillard, T. M., Hillmyer, M. A. & Bates, F. S. May 16 2017 In : Physical Review Letters. 118, 20, 207801

Research output: Research - peer-reviewArticle

copolymers
asymmetry
minorities
x ray scattering
self consistent fields
1 Citations

Controlled synthesis of ABCA' tetrablock terpolymers

Radlauer, M. R., Fukuta, S., Matta, M. E. & Hillmyer, M. A. Aug 25 2017 In : Polymer (United Kingdom). 124, p. 60-67 8 p.

Research output: Research - peer-reviewArticle

Terpolymers
Polymers
Polystyrenes
Polyisoprenes
Molar mass

Degradable Thermosets Derived from an Isosorbide/Succinic Anhydride Monomer and Glycerol

Wilbon, P. A., Swartz, J. L., Meltzer, N. R., Brutman, J. P., Hillmyer, M. A. & Wissinger, J. E. Oct 2 2017 In : ACS Sustainable Chemistry and Engineering. 5, 10, p. 9185-9190 6 p.

Research output: Research - peer-reviewArticle

Isosorbide
Thermosets
Glycerol
Monomers
succinic anhydride
3 Citations

Direct Observation of Nanostructures during Aqueous Dissolution of Polymer/Drug Particles

Ricarte, R. G., Li, Z., Johnson, L. M., Ting, J. M., Reineke, T. M., Bates, F. S., Hillmyer, M. A. & Lodge, T. P. Apr 25 2017 In : Macromolecules. 50, 8, p. 3143-3152 10 p.

Research output: Research - peer-reviewArticle

Nanostructures
Polymers
Dissolution
Pharmaceutical Preparations
Dispersions
3 Citations

Effect of homopolymer in polymerization-induced microphase separation process

Park, J., Saba, S. A., Hillmyer, M. A., Kang, D. C. & Seo, M. Sep 22 2017 In : Polymer (United Kingdom). 126, p. 338-351 14 p.

Research output: Research - peer-reviewArticle

Microphase separation
Homopolymerization
Polymerization
Phase separation
Polymers
3 Citations

Enhanced Performance of Blended Polymer Excipients in Delivering a Hydrophobic Drug through the Synergistic Action of Micelles and HPMCAS

Li, Z., Johnson, L. M., Ricarte, R. G., Yao, L. J., Hillmyer, M. A., Bates, F. S. & Lodge, T. P. Mar 21 2017 In : Langmuir. 33, 11, p. 2837-2848 12 p.

Research output: Research - peer-reviewArticle

hydroxypropylmethylcellulose acetate succinate
Excipients
Micelles
Polymers
Pharmaceutical Preparations
6 Citations

Impact of Polymer Excipient Molar Mass and End Groups on Hydrophobic Drug Solubility Enhancement

Johnson, L. M., Li, Z., LaBelle, A. J., Bates, F. S., Lodge, T. P. & Hillmyer, M. A. Feb 14 2017 In : Macromolecules. 50, 3, p. 1102-1112 11 p.

Research output: Research - peer-reviewArticle

Molar mass
Excipients
Polymers
Solubility
Pharmaceutical Preparations
3 Citations

Intrinsically Hierarchical Nanoporous Polymers via Polymerization-Induced Microphase Separation

Larsen, M. B., Van Horn, J. D., Wu, F. & Hillmyer, M. A. Jun 13 2017 In : Macromolecules. 50, 11, p. 4363-4371 9 p.

Research output: Research - peer-reviewArticle

Microphase separation
Polymers
Monomers
Polymerization
Microporosity
4 Citations

Morphological consequences of frustration in ABC triblock polymers

Radlauer, M. R., Sinturel, C., Asai, Y., Arora, A., Bates, F. S., Dorfman, K. D. & Hillmyer, M. A. Jan 1 2017 In : Macromolecules. 50, 1, p. 446-458 13 p.

Research output: Research - peer-reviewArticle

Polymers
Thin films
Terpolymers
Styrene
Volume fraction

Nanoporous Thermosets with Percolating Pores from Block Polymers Chemically Fixed above the Order-Disorder Transition

Vidil, T., Hampu, N. & Hillmyer, M. A. Oct 25 2017 In : ACS Central Science. 3, 10, p. 1114-1120 7 p.

Research output: Research - peer-reviewArticle

Order disorder transitions
Composite membranes
Thermosets
Ultrafiltration
X ray scattering

Oxidatively Stable Polyolefin Thermoplastics and Elastomers for Biomedical Applications

Wang, Y. & Hillmyer, M. A. Jun 20 2017 In : ACS Macro Letters. 6, 6, p. 613-618 6 p.

Research output: Research - peer-reviewArticle

Elastomers
Thermoplastics
ethylene
PL 732
Polyolefins
1 Citations

POLYMER day: Outreach experiments for high school students

Ting, J. M., Ricarte, R. G., Schneiderman, D. K., Saba, S. A., Jiang, Y., Hillmyer, M. A., Bates, F. S., Reineke, T. M., Macosko, C. W. & Lodge, T. P. Nov 14 2017 In : Journal of Chemical Education. 94, 11, p. 1629-1638 10 p.

Research output: Research - peer-reviewArticle

Polymers
Students
Experiments
experiment
school
6 Citations

Robust Polymer Electrolyte Membranes with High Ambient-Temperature Lithium-Ion Conductivity via Polymerization-Induced Microphase Separation

Chopade, S. A., Au, J. G., Li, Z., Schmidt, P. W., Hillmyer, M. A. & Lodge, T. P. May 3 2017 In : ACS Applied Materials and Interfaces. 9, 17, p. 14561-14565 5 p.

Research output: Research - peer-reviewArticle

Microphase separation
Lithium
Electrolytes
Polymers
Polymerization

Selective Decarbonylation of Fatty Acid Esters to Linear α-Olefins

John, A., Dereli, B., OrtunÌo, M. A., Johnson, H. E., Hillmyer, M. A., Cramer, C. J. & Tolman, W. B. Aug 14 2017 In : Organometallics. 36, 15, p. 2956-2964 9 p.

Research output: Research - peer-reviewArticle

fatty acids
alkenes
esters
ligands
Alkenes

Self-Supporting, Hydrophobic, Ionic Liquid-Based Reference Electrodes Prepared by Polymerization-Induced Microphase Separation

Chopade, S. A., Anderson, E. L., Schmidt, P. W., Lodge, T. P., Hillmyer, M. A. & Buhlmann, P. Oct 27 2017 In : ACS Sensors. 2, 10, p. 1498-1504 7 p.

Research output: Research - peer-reviewArticle

Ionic Liquids
Microphase separation
Polymerization
Electrodes
Ionic liquids
6 Citations

Strong, Resilient, and Sustainable Aliphatic Polyester Thermoplastic Elastomers

Watts, A., Kurokawa, N. & Hillmyer, M. A. Jun 12 2017 In : Biomacromolecules. 18, 6, p. 1845-1854 10 p.

Research output: Research - peer-reviewArticle

Thermoplastic elastomers
Polyesters
poly(lactide)
caprolactone
Elastomers
3 Citations

Structural effects on the reprocessability and stress relaxation of crosslinked polyhydroxyurethanes

Fortman, D. J., Brutman, J. P., Hillmyer, M. A. & Dichtel, W. R. Dec 5 2017 In : Journal of Applied Polymer Science. 134, 45, 44984

Research output: Research - peer-reviewArticle

Carbonates
Stress relaxation
Temperature
Polymers
Compression molding
Ring opening polymerization
Hydrogenation
Copolymers
ethylene
acrylic acid
2 Citations

The promise of plastics from plants

Hillmyer, M. A. Nov 17 2017 In : Science. 358, 6365, p. 868-870 3 p.

Research output: Research - peer-reviewShort survey

environmental technology
industrial production
polymer
plastic
15 Citations

Thermal processing of diblock copolymer melts mimics metallurgy

Kim, K., Schulze, M. W., Arora, A., Lewis, R. M., Hillmyer, M. A., Dorfman, K. D. & Bates, F. S. May 5 2017 In : Science. 356, 6337, p. 520-523 4 p.

Research output: Research - peer-reviewArticle

Metallurgy
Hot Temperature
Temperature
Transition Temperature
History

Tricontinuous Nanostructured Polymers via Polymerization-Induced Microphase Separation

Saba, S. A., Lee, B. & Hillmyer, M. A. Nov 21 2017 In : ACS Macro Letters. 6, 11, p. 1232-1236 5 p.

Research output: Research - peer-reviewArticle

Microphase separation
Block copolymers
Polymers
Polymerization
divinyl benzene
5 Citations

Tuning Mesoporosity in Cross-Linked Nanostructured Thermosets via Polymerization-Induced Microphase Separation

Schulze, M. W. & Hillmyer, M. A. Feb 14 2017 In : Macromolecules. 50, 3, p. 997-1007 11 p.

Research output: Research - peer-reviewArticle

Microphase separation
Thermosets
Macros
Tuning
Polymerization
2016
12 Citations

Acrylic Triblock Copolymers Incorporating Isosorbide for Pressure Sensitive Adhesives

Gallagher, J. J., Hillmyer, M. A. & Reineke, T. M. Jun 6 2016 In : ACS Sustainable Chemistry and Engineering. 4, 6, p. 3379-3387 9 p.

Research output: Research - peer-reviewArticle

Isosorbide
Block copolymers
Acrylics
Adhesives
adhesive
29 Citations

Aliphatic Polyester Block Polymer Design

Schneiderman, D. K. & Hillmyer, M. A. Apr 26 2016 In : Macromolecules. 49, 7, p. 2419-2428 10 p.

Research output: Research - peer-reviewArticle

Polyesters
Block copolymers
Polymerization
Molar mass
Enthalpy
12 Citations

Anhydrous Proton Conducting Polymer Electrolyte Membranes via Polymerization-Induced Microphase Separation

Chopade, S. A., So, S., Hillmyer, M. A. & Lodge, T. P. Mar 9 2016 In : ACS Applied Materials and Interfaces. 8, 9, p. 6200-6210 11 p.

Research output: Research - peer-reviewArticle

Microphase separation
Conducting polymers
Electrolytes
Protons
Polymers
3 Citations

Avoiding Errors in Electrochemical Measurements: Effect of Frit Material on the Performance of Reference Electrodes with Porous Frit Junctions

Mousavi, M. P. S., Saba, S. A., Anderson, E. L., Hillmyer, M. A. & Buhlmann, P. Sep 6 2016 In : Analytical Chemistry. 88, 17, p. 8706-8713 8 p.

Research output: Research - peer-reviewArticle

Glass
Electrodes
Electrostatics
Screening
Ions
3 Citations

Branched Diol Monomers from the Sequential Hydrogenation of Renewable Carboxylic Acids

Spanjers, C. S., Schneiderman, D. K., Wang, J. Z., Wang, J., Hillmyer, M. A., Zhang, K. & Dauenhauer, P. J. Oct 6 2016 In : ChemCatChem. 8, 19, p. 3031-3035 5 p.

Research output: Research - peer-reviewArticle

Lactones
Carboxylic Acids
Hydrogenation
Monomers
carboxylic acids
16 Citations

Chemically Recyclable Biobased Polyurethanes

Schneiderman, D. K., Vanderlaan, M. E., Mannion, A. M., Panthani, T. R., Batiste, D. C., Wang, J. Z., Bates, F. S., Macosko, C. W. & Hillmyer, M. A. Apr 19 2016 In : ACS Macro Letters. 5, 4, p. 515-518 4 p.

Research output: Research - peer-reviewArticle

Polyurethanes
Petroleum
Foams
Recycling
delta-valerolactone
10 Citations

Controlled chain walking for the synthesis of thermoplastic polyolefin elastomers: Synthesis, structure, and properties

O'Connor, K. S., Watts, A., Vaidya, T., LaPointe, A. M., Hillmyer, M. A. & Coates, G. W. Sep 27 2016 In : Macromolecules. 49, 18, p. 6743-6751 9 p.

Research output: Research - peer-reviewArticle

Elastomers
Thermoplastics
PL 732
Polyolefins
Copolymers
2 Citations
Compatibilizers
Polymethyl methacrylates
Grafts
Polyethylenes
Copolymers
12 Citations

Design of Graft Block Polymer Thermoplastics

Zhang, J., Schneiderman, D. K., Li, T., Hillmyer, M. A. & Bates, F. S. Dec 13 2016 In : Macromolecules. 49, 23, p. 9108-9118 11 p.

Research output: Research - peer-reviewArticle

Graft copolymers
Grafts
Thermoplastics
Block copolymers
Crystallization
6 Citations

Diels-Alder Reactions of Furans with Itaconic Anhydride: Overcoming Unfavorable Thermodynamics

Pehere, A. D., Xu, S., Thompson, S. K., Hillmyer, M. A. & Hoye, T. R. Jun 3 2016 In : Organic Letters. 18, 11, p. 2584-2587 4 p.

Research output: Research - peer-reviewArticle

Diels-Alder reactions
furans
anhydrides
thermodynamics
Furans
6 Citations

Discussion on "aperiodic Copolymers"

Rowan, S. J., Barner-Kowollik, C., Klumperman, B., Gaspard, P., Grubbs, R. B., Hillmyer, M. A., Hutchings, L. R., Mahanthappa, M. K., Moatsou, D., O'Reilly, R. K., Ouchi, M., Sawamoto, M. & Lodge, T. P. Jan 19 2016 In : ACS Macro Letters. 5, 1, p. 1-3 3 p.

Research output: Research - peer-reviewReview article

Terminology
Copolymers
Macromolecules
Macros
Monomers
1 Citations

Filler-Reinforced Elastomers Based on Functional Polyolefin Prepolymers

Ren, N., Matta, M. E., Martinez, H., Walton, K. L., Munro, J. C., Schneiderman, D. K. & Hillmyer, M. A. Jun 1 2016 In : Industrial and Engineering Chemistry Research. 55, 21, p. 6106-6112 7 p.

Research output: Research - peer-reviewArticle

Elastomers
Fillers
PL 732
Polyolefins
Mechanical properties
1 Citations

High surface area carbon black (BP-2000) as a reinforcing agent for poly[(−)-lactide]

Delgado, P. A., Brutman, J. P., Masica, K., Molde, J., Wood, B. & Hillmyer, M. A. Dec 5 2016 In : Journal of Applied Polymer Science. 133, 45, 43926

Research output: Research - peer-reviewArticle

Soot
poly(lactide)
Hot Temperature
Carbon black
Composite materials
4 Citations

Lightweight micro-cellular plastics from polylactide/polyolefin hybrids

Xu, Y., Delgado, P., Todd, A. D., Loi, J., Saba, S. A., McEneany, R. J., Tower, T., Topolkaraev, V., Macosko, C. W. & Hillmyer, M. A. Oct 12 2016 In : Polymer (United Kingdom). 102, p. 73-83 11 p.

Research output: Research - peer-reviewArticle

Foamed plastics
Polyolefins
Polypropylenes
PL 732
poly(lactide)
19 Citations

Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a Predictive Model for Cyclic Ester Polymerizations

Marlier, E. E., MacAranas, J. A., Marell, D. J., Dunbar, C. R., Johnson, M. A., DePorre, Y., Miranda, M. O., Neisen, B. D., Cramer, C. J., Hillmyer, M. A. & Tolman, W. B. Feb 5 2016 In : ACS Catalysis. 6, 2, p. 1215-1224 10 p.

Research output: Research - peer-reviewArticle

Ring opening polymerization
Esters
Polymerization
caprolactone
disalicylaldehyde ethylenediamine
2 Citations

Multicompartment Micelles by Aqueous Self-Assembly of μ-A(BC)n Miktobrush Terpolymers

Moughton, A. O., Sagawa, T., Yin, L., Lodge, T. P. & Hillmyer, M. A. Nov 30 2016 In : ACS Omega. 1, 5, p. 1027-1033 7 p.

Research output: Research - peer-reviewArticle

Terpolymers
Micelles
Self assembly
Poly C
Molar mass
3 Citations

Nanoscale Concentration Quantification of Pharmaceutical Actives in Amorphous Polymer Matrices by Electron Energy-Loss Spectroscopy

Ricarte, R. G., Lodge, T. P. & Hillmyer, M. A. Jul 26 2016 In : Langmuir. 32, 29, p. 7411-7419 9 p.

Research output: Research - peer-reviewArticle

energy dissipation
electron energy
polymers
matrices
spectroscopy
4 Citations

Poly(cyclohexylethylene)-block-Poly(lactide) Oligomers for Ultrasmall Nanopatterning Using Atomic Layer Deposition

Yao, L., Oquendo, L. E., Schulze, M. W., Lewis, R. M., Gladfelter, W. L. & Hillmyer, M. A. Mar 30 2016 In : ACS Applied Materials and Interfaces. 8, 11, p. 7431-7439 9 p.

Research output: Research - peer-reviewArticle

Atomic layer deposition
Oligomers
Thin films
Substrates
poly(lactide)
1 Citations

Poly(urea ester): A family of biodegradable polymers with high melting temperatures

Tang, D., Chen, Z., Correa-Netto, F., Macosko, C. W., Hillmyer, M. A. & Zhang, G. Jan 1 2016 In : Journal of Polymer Science, Part A: Polymer Chemistry. 54, 24, p. 3795-3799 5 p.

Research output: Research - peer-reviewArticle

Biodegradable polymers
Melting point
Urea
Polymers
poly(ester-urea)
2 Citations

Polysilylether: A Degradable Polymer from Biorenewable Feedstocks

Cheng, C., Watts, A., Hillmyer, M. A. & Hartwig, J. F. Jan 1 2016 In : Angewandte Chemie - International Edition. 55, 39, p. 11872-11876 5 p.

Research output: Research - peer-reviewArticle

Feedstocks
Polymers
Monomers
Molar mass
Polymerization
8 Citations

Reactive Compatibilization of Poly(ethylene terephthalate) and High-Density Polyethylene Using Amino-Telechelic Polyethylene

Todd, A. D., McEneany, R. J., Topolkaraev, V. A., Macosko, C. W. & Hillmyer, M. A. Dec 13 2016 In : Macromolecules. 49, 23, p. 8988-8994 7 p.

Research output: Research - peer-reviewArticle

Compatibilizers
High density polyethylenes
Polyethylene terephthalates
Polyethylenes
Polyethylene Terephthalates
6 Citations

Regioselective cross metathesis for block and heterotelechelic polymer synthesis

Radlauer, M. R., Matta, M. E. & Hillmyer, M. A. Oct 28 2016 In : Polymer Chemistry. 7, 40, p. 6269-6278 10 p.

Research output: Research - peer-reviewArticle

Ring opening polymerization
Polymers
Polymerization
Monomers
Molar mass
13 Citations

Renewable, Degradable, and Chemically Recyclable Cross-Linked Elastomers

Brutman, J. P., De Hoe, G. X., Schneiderman, D. K., Le, T. N. & Hillmyer, M. A. Oct 26 2016 In : Industrial and Engineering Chemistry Research. 55, 42, p. 11097-11106 10 p.

Research output: Research - peer-reviewArticle

Elastomers
Tensile strength
Degradation
delta-valerolactone
Carbonates
31 Citations

Tough and Sustainable Graft Block Copolymer Thermoplastics

Zhang, J., Li, T., Mannion, A. M., Schneiderman, D. K., Hillmyer, M. A. & Bates, F. S. Mar 15 2016 In : ACS Macro Letters. 5, 3, p. 407-412 6 p.

Research output: Research - peer-reviewArticle

Graft copolymers
Thermoplastics
Block copolymers
Hypromellose Derivatives
Microphase separation
3 Citations

"Uncontrolled" Preparation of Disperse Poly(lactide)-block-poly(styrene)-block-poly(lactide) for Nanopatterning Applications

Vanderlaan, M. E. & Hillmyer, M. A. Nov 8 2016 In : Macromolecules. 49, 21, p. 8031-8040 10 p.

Research output: Research - peer-reviewArticle

Styrene
poly(lactide)
X ray scattering
Self assembly
Block copolymers
2015
23 Citations

Bottlebrush Block Polymers: Quantitative Theory and Experiments

Dalsin, S. J., Rions-Maehren, T. G., Beam, M. D., Bates, F. S., Hillmyer, M. A. & Matsen, M. W. Nov 6 2015 In : ACS Nano. 9, 12, p. 12233-12245 13 p.

Research output: Research - peer-reviewArticle

Block copolymers
Molecules
Experiments
polymers
exponents