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2017
2 Citations

A review of biorefinery separations for bioproduct production via thermocatalytic processing

Nguyen, H., Dejaco, R. F., Mittal, N., Siepmann, J. I., Tsapatsis, M., Snyder, M. A., Fan, W., Saha, B. & Vlachos, D. G. Jun 7 2017 In : Annual Review of Chemical and Biomolecular Engineering. 8, p. 115-137 23 p.

Research output: Research - peer-reviewReview article

Processing
Biomass
Carbon
Adsorption
Zeolites
Zeolites
Bioethanol
Molecular modeling
Economic analysis
Process design
3 Citations

Biomass-Derived Butadiene by Dehydra-Decyclization of Tetrahydrofuran

Abdelrahman, O. A., Park, D. S., Vinter, K. P., Spanjers, C. S., Ren, L., Cho, H. J., Vlachos, D. G., Fan, W., Tsapatsis, M. & Dauenhauer, P. J. May 1 2017 In : ACS Sustainable Chemistry and Engineering. 5, 5, p. 3732-3736 5 p.

Research output: Research - peer-reviewArticle

Butadiene
Phosphorus
Biomass
tetrahydrofuran
1,3-butadiene

Epitaxial growth: Rapid synthesis of highly permeable and selective zeolite-T membranes

Luo, Y., Lv, Y., Kumar, P., Chu, J., Yang, J., Tsapatsis, M., Mkhoyan, K. A., He, G., Lu, J. & Zhang, Y. 2017 In : Journal of Materials Chemistry A. 5, 34, p. 17828-17832 5 p.

Research output: Research - peer-reviewArticle

Zeolites
Epitaxial growth
Seed
Membranes
2-Propanol
2 Citations

Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal-Organic Framework Adsorbents and Membranes

Shah, M. S., Tsapatsis, M. & Siepmann, J. I. Jul 26 2017 In : Chemical Reviews. 117, 14, p. 9755-9803 49 p.

Research output: Research - peer-reviewReview article

Zeolites
Hydrogen Sulfide
Adsorbents
Oxides
Metals
2 Citations

Nanoscale Control of Homoepitaxial Growth on a Two-Dimensional Zeolite

Shete, M., Kumar, M., Kim, D., Rangnekar, N., Xu, D., Topuz, B., Agrawal, K. V., Karapetrova, E., Stottrup, B., Al-Thabaiti, S., Basahel, S., Narasimharao, K., Rimer, J. D. & Tsapatsis, M. Jan 9 2017 In : Angewandte Chemie - International Edition. 56, 2, p. 535-539 5 p.

Research output: Research - peer-reviewArticle

Zeolites
Crystal growth
Crystallization
Nanosheets
Crystallites
6 Citations

Renewable Isoprene by Sequential Hydrogenation of Itaconic Acid and Dehydra-Decyclization of 3-Methyl-Tetrahydrofuran

Abdelrahman, O. A., Park, D. S., Vinter, K. P., Spanjers, C. S., Ren, L., Cho, H. J., Zhang, K., Fan, W., Tsapatsis, M. & Dauenhauer, P. J. Feb 3 2017 In : ACS Catalysis. 7, 2, p. 1428-1431 4 p.

Research output: Research - peer-reviewArticle

Hydrogenation
tetrahydrofuran
itaconic acid
isoprene
Isoprene
7 Citations

Renewable p-Xylene from 2,5-Dimethylfuran and Ethylene Using Phosphorus-Containing Zeolite Catalysts

Cho, H. J., Ren, L., Vattipalli, V., Yeh, Y. H., Gould, N., Xu, B., Gorte, R. J., Lobo, R., Dauenhauer, P. J., Tsapatsis, M. & Fan, W. 2017 (Accepted/In press) In : ChemCatChem.

Research output: Research - peer-reviewArticle

Zeolites
Phosphorus
Catalysts
4-xylene
ethylene

Simple quantification of zeolite acid site density by reactive gas chromatography

Abdelrahman, O. A., Vinter, K. P., Ren, L., Xu, D., Gorte, R. J., Tsapatsis, M. & Dauenhauer, P. J. 2017 In : Catalysis Science and Technology. 7, 17, p. 3831-3841 11 p.

Research output: Research - peer-reviewArticle

Zeolites
Gas chromatography
Acids
Gases
Temperature programmed desorption
1 Citations

Studying two-dimensional zeolites with the tools of surface science: MFI nanosheets on Au(111)

Kestell, J. D., Zhong, J. Q., Shete, M., Waluyo, I., Sadowski, J. T., Stacchiola, D. J., Tsapatsis, M. & Boscoboinik, J. A. Feb 1 2017 In : Catalysis Today. 280, p. 283-288 6 p.

Research output: Research - peer-reviewArticle

Nanosheets
Zeolites
Absorption spectroscopy
Infrared radiation
Catalysts

Sub-Micrometer Zeolite Films on Gold-Coated Silicon Wafers with Single-Crystal-Like Dielectric Constant and Elastic Modulus

Tiriolo, R., Rangnekar, N., Zhang, H., Shete, M., Bai, P., Nelson, J., Karapetrova, E., Macosko, C. W., Siepmann, J. I., Lamanna, E., Lavano, A. & Tsapatsis, M. 2017 (Accepted/In press) In : Advanced Functional Materials.

Research output: Research - peer-reviewArticle

micrometers
modulus of elasticity
wafers
permittivity
gold

Transferable potentials for phase equilibria. Improved united-atom description of ethane and ethylene

Shah, M. S., Siepmann, J. I. & Tsapatsis, M. 2017 (Accepted/In press) In : AIChE Journal.

Research output: Research - peer-reviewArticle

Ethane
Phase equilibria
Atoms
ethylene
Ethylene
12 Citations

Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets

Jeon, M. Y. , Kim, D. , Kumar, P. , Lee, P. S. , Rangnekar, N. , Bai, P. , Shete, M. , Elyassi, B. , Lee, H. S. , Narasimharao, K. , Basahel, S. N. , Al-Thabaiti, S. , Xu, W. , Cho, H. J. , Fetisov, E. O. , Thyagarajan, R. , Dejaco, R. F. , Fan, W. , Mkhoyan, K. A. , Siepmann, J. I. & 1 others Tsapatsis, M. Mar 30 2017 In : Nature. 543, 7647, p. 690-694 5 p.

Research output: Research - peer-reviewArticle

Zeolites
Membranes
Nanoparticles
Chemical Industry
Silicates
2016
5 Citations

Adsorptive Separation of 1-Butanol from Aqueous Solutions Using MFI-and FER-Type Zeolite Frameworks: A Monte Carlo Study

Dejaco, R. F., Bai, P., Tsapatsis, M. & Siepmann, J. I. Mar 1 2016 In : Langmuir. 32, 8, p. 2093-2101 9 p.

Research output: Research - peer-reviewArticle

ethyl alcohol
aqueous solutions
Zeolites
1-Butanol
Butenes
3 Citations
distillation
butanes
economics
mathematical models
isomers
5 Citations

Combining Pre- and Post-Nucleation Trajectories for the Synthesis of High FAU-Content Faujasite Nanocrystals from Organic-Free Sols

Khaleel, M., Xu, W., Lesch, D. A. & Tsapatsis, M. Jun 28 2016 In : Chemistry of Materials. 28, 12, p. 4204-4213 10 p.

Research output: Research - peer-reviewArticle

Polymethyl Methacrylate
Nanocrystals
Nucleation
Trajectories
faujasite

Cover Picture: Open-Pore Two-Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon-Isomer-Selective Membranes on Porous Polymer Supports (Angew. Chem. Int. Ed. 25/2016)

Zhang, H., Xiao, Q., Guo, X., Li, N., Kumar, P., Rangnekar, N., Jeon, M. Y., Al-Thabaiti, S., Narasimharao, K., Basahel, S. N., Topuz, B., Onorato, F. J., Macosko, C. W., Mkhoyan, K. A. & Tsapatsis, M. Jun 13 2016 In : Angewandte Chemie - International Edition. 55, 25, p. 7009 1 p.

Research output: Research - peer-reviewComment/debate

Nanosheets
Zeolites
Isomers
Hydrocarbons
Membranes
12 Citations

Ethanol/water mixture pervaporation performance of b-oriented silicalite-1 membranes made by gel-free secondary growth

Elyassi, B., Jeon, M. Y., Tsapatsis, M., Narasimharao, K., Basahel, S. N. & Al-Thabaiti, S. Feb 1 2016 In : AICHE Journal. 62, 2, p. 556-563 8 p.

Research output: Research - peer-reviewArticle

Pervaporation
Ethanol
Gels
Membranes
Water
4 Citations

Factors Governing the Formation of Hierarchically and Sequentially Intergrown MFI Zeolites by Using Simple Diquaternary Ammonium Structure-Directing Agents

Keoh, S. H., Chaikittisilp, W., Muraoka, K., Mukti, R. R., Shimojima, A., Kumar, P., Tsapatsis, M. & Okubo, T. Dec 27 2016 In : Chemistry of Materials. 28, 24, p. 8997-9007 11 p.

Research output: Research - peer-reviewArticle

Zeolites
Ammonium Compounds
Diquat
Crystals
Electron microscopes
2 Citations

Hierarchical materials: Background and perspectives

Mishnaevsky, L. & Tsapatsis, M. Sep 1 2016 In : MRS Bulletin. 41, 9, p. 661-664 4 p.

Research output: Research - peer-reviewArticle

inspiration
nanotechnology
manufacturing
requirements
Nanotechnology
3 Citations
Hydrocarbons
Sorbents
Natural gas
Adsorption
Sour gas
9 Citations

Interplay between hydrophilicity and surface barriers on water transport in zeolite membranes

Fasano, M., Humplik, T., Bevilacqua, A., Tsapatsis, M., Chiavazzo, E., Wang, E. N. & Asinari, P. Oct 3 2016 In : Nature Communications. 7, 12762

Research output: Research - peer-reviewArticle

Zeolites
Hydrophilicity
Membranes
Water
Hydrophobic and Hydrophilic Interactions
2 Citations

Modeling, optimization, and cost analysis of an IGCC plant with a membrane reactor for carbon capture

Lima, F. V., Daoutidis, P. & Tsapatsis, M. 2016 (Accepted/In press) In : AICHE Journal.

Research output: Research - peer-reviewArticle

Carbon capture
Gasification
Membranes
Costs
Carbon
7 Citations

Nucleation of open framework materials: Navigating the voids

Rimer, J. D. & Tsapatsis, M. May 1 2016 In : MRS Bulletin. 41, 5, p. 393-398 6 p.

Research output: Research - peer-reviewArticle

voids
nucleation
crystals
Nucleation
Crystals
11 Citations

Open-Pore Two-Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon-Isomer-Selective Membranes on Porous Polymer Supports

Zhang, H., Xiao, Q., Guo, X., Li, N., Kumar, P., Rangnekar, N., Jeon, M. Y., Al-Thabaiti, S., Narasimharao, K., Basahel, S. N., Topuz, B., Onorato, F. J., Macosko, C. W., Mkhoyan, K. A. & Tsapatsis, M. 2016 (Accepted/In press) In : Angewandte Chemie - International Edition.

Research output: Research - peer-reviewArticle

Zeolites
Nanosheets
Hydrocarbons
Isomers
Polymers
6 Citations

Oxidation and Reduction under Cover: Chemistry at the Confined Space between Ultrathin Nanoporous Silicates and Ru(0001)

Zhong, J. Q., Kestell, J., Waluyo, I., Wilkins, S., Mazzoli, C., Barbour, A., Kaznatcheev, K., Shete, M., Tsapatsis, M. & Boscoboinik, J. A. May 5 2016 In : Journal of Physical Chemistry C. 120, 15, p. 8240-8245 6 p.

Research output: Research - peer-reviewArticle

silicates
chemistry
silicon dioxide
oxidation
Silicates
3 Citations

Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

Ren, L., Guo, Q., Orazov, M., Xu, D., Politi, D., Kumar, P., Alhassan, S. M., Mkhoyan, K. A., Sidiras, D., Davis, M. E. & Tsapatsis, M. 2016 (Accepted/In press) In : ChemCatChem.

Research output: Research - peer-reviewArticle

solid state
catalysts
acids
Lewis Acids
Catalysts
12 Citations

Thermal Stabilization of Metal-Organic Framework-Derived Single-Site Catalytic Clusters through Nanocasting

Malonzo, C. D., Shaker, S. M., Ren, L., Prinslow, S. D., Platero-Prats, A. E., Gallington, L. C., Borycz, J., Thompson, A. B., Wang, T. C., Farha, O. K., Hupp, J. T., Lu, C. C., Chapman, K. W., Myers, J. C., Penn, R. L., Gagliardi, L., Tsapatsis, M. & Stein, A. Mar 2 2016 In : Journal of the American Chemical Society. 138, 8, p. 2739-2748 10 p.

Research output: Research - peer-reviewArticle

Stabilization
Metals
Temperature
Hot Temperature
Catalytic Domain
2 Citations

Tunable oleo-furan surfactants by acylation of renewable furans

Park, D. S., Joseph, K. E., Koehle, M., Krumm, C., Ren, L., Damen, J. N., Shete, M. H., Lee, H. S., Zuo, X., Lee, B., Fan, W., Vlachos, D. G., Lobo, R. F., Tsapatsis, M. & Dauenhauer, P. J. Nov 23 2016 In : ACS Central Science. 2, 11, p. 820-824 5 p.

Research output: Research - peer-reviewArticle

Furans
Acylation
Surface-Active Agents
Water
furan
6 Citations

Understanding Diffusion in Hierarchical Zeolites with House-of-Cards Nanosheets

Bai, P., Haldoupis, E., Dauenhauer, P. J., Tsapatsis, M. & Siepmann, J. I. Aug 23 2016 In : ACS Nano. 10, 8, p. 7612-7618 7 p.

Research output: Research - peer-reviewArticle

zeolites
Zeolites
Nanosheets
sorbates
free energy
2015
16 Citations

2D zeolite coatings: Langmuir-Schaefer deposition of 3 nm thick MFI zeolite nanosheets

Rangnekar, N., Shete, M., Agrawal, K. V., Topuz, B., Kumar, P., Guo, Q., Ismail, I., Alyoubi, A., Basahel, S., Narasimharao, K., Macosko, C. W., Mkhoyan, K. A., Al-Thabaiti, S., Stottrup, B. & Tsapatsis, M. May 1 2015 In : Angewandte Chemie - International Edition. 54, 22, p. 6571-6575 5 p.

Research output: Research - peer-reviewArticle

Zeolites
Nanosheets
Coatings
Calcination
Suspensions

431787 a highly permeable and selective aminofunctionalized MOF CAU-1 membrane for separation of molecular mixture

Yang, J., Yin, H., Wang, J., Lu, J., Zhang, Y., Lin, J. Y. S. & Tsapatsis, M. 2015 Separations Division 2015 - Core Programming Area at the 2015 AIChE Annual Meeting. AIChE, Vol. 2, p. 753-755 3 p.

Research output: ResearchConference contribution

Carbon Monoxide
Membranes
Adsorption
Pore size
Metals
3 Citations

Activation of giant silicalite-1 monocrystals combining rapid thermal processing and ozone calcination

Navarro, M., Mateo, E., Diosdado, B., Tsapatsis, M. & Coronas, J. 2015 In : RSC Advances. 5, 23, p. 18035-18040 6 p.

Research output: Research - peer-reviewArticle

Rapid thermal processing
Ozone
Calcination
Thermogravimetric analysis
Chemical activation
2 Citations

Carbon Nanotube Selective Membranes with Subnanometer, Vertically Aligned Pores, and Enhanced Gas Transport Properties

Labropoulos, A., Veziri, C., Kapsi, M., Pilatos, G., Likodimos, V., Tsapatsis, M., Kanellopoulos, N. K., Romanos, G. E. & Karanikolos, G. N. Dec 22 2015 In : Chemistry of Materials. 27, 24, p. 8198-8210 13 p.

Research output: Research - peer-reviewArticle

Carbon Nanotubes
Transport properties
Nanotubes
Gases
Membranes
9 Citations

Development of the Transferable Potentials for Phase Equilibria Model for Hydrogen Sulfide

Shah, M. S., Tsapatsis, M. & Siepmann, J. I. Jun 11 2015 In : Journal of Physical Chemistry B. 119, 23, p. 7041-7052 12 p.

Research output: Research - peer-reviewArticle

hydrogen sulfide
interactions
Hydrogen Sulfide
Phase equilibria
Hydrogen sulfide
32 Citations
crude oil
zeolites
Zeolites
broths
fermentation
2 Citations

Economic assessment of Temperature Swing Adsorption systems as Claus Tail Gas Clean Up Units

Al Wahedi, Y., Torres, A. I., Al Hashimi, S., Dowling, N. I., Daoutidis, P. & Tsapatsis, M. Apr 4 2015 In : Chemical Engineering Science. 126, p. 186-195 10 p.

Research output: Research - peer-reviewArticle

Adsorption
Tail
Recovery
Economics
Unit
6 Citations

Monte Carlo simulations probing the adsorptive separation of hydrogen sulfide/methane mixtures using all-silica zeolites

Shah, M. S., Tsapatsis, M. & Siepmann, J. I. Nov 10 2015 In : Langmuir. 31, 44, p. 12268-12278 11 p.

Research output: Research - peer-reviewArticle

hydrogen sulfide
zeolites
methane
silicon dioxide
adsorption
2 Citations

Nucleation, Growth, and Robust Synthesis of SPP Zeolite: Effect of Ethanol, Sodium, and Potassium

Swindlehurst, G. R., Kumar, P., Xu, D., Alhassan, S. M., Mkhoyan, K. A. & Tsapatsis, M. May 28 2015 In : Topics in Catalysis. 58, 7-9, p. 545-558 14 p.

Research output: Research - peer-reviewArticle

Zeolites
Nanosheets
Polymethyl Methacrylate
Potassium
Nucleation
36 Citations

Oriented MFI membranes by gel-less secondary growth of sub-100 nm MFI-nanosheet seed layers

Agrawal, K. V., Topuz, B., Pham, T. C. T., Nguyen, T. H., Sauer, N., Rangnekar, N., Zhang, H., Narasimharao, K., Basahel, S. N., Francis, L. F., Macosko, C. W., Al-Thabaiti, S., Tsapatsis, M. & Yoon, K. B. Jun 1 2015 In : Advanced Materials. 27, 21, p. 3243-3249 7 p.

Research output: Research - peer-reviewArticle

Nanosheets
Molecular sieves
Butane
Xylene
Isomers
10 Citations

Quantification of thickness and wrinkling of exfoliated two-dimensional zeolite nanosheets

Kumar, P., Agrawal, K. V., Tsapatsis, M. & Mkhoyan, K. A. May 11 2015 In : Nature Communications. 6, 7128

Research output: Research - peer-reviewArticle

wrinkling
Zeolites
Nanosheets
cells
absorbents
41 Citations

Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization

Ren, L., Guo, Q., Kumar, P., Orazov, M., Xu, D., Alhassan, S. M., Mkhoyan, K. A., Davis, M. E. & Tsapatsis, M. Sep 1 2015 In : Angewandte Chemie - International Edition. 54, 37, p. 10848-10851 4 p.

Research output: Research - peer-reviewArticle

Lactulose
Zeolites
Nanosheets
Lactose
Isomerization
1 Citations
Economic analysis
Ethanol
Membranes
Water
Economics
80 Citations

Zeolite membranes - a review and comparison with MOFs

Rangnekar, N., Mittal, N., Elyassi, B., Caro, J. & Tsapatsis, M. Oct 21 2015 In : Chemical Society Reviews. 44, 20, p. 7128-7154 27 p.

Research output: Research - peer-reviewArticle

Zeolites
Membranes
Metals
Industrial applications
Seed
2014
28 Citations

2-dimensional zeolites

Tsapatsis, M. 2014 In : AICHE Journal. 60, 7, p. 2374-2381 8 p.

Research output: Research - peer-reviewArticle

Zeolites
Catalysis
Membranes
13 Citations
zeolites
selectivity
acids
cells
Zeolites
20 Citations

A high-performance adsorbent for hydrogen sulfide removal

Elyassi, B., Wahedi, Y. A., Rajabbeigi, N., Kumar, P., Jeong, J. S., Zhang, X., Kumar, P., Balasubramanian, V. V., Katsiotis, M. S., Andre Mkhoyan, K., Boukos, N., Hashimi, S. A. & Tsapatsis, M. May 15 2014 In : Microporous and Mesoporous Materials. 190, p. 152-155 4 p.

Research output: Research - peer-reviewArticle

hydrogen sulfide
adsorbents
adsorption
Adsorbents
Adsorption
32 Citations

Challenges of and Insights into Acid-Catalyzed Transformations of Sugars

Caratzoulas, S., Davis, M. E., Gorte, R. J., Gounder, R., Lobo, R. F., Nikolakis, V., Sandler, S. I., Snyder, M. A., Tsapatsis, M. & Vlachos, D. G. Oct 9 2014 In : Journal of Physical Chemistry C. 118, 40, p. 22815-22833 19 p.

Research output: Research - peer-reviewArticle

Lewis Acids
Sugars
Hydroxyl Radical
Acids
5-methyl-2-furfural
5 Citations
ethyl alcohol
isomers
aqueous solutions
Isomers
Ethanol
1 Citations

Crystallographic structure determination of MFI-zeolite nanosheets

Kumar, P., Varoon Agrawal, K., Tsapatsis, M. & Andre Mkhoyan, K. Aug 1 2014 In : Microscopy and Microanalysis. 20, 3, p. 390-391 2 p.

Research output: Research - peer-reviewArticle

Nanosheets