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2017
48 Citations

50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers

Schneiderman, D. K. & Hillmyer, M. A., May 23 2017, In : Macromolecules. 50, 10, p. 3733-3749 17 p.

Research output: Contribution to journalArticle

Polymers
Thermosets
Feedstocks
Recycling
Industry
7 Citations

Anhydride-Additive-Free Nickel-Catalyzed Deoxygenation of Carboxylic Acids to Olefins

John, A., Hillmyer, M. A. & Tolman, W. B., Feb 13 2017, In : Organometallics. 36, 3, p. 506-509 4 p.

Research output: Contribution to journalArticle

deoxygenation
Anhydrides
Reducing Agents
Alkenes
anhydrides
13 Citations

Conformational Asymmetry and Quasicrystal Approximants in Linear Diblock Copolymers

Schulze, M. W., Lewis, R. M., Lettow, J. H., Hickey, R. J., Gillard, T. M., Hillmyer, M. A. & Bates, F. S., May 16 2017, In : Physical Review Letters. 118, 20, 207801

Research output: Contribution to journalArticle

copolymers
asymmetry
minorities
x ray scattering
self consistent fields
4 Citations

Controlled synthesis of ABCA' tetrablock terpolymers

Radlauer, M. R., Fukuta, S., Matta, M. E. & Hillmyer, M. A., Aug 25 2017, In : Polymer (United Kingdom). 124, p. 60-67 8 p.

Research output: Contribution to journalArticle

Terpolymers
Polymers
Polystyrenes
Polyisoprenes
Molar mass
1 Citations

Degradable Thermosets Derived from an Isosorbide/Succinic Anhydride Monomer and Glycerol

Wilbon, P. A., Swartz, J. L., Meltzer, N. R., Brutman, J. P., Hillmyer, M. A. & Wissinger, J. E., Oct 2 2017, In : ACS Sustainable Chemistry and Engineering. 5, 10, p. 9185-9190 6 p.

Research output: Contribution to journalArticle

Isosorbide
Thermosets
Glycerol
Monomers
Polyethylene oxides
5 Citations

Direct Observation of Nanostructures during Aqueous Dissolution of Polymer/Drug Particles

Ricarte, R. G., Li, Z., Johnson, L. M., Ting, J. M., Reineke, T. M., Bates, F. S., Hillmyer, M. A. & Lodge, T. P., Apr 25 2017, In : Macromolecules. 50, 8, p. 3143-3152 10 p.

Research output: Contribution to journalArticle

hydroxypropylmethylcellulose acetate succinate
Nanostructures
Dispersions
Polymers
Dissolution
6 Citations

Effect of homopolymer in polymerization-induced microphase separation process

Park, J., Saba, S. A., Hillmyer, M. A., Kang, D. C. & Seo, M., Sep 22 2017, In : Polymer (United Kingdom). 126, p. 338-351 14 p.

Research output: Contribution to journalArticle

Microphase separation
Homopolymerization
Polymerization
Phase separation
Polymers
8 Citations

Enhanced Performance of Blended Polymer Excipients in Delivering a Hydrophobic Drug through the Synergistic Action of Micelles and HPMCAS

Li, Z., Johnson, L. M., Ricarte, R. G., Yao, L. J., Hillmyer, M. A., Bates, F. S. & Lodge, T. P., Mar 21 2017, In : Langmuir. 33, 11, p. 2837-2848 12 p.

Research output: Contribution to journalArticle

hydroxypropylmethylcellulose acetate succinate
Excipients
Micelles
acetates
Supersaturation
11 Citations

Impact of Polymer Excipient Molar Mass and End Groups on Hydrophobic Drug Solubility Enhancement

Johnson, L. M., Li, Z., LaBelle, A. J., Bates, F. S., Lodge, T. P. & Hillmyer, M. A., Feb 14 2017, In : Macromolecules. 50, 3, p. 1102-1112 11 p.

Research output: Contribution to journalArticle

Molar mass
Excipients
Polymers
Solubility
Dispersions
4 Citations

Intrinsically Hierarchical Nanoporous Polymers via Polymerization-Induced Microphase Separation

Larsen, M. B., Van Horn, J. D., Wu, F. & Hillmyer, M. A., Jun 13 2017, In : Macromolecules. 50, 11, p. 4363-4371 9 p.

Research output: Contribution to journalArticle

Microphase separation
Polymers
Monomers
Microporosity
Polymerization
8 Citations

Morphological consequences of frustration in ABC triblock polymers

Radlauer, M. R., Sinturel, C., Asai, Y., Arora, A., Bates, F. S., Dorfman, K. D. & Hillmyer, M. A., Jan 1 2017, In : Macromolecules. 50, 1, p. 446-458 13 p.

Research output: Contribution to journalArticle

Polymers
Thin films
Isoprene
Terpolymers
Styrene
1 Citations

Nanoporous Thermosets with Percolating Pores from Block Polymers Chemically Fixed above the Order-Disorder Transition

Vidil, T., Hampu, N. & Hillmyer, M. A., Oct 25 2017, In : ACS Central Science. 3, 10, p. 1114-1120 7 p.

Research output: Contribution to journalArticle

Order disorder transitions
Composite membranes
Thermosets
Ultrafiltration
X ray scattering
1 Citations

Oxidatively Stable Polyolefin Thermoplastics and Elastomers for Biomedical Applications

Wang, Y. & Hillmyer, M. A., Jun 20 2017, In : ACS Macro Letters. 6, 6, p. 613-618 6 p.

Research output: Contribution to journalArticle

Elastomers
Polyolefins
Thermoplastics
Ethylene
Urethane
4 Citations

POLYMER day: Outreach experiments for high school students

Ting, J. M., Ricarte, R. G., Schneiderman, D. K., Saba, S. A., Jiang, Y., Hillmyer, M. A., Bates, F. S., Reineke, T. M., Macosko, C. W. & Lodge, T. P., Nov 14 2017, In : Journal of Chemical Education. 94, 11, p. 1629-1638 10 p.

Research output: Contribution to journalArticle

Polymers
Students
experiment
school
student
12 Citations

Robust Polymer Electrolyte Membranes with High Ambient-Temperature Lithium-Ion Conductivity via Polymerization-Induced Microphase Separation

Chopade, S. A., Au, J. G., Li, Z., Schmidt, P. W., Hillmyer, M. A. & Lodge, T. P., May 3 2017, In : ACS Applied Materials and Interfaces. 9, 17, p. 14561-14565 5 p.

Research output: Contribution to journalArticle

Microphase separation
Lithium
Electrolytes
Polymers
Polymerization
7 Citations

Selective Decarbonylation of Fatty Acid Esters to Linear α-Olefins

John, A., Dereli, B., OrtunÌo, M. A., Johnson, H. E., Hillmyer, M. A., Cramer, C. J. & Tolman, W. B., Aug 14 2017, In : Organometallics. 36, 15, p. 2956-2964 9 p.

Research output: Contribution to journalArticle

Alkenes
fatty acids
alkenes
esters
Esters

Self-Supporting, Hydrophobic, Ionic Liquid-Based Reference Electrodes Prepared by Polymerization-Induced Microphase Separation

Chopade, S. A., Anderson, E. L., Schmidt, P. W., Lodge, T. P., Hillmyer, M. A. & Buhlmann, P., Oct 27 2017, In : ACS Sensors. 2, 10, p. 1498-1504 7 p.

Research output: Contribution to journalArticle

Ionic Liquids
Microphase separation
Ionic liquids
polymerization
Polymerization
12 Citations

Strong, Resilient, and Sustainable Aliphatic Polyester Thermoplastic Elastomers

Watts, A., Kurokawa, N. & Hillmyer, M. A., Jun 12 2017, In : Biomacromolecules. 18, 6, p. 1845-1854 10 p.

Research output: Contribution to journalArticle

Thermoplastic elastomers
Polyesters
Elastomers
Styrene
Molar mass
8 Citations

Structural effects on the reprocessability and stress relaxation of crosslinked polyhydroxyurethanes

Fortman, D. J., Brutman, J. P., Hillmyer, M. A. & Dichtel, W. R., Dec 5 2017, In : Journal of Applied Polymer Science. 134, 45, 44984

Research output: Contribution to journalArticle

Carbonates
Stress relaxation
Polymers
Compression molding
Thermosets
Ring opening polymerization
Hydrogenation
Ethylene
Methacrylates
Copolymers
14 Citations

The promise of plastics from plants

Hillmyer, M. A., Nov 17 2017, In : Science. 358, 6365, p. 868-870 3 p.

Research output: Contribution to journalShort survey

environmental technology
industrial production
polymer
plastic
30 Citations

Thermal processing of diblock copolymer melts mimics metallurgy

Kim, K., Schulze, M. W., Arora, A., Lewis, R. M., Hillmyer, M. A., Dorfman, K. D. & Bates, F. S., May 5 2017, In : Science. 356, 6337, p. 520-523 4 p.

Research output: Contribution to journalArticle

Metallurgy
Hot Temperature
Temperature
Transition Temperature
History

Tricontinuous Nanostructured Polymers via Polymerization-Induced Microphase Separation

Saba, S. A., Lee, B. & Hillmyer, M. A., Nov 21 2017, In : ACS Macro Letters. 6, 11, p. 1232-1236 5 p.

Research output: Contribution to journalArticle

divinyl benzene
Microphase separation
Block copolymers
Polymers
Polymerization
9 Citations

Tuning Mesoporosity in Cross-Linked Nanostructured Thermosets via Polymerization-Induced Microphase Separation

Schulze, M. W. & Hillmyer, M. A., Feb 14 2017, In : Macromolecules. 50, 3, p. 997-1007 11 p.

Research output: Contribution to journalArticle

divinyl benzene
Microphase separation
Thermosets
Macros
Tuning
2016
20 Citations

Acrylic Triblock Copolymers Incorporating Isosorbide for Pressure Sensitive Adhesives

Gallagher, J. J., Hillmyer, M. A. & Reineke, T. M., Jun 6 2016, In : ACS Sustainable Chemistry and Engineering. 4, 6, p. 3379-3387 9 p.

Research output: Contribution to journalArticle

Isosorbide
Block copolymers
Acrylics
Adhesives
polymerization
43 Citations

Aliphatic Polyester Block Polymer Design

Schneiderman, D. K. & Hillmyer, M. A., Apr 26 2016, In : Macromolecules. 49, 7, p. 2419-2428 10 p.

Research output: Contribution to journalArticle

Polyesters
Block copolymers
Polymerization
Molar mass
Enthalpy
15 Citations

Anhydrous Proton Conducting Polymer Electrolyte Membranes via Polymerization-Induced Microphase Separation

Chopade, S. A., So, S., Hillmyer, M. A. & Lodge, T. P., Mar 9 2016, In : ACS Applied Materials and Interfaces. 8, 9, p. 6200-6210 11 p.

Research output: Contribution to journalArticle

Microphase separation
Conducting polymers
Ionic Liquids
Electrolytes
Protons
6 Citations

Avoiding Errors in Electrochemical Measurements: Effect of Frit Material on the Performance of Reference Electrodes with Porous Frit Junctions

Mousavi, M. P. S., Saba, S. A., Anderson, E. L., Hillmyer, M. A. & Buhlmann, P., Sep 6 2016, In : Analytical Chemistry. 88, 17, p. 8706-8713 8 p.

Research output: Contribution to journalArticle

Glass
Electrodes
Electrostatics
Screening
Ions
5 Citations

Branched Diol Monomers from the Sequential Hydrogenation of Renewable Carboxylic Acids

Spanjers, C. S., Schneiderman, D. K., Wang, J. Z., Wang, J., Hillmyer, M. A., Zhang, K. & Dauenhauer, P. J., Oct 6 2016, In : ChemCatChem. 8, 19, p. 3031-3035 5 p.

Research output: Contribution to journalArticle

Lactones
Carboxylic Acids
Carboxylic acids
triols
carboxylic acids
23 Citations

Chemically Recyclable Biobased Polyurethanes

Schneiderman, D. K., Vanderlaan, M. E., Mannion, A. M., Panthani, T. R., Batiste, D. C., Wang, J. Z., Bates, F. S., Macosko, C. W. & Hillmyer, M. A., Apr 19 2016, In : ACS Macro Letters. 5, 4, p. 515-518 4 p.

Research output: Contribution to journalArticle

Polyurethanes
Petroleum
Foams
Recycling
Crude oil
22 Citations

Controlled chain walking for the synthesis of thermoplastic polyolefin elastomers: Synthesis, structure, and properties

O'Connor, K. S., Watts, A., Vaidya, T., LaPointe, A. M., Hillmyer, M. A. & Coates, G. W., Sep 27 2016, In : Macromolecules. 49, 18, p. 6743-6751 9 p.

Research output: Contribution to journalArticle

Elastomers
Polyolefins
Thermoplastics
Thermoplastic elastomers
Copolymers
3 Citations
Refuse compaction
Compatibilizers
Polymethyl methacrylates
Grafts
Polyethylenes
17 Citations

Design of Graft Block Polymer Thermoplastics

Zhang, J., Schneiderman, D. K., Li, T., Hillmyer, M. A. & Bates, F. S., Dec 13 2016, In : Macromolecules. 49, 23, p. 9108-9118 11 p.

Research output: Contribution to journalArticle

Graft copolymers
Grafts
Thermoplastics
Block copolymers
Crystallization
9 Citations

Diels-Alder Reactions of Furans with Itaconic Anhydride: Overcoming Unfavorable Thermodynamics

Pehere, A. D., Xu, S., Thompson, S. K., Hillmyer, M. A. & Hoye, T. R., Jun 3 2016, In : Organic Letters. 18, 11, p. 2584-2587 4 p.

Research output: Contribution to journalArticle

Furans
Diels-Alder reactions
Anhydrides
furans
Cycloaddition Reaction
6 Citations

Discussion on "aperiodic Copolymers"

Rowan, S. J., Barner-Kowollik, C., Klumperman, B., Gaspard, P., Grubbs, R. B., Hillmyer, M. A., Hutchings, L. R., Mahanthappa, M. K., Moatsou, D., O'Reilly, R. K., Ouchi, M., Sawamoto, M. & Lodge, T. P., Jan 19 2016, In : ACS Macro Letters. 5, 1, p. 1-3 3 p.

Research output: Contribution to journalReview article

Terminology
Copolymers
Macromolecules
Macros
Monomers
2 Citations

Filler-Reinforced Elastomers Based on Functional Polyolefin Prepolymers

Ren, N., Matta, M. E., Martinez, H., Walton, K. L., Munro, J. C., Schneiderman, D. K. & Hillmyer, M. A., Jun 1 2016, In : Industrial and Engineering Chemistry Research. 55, 21, p. 6106-6112 7 p.

Research output: Contribution to journalArticle

Elastomers
Polyolefins
Fillers
Soot
Mechanical properties
2 Citations

High surface area carbon black (BP-2000) as a reinforcing agent for poly[(−)-lactide]

Delgado, P. A., Brutman, J. P., Masica, K., Molde, J., Wood, B. & Hillmyer, M. A., Dec 5 2016, In : Journal of Applied Polymer Science. 133, 45, 43926

Research output: Contribution to journalArticle

Soot
Carbon black
Composite materials
Crystallization
Heat resistance
5 Citations

Lightweight micro-cellular plastics from polylactide/polyolefin hybrids

Xu, Y., Delgado, P., Todd, A. D., Loi, J., Saba, S. A., McEneany, R. J., Tower, T., Topolkaraev, V., Macosko, C. W. & Hillmyer, M. A., Oct 12 2016, In : Polymer (United Kingdom). 102, p. 73-83 11 p.

Research output: Contribution to journalArticle

Foamed plastics
Polyolefins
Polypropylenes
Elastomers
Homopolymerization
26 Citations

Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a Predictive Model for Cyclic Ester Polymerizations

Marlier, E. E., MacAranas, J. A., Marell, D. J., Dunbar, C. R., Johnson, M. A., DePorre, Y., Miranda, M. O., Neisen, B. D., Cramer, C. J., Hillmyer, M. A. & Tolman, W. B., Feb 5 2016, In : ACS Catalysis. 6, 2, p. 1215-1224 10 p.

Research output: Contribution to journalArticle

Ring opening polymerization
Esters
Polymerization
Carbon
Ligands
5 Citations

Multicompartment Micelles by Aqueous Self-Assembly of μ-A(BC)n Miktobrush Terpolymers

Moughton, A. O., Sagawa, T., Yin, L., Lodge, T. P. & Hillmyer, M. A., Nov 30 2016, In : ACS Omega. 1, 5, p. 1027-1033 7 p.

Research output: Contribution to journalArticle

Terpolymers
Micelles
Self assembly
Poly C
Molar mass
6 Citations

Nanoscale Concentration Quantification of Pharmaceutical Actives in Amorphous Polymer Matrices by Electron Energy-Loss Spectroscopy

Ricarte, R. G., Lodge, T. P. & Hillmyer, M. A., Jul 26 2016, In : Langmuir. 32, 29, p. 7411-7419 9 p.

Research output: Contribution to journalArticle

hydroxypropylmethylcellulose acetate succinate
Electron energy loss spectroscopy
Phenytoin
Polymer matrix
Dispersions
3 Citations

Organocatalytic Cationic Ring-Opening Polymerization of a Cyclic Hemiacetal Ester

Neitzel, A. E., Haversang, T. J. & Hillmyer, M. A., Jan 1 2016, In : Industrial and Engineering Chemistry Research. 55, 45, p. 11747-11755 9 p.

Research output: Contribution to journalArticle

Cationic polymerization
Ring opening polymerization
Molar mass
Esters
Monomers
6 Citations

Poly(cyclohexylethylene)-block-Poly(lactide) Oligomers for Ultrasmall Nanopatterning Using Atomic Layer Deposition

Yao, L., Oquendo, L. E., Schulze, M. W., Lewis, R. M., Gladfelter, W. L. & Hillmyer, M. A., Mar 30 2016, In : ACS Applied Materials and Interfaces. 8, 11, p. 7431-7439 9 p.

Research output: Contribution to journalArticle

Atomic layer deposition
Oligomers
Thin films
Anionic polymerization
Ring opening polymerization
1 Citations

Poly(urea ester): A family of biodegradable polymers with high melting temperatures

Tang, D., Chen, Z., Correa-Netto, F., Macosko, C. W., Hillmyer, M. A. & Zhang, G., Jan 1 2016, In : Journal of Polymer Science, Part A: Polymer Chemistry. 54, 24, p. 3795-3799 5 p.

Research output: Contribution to journalArticle

Biodegradable polymers
Urea
Melting point
Esters
Polymers
5 Citations

Polysilylether: A Degradable Polymer from Biorenewable Feedstocks

Cheng, C., Watts, A., Hillmyer, M. A. & Hartwig, J. F., Jan 1 2016, In : Angewandte Chemie - International Edition. 55, 39, p. 11872-11876 5 p.

Research output: Contribution to journalArticle

Feedstocks
Polymers
Molar mass
Monomers
Polymerization
13 Citations

Reactive Compatibilization of Poly(ethylene terephthalate) and High-Density Polyethylene Using Amino-Telechelic Polyethylene

Todd, A. D., McEneany, R. J., Topolkaraev, V. A., Macosko, C. W. & Hillmyer, M. A., Dec 13 2016, In : Macromolecules. 49, 23, p. 8988-8994 7 p.

Research output: Contribution to journalArticle

Polyethylene Terephthalates
Compatibilizers
Polyethylene
High density polyethylenes
Polyethylene terephthalates
12 Citations

Regioselective cross metathesis for block and heterotelechelic polymer synthesis

Radlauer, M. R., Matta, M. E. & Hillmyer, M. A., Oct 28 2016, In : Polymer Chemistry. 7, 40, p. 6269-6278 10 p.

Research output: Contribution to journalArticle

Ring opening polymerization
Polymerization
Polymers
Monomers
Molar mass
15 Citations

Renewable, Degradable, and Chemically Recyclable Cross-Linked Elastomers

Brutman, J. P., De Hoe, G. X., Schneiderman, D. K., Le, T. N. & Hillmyer, M. A., Oct 26 2016, In : Industrial and Engineering Chemistry Research. 55, 42, p. 11097-11106 10 p.

Research output: Contribution to journalArticle

Elastomers
Tensile strength
Degradation
Carbonates
Rubber
36 Citations

Tough and Sustainable Graft Block Copolymer Thermoplastics

Zhang, J., Li, T., Mannion, A. M., Schneiderman, D. K., Hillmyer, M. A. & Bates, F. S., Mar 15 2016, In : ACS Macro Letters. 5, 3, p. 407-412 6 p.

Research output: Contribution to journalArticle

Graft copolymers
Thermoplastics
Block copolymers
Microphase separation
Molar mass
7 Citations

"Uncontrolled" Preparation of Disperse Poly(lactide)-block-poly(styrene)-block-poly(lactide) for Nanopatterning Applications

Vanderlaan, M. E. & Hillmyer, M. A., Nov 8 2016, In : Macromolecules. 49, 21, p. 8031-8040 10 p.

Research output: Contribution to journalArticle

Styrene
X ray scattering
Self assembly
Block copolymers
Thin films