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  • Larry Que
2015

Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate Framework

Schreiber, R. E., Cohen, H., Leitus, G., Wolf, S. G., Zhou, A., Que, L. & Neumann, R., Jul 15 2015, In : Journal of the American Chemical Society. 137, 27, p. 8738-8748 11 p.

Research output: Contribution to journalArticle

19 Scopus citations
2012

Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: Proximity and spin-state reactivity rules

Mas-Ballesté, R., McDonald, A. R., Reed, D., Usharani, D., Schyman, P., Milko, P., Shaik, S. & Que, L., Sep 10 2012, In : Chemistry - A European Journal. 18, 37, p. 11747-11760 14 p.

Research output: Contribution to journalArticle

13 Scopus citations
2015

An unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway

Makris, T. M., Vu, V. V., Meier, K. K., Komor, A. J., Rivard, B. S., Münck, E., Que, L. & Lipscomb, J. D., Feb 4 2015, In : Journal of the American Chemical Society. 137, 4, p. 1608-1617 10 p.

Research output: Contribution to journalArticle

36 Scopus citations
2013

NO binding to Mn-substituted homoprotocatechuate 2,3-dioxygenase: Relationship to O2 reactivity

Hayden, J. A., Farquhar, E. R., Que, L., Lipscomb, J. D. & Hendrich, M. P., Oct 1 2013, In : Journal of Biological Inorganic Chemistry. 18, 7, p. 717-728 12 p.

Research output: Contribution to journalArticle

7 Scopus citations
2011

Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners

England, J., Farquhar, E. R., Guo, Y., Cranswick, M. A., Ray, K., Münck, E. & Que, L., Apr 4 2011, In : Inorganic Chemistry. 50, 7, p. 2885-2896 12 p.

Research output: Contribution to journalArticle

15 Scopus citations
2012

Evaluating the identity and diiron core transformations of a (μ-Oxo)diiron(III)complex supported by electron-rich tris(pyridyl-2-methyl) amine ligands

Do, L. H., Xue, G., Que, L. & Lippard, S. J., Feb 20 2012, In : Inorganic chemistry. 51, 4, p. 2393-2402 10 p.

Research output: Contribution to journalArticle

28 Scopus citations
2018
Open Access
16 Scopus citations

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

Rasheed, W., Draksharapu, A., Banerjee, S., Young, V. G., Fan, R., Guo, Y., Ozerov, M., Nehrkorn, J., Krzystek, J., Telser, J. & Que, L., Jul 20 2018, In : Angewandte Chemie - International Edition. 57, 30, p. 9387-9391 5 p.

Research output: Contribution to journalArticle

19 Scopus citations

Sc 3+ (or HClO 4 ) Activation of a Nonheme Fe III -OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene

Kal, S., Draksharapu, A. & Que, L., May 2 2018, In : Journal of the American Chemical Society. 140, 17, p. 5798-5804 7 p.

Research output: Contribution to journalArticle

Open Access
20 Scopus citations
2012

1H-ENDOR evidence for a hydrogen-bonding interaction that modulates the reactivity of a nonheme Fe IV=O unit

Shanmugam, M., Xue, G., Que, L. & Hoffman, B. M., Oct 1 2012, In : Inorganic chemistry. 51, 19, p. 10080-10082 3 p.

Research output: Contribution to journalArticle

9 Scopus citations
2019

NMR Reveals That a Highly Reactive Nonheme FeIV=O Complex Retains Its Six-Coordinate Geometry and S=1 State in Solution

Banerjee, S., Rasheed, W., Fan, R., Draksharapu, A., Oloo, W. N., Guo, Y. & Que, L., Jul 22 2019, In : Chemistry - A European Journal. 25, 41, p. 9608-9613 6 p.

Research output: Contribution to journalArticle

4 Scopus citations
2016

Nuclear Resonance Vibrational Spectroscopic Definition of Peroxy Intermediates in Nonheme Iron Sites

Sutherlin, K. D., Liu, L. V., Lee, Y. M., Kwak, Y., Yoda, Y., Saito, M., Kurokuzu, M., Kobayashi, Y., Seto, M., Que, L., Nam, W. & Solomon, E. I., Nov 2 2016, In : Journal of the American Chemical Society. 138, 43, p. 14294-14302 9 p.

Research output: Contribution to journalArticle

Open Access
3 Scopus citations

Modeling Non-Heme Iron Halogenases: High-Spin Oxoiron(IV)-Halide Complexes That Halogenate C-H Bonds

Puri, M., Biswas, A. N., Fan, R., Guo, Y. & Que, L., Mar 2 2016, In : Journal of the American Chemical Society. 138, 8, p. 2484-2487 4 p.

Research output: Contribution to journalArticle

33 Scopus citations
2012

Structural, EPR, and Mössbauer characterization of (μ-alkoxo)(μ-carboxylato)diiron(II,III) model complexes for the active sites of mixed-valent diiron enzymes

Li, F., Chakrabarti, M., Dong, Y., Kauffmann, K., Bominaar, E. L., Münck, E. & Que, L., Mar 5 2012, In : Inorganic Chemistry. 51, 5, p. 2917-2929 13 p.

Research output: Contribution to journalArticle

17 Scopus citations

π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity

Srnec, M., Wong, S. D., England, J., Que, L. & Solomon, E. I., Sep 4 2012, In : Proceedings of the National Academy of Sciences of the United States of America. 109, 36, p. 14326-14331 6 p.

Research output: Contribution to journalArticle

54 Scopus citations
2014

H2O2 activation with biomimetic non-haem iron complexes and AcOH: Connecting the g = 2.7 EPR signal with a visible chromophore

Makhlynets, O. V., Oloo, W. N., Moroz, Y. S., Belaya, I. G., Palluccio, T. D., Filatov, A. S., Müller, P., Cranswick, M. A., Que, L. & Rybak-Akimova, E. V., Jan 21 2014, In : Chemical Communications. 50, 6, p. 645-648 4 p.

Research output: Contribution to journalArticle

39 Scopus citations
2019

Octahedral iron(iv)-tosylimido complexes exhibiting single electron-oxidation reactivity

Sabenya, G., Gamba, I., Gómez, L., Clémancey, M., Frisch, J. R., Klinker, E. J., Blondin, G., Torelli, S., Que, L., Martin-Diaconescu, V., Latour, J. M., Lloret-Fillol, J. & Costas, M., 2019, In : Chemical Science. 10, 41, p. 9513-9529 17 p.

Research output: Contribution to journalArticle

Open Access
2 Scopus citations
2015
17 Scopus citations
2019

A Mn II Mn III -Peroxide Complex Capable of Aldehyde Deformylation

Magherusan, A. M., Kal, S., Nelis, D. N., Doyle, L. M., Farquhar, E. R., Que, L. & McDonald, A. R., Apr 16 2019, In : Angewandte Chemie - International Edition. 58, 17, p. 5718-5722 5 p.

Research output: Contribution to journalArticle

2 Scopus citations
2017

Oxoiron(IV) Tetramethylcyclam Complexes with Axial Carboxylate Ligands: Effect of Tethering the Carboxylate on Reactivity

Bigelow, J. O., England, J., Klein, J. E. M. N., Farquhar, E. R., Frisch, J. R., Martinho, M., Mandal, D., Münck, E., Shaik, S. & Que, L., Mar 20 2017, In : Inorganic chemistry. 56, 6, p. 3287-3301 15 p.

Research output: Contribution to journalArticle

12 Scopus citations
2012

Editorial overview

Armstrong, F. & Que, L., Apr 1 2012, In : Current Opinion in Chemical Biology. 16, 1-2, p. 1-2 2 p.

Research output: Contribution to journalEditorial

2019

Spectroscopic and Reactivity Comparisons between Nonheme Oxoiron(IV) and Oxoiron(V) Species Bearing the Same Ancillary Ligand

Dantignana, V., Serrano-Plana, J., Draksharapu, A., Magallón, C., Banerjee, S., Fan, R., Gamba, I., Guo, Y., Que, L., Costas, M. & Company, A., Sep 25 2019, In : Journal of the American Chemical Society. 141, 38, p. 15078-15091 14 p.

Research output: Contribution to journalArticle

Open Access
5 Scopus citations
2015

Synthetic models of 2-oxoglutarate-dependent oxygenases

Allpress, C. J., Kleespies, S. T. & Que, L., Jan 1 2015, 2-Oxoglutarate-Dependent Oxygenases. Hausinger, R. P. & Schofield, C. J. (eds.). 3 ed. Royal Society of Chemistry, p. 123-148 26 p. (RSC Metallobiology; vol. 2015-January, no. 3).

Research output: Chapter in Book/Report/Conference proceedingChapter

2 Scopus citations
2013

Rate-determining water-assisted O-O bond cleavage of an Fe III-OOH intermediate in a bio-inspired nonheme iron-catalyzed oxidation

Oloo, W. N., Fielding, A. J. & Que, L., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6438-6441 4 p.

Research output: Contribution to journalArticle

76 Scopus citations

Oxidation of water by a nonhaem diiron(iv) complex via proton-coupled electron transfer

Wang, D. & Que, L., Oct 22 2013, In : Chemical Communications. 49, 91, p. 10682-10684 3 p.

Research output: Contribution to journalArticle

18 Scopus citations
2020

Bio-inspired Nonheme Iron Oxidation Catalysis: Involvement of Oxoiron(V) Oxidants in Cleaving Strong C−H Bonds

Kal, S., Xu, S. & Que, L., May 4 2020, In : Angewandte Chemie - International Edition. 59, 19, p. 7332-7349 18 p.

Research output: Contribution to journalReview article

5 Scopus citations
2011

Modeling the cis-Oxo-Labile binding site motif of non-heme iron oxygenases: Water exchange and oxidation reactivity of a non-heme iron(IV)-Oxo compound bearing a tripodal tetradentate ligand

Company, A., Prat, I., Frisch, J. R., Mas-Ballesté, D. R., Güell, M., Juhász, G., Ribas, X., Münck, D. E., Luis, J. M., Que, L. & Costas, M., Feb 1 2011, In : Chemistry - A European Journal. 17, 5, p. 1622-1634 13 p.

Research output: Contribution to journalArticle

82 Scopus citations
2013

Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate

Li, F., Van Heuvelen, K. M., Meier, K. K., Münck, E. & Que, L., Jul 17 2013, In : Journal of the American Chemical Society. 135, 28, p. 10198-10201 4 p.

Research output: Contribution to journalArticle

73 Scopus citations
2018

Diiron monooxygenases in natural product biosynthesis

Komor, A. J., Jasniewski, A. J., Que, L. & Lipscomb, J. D., Jul 2018, In : Natural Product Reports. 35, 7, p. 646-659 14 p.

Research output: Contribution to journalReview article

Open Access
10 Scopus citations
2019

Trapping iron(III)-Oxo species at the boundary of the "oxo Wall": Insights into the nature of the Fe(III)-O bond

Andris, E., Navrátil, R., Jašík, J., Puri, M., Costas, M., Que, L. & Roithovaá, J., Oct 30 2019, In : Journal of the American Chemical Society. 140, 43, p. 14391-14400 10 p.

Research output: Contribution to journalArticle

15 Scopus citations
2014

Note from the SBIC President

Que, L., Jan 1 2014, In : Journal of Biological Inorganic Chemistry. 19, 1, p. 125-126 2 p.

Research output: Contribution to journalEditorial

2012

Characterization of an O 2 adduct of an active cobalt-substituted extradiol-cleaving catechol dioxygenase

Fielding, A. J., Lipscomb, J. D. & Que, L., Jan 18 2012, In : Journal of the American Chemical Society. 134, 2, p. 796-799 4 p.

Research output: Contribution to journalArticle

32 Scopus citations
2013

Factors affecting the carboxylate shift upon formation of nonheme diiron-O2 adducts

Frisch, J. R., McDonnell, R., Rybak-Akimova, E. V. & Que, L., Mar 11 2013, In : Inorganic chemistry. 52, 5, p. 2627-2636 10 p.

Research output: Contribution to journalArticle

10 Scopus citations
2017

Facile and Reversible Formation of Iron(III)–Oxo–Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III)

Draksharapu, A., Rasheed, W., Klein, J. E. M. N. & Que, L., Jan 1 2017, In : Angewandte Chemie - International Edition. 56, 31, p. 9091-9095 5 p.

Research output: Contribution to journalArticle

Open Access
15 Scopus citations
2015

Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(iv) complexes

Ye, S., Xue, G., Krivokapic, I., Petrenko, T., Bill, E., Que, L. & Neese, F., May 1 2015, In : Chemical Science. 6, 5, p. 2909-2921 13 p.

Research output: Contribution to journalArticle

18 Scopus citations
2014

Note from the SBIC President

Que, L., Jun 1 2014, In : Journal of Biological Inorganic Chemistry. 19, 4-5, 1 p.

Research output: Contribution to journalEditorial

2015

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

De Sousa, D. P., Bigelow, J. O., Sundberg, J., Que, L. & McKenzie, C. J., Feb 18 2015, In : Chemical Communications. 51, 14, p. 2802-2805 4 p.

Research output: Contribution to journalArticle

13 Scopus citations
2011

A hyperactive cobalt-substituted extradiol-cleaving catechol dioxygenase

Fielding, A. J., Kovaleva, E. G., Farquhar, E. R., Lipscomb, J. D. & Que, L., Feb 1 2011, In : Journal of Biological Inorganic Chemistry. 16, 2, p. 341-355 15 p.

Research output: Contribution to journalArticle

60 Scopus citations
2019
6 Scopus citations
2011

Characterization of a high-spin non-heme FeIII-OOH intermediate and its quantitative conversion to an FeIV=O complex

Li, F., Meier, K. K., Cranswick, M. A., Chakrabarti, M., Van Heuvelen, K. M., Münck, E. & Que, L., May 18 2011, In : Journal of the American Chemical Society. 133, 19, p. 7256-7259 4 p.

Research output: Contribution to journalArticle

80 Scopus citations
2017
Open Access
23 Scopus citations
2015

Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes

Puri, M. & Que, L., Jul 15 2015, In : Accounts of Chemical Research. 48, 8, p. 2443-2452 10 p.

Research output: Contribution to journalArticle

119 Scopus citations

Oxoiron(IV) Complex of the Ethylene-Bridged Dialkylcyclam Ligand Me2EBC

England, J., Prakash, J., Cranswick, M. A., Mandal, D., Guo, Y., Münck, E., Shaik, S. & Que, L., Aug 17 2015, In : Inorganic Chemistry. 54, 16, p. 7828-7839 12 p.

Research output: Contribution to journalArticle

14 Scopus citations
2019

Facile Conversion of syn-[Fe IV (O)(TMC)] 2+ into the anti Isomer via Meunier's Oxo–Hydroxo Tautomerism Mechanism

Prakash, J., Sheng, Y., Draksharapu, A., Klein, J. E. M. N., Cramer, C. J. & Que, L., Feb 11 2019, In : Angewandte Chemie - International Edition. 58, 7, p. 1995-1999 5 p.

Research output: Contribution to journalArticle

Open Access
1 Scopus citations
2018

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-Oxo Intermediate

Fan, R., Serrano-Plana, J., Oloo, W. N., Draksharapu, A., Delgado-Pinar, E., Company, A., Martin-Diaconescu, V., Borrell, M., Lloret-Fillol, J., García-España, E., Guo, Y., Bominaar, E. L., Que, L., Costas, M. & Münck, E., Mar 21 2018, In : Journal of the American Chemical Society. 140, 11, p. 3916-3928 13 p.

Research output: Contribution to journalArticle

31 Scopus citations
2013

Nonheme iron oxidant formed in the presence of H2O2 and acetic acid is the cyclic ferric peracetate complex, not a perferryloxo complex

Wang, Y., Janardanan, D., Usharani, D., Han, K., Que, L. & Shaik, S., Jan 1 2013, In : ACS Catalysis. 3, 6, p. 1334-1341 8 p.

Research output: Contribution to journalArticle

74 Scopus citations
2017
63 Scopus citations
2011

In vivo self-hydroxylation of an iron-substituted manganese-dependent extradiol cleaving catechol dioxygenase

Farquhar, E. R., Emerson, J. P., Koehntop, K. D., Reynolds, M. F., Trmčić, M. & Que, L., Apr 1 2011, In : Journal of Biological Inorganic Chemistry. 16, 4, p. 589-597 9 p.

Research output: Contribution to journalArticle

3 Scopus citations
2015

Bioinspired Nonheme Iron Catalysts for C-H and C=C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

Oloo, W. N. & Que, L., Aug 17 2015, In : Accounts of Chemical Research. 48, 9, p. 2612-2621 10 p.

Research output: Contribution to journalArticle

192 Scopus citations
2016

X-ray absorption spectroscopic characterization of the diferric-peroxo intermediate of human deoxyhypusine hydroxylase in the presence of its substrate eIF5a

Jasniewski, A. J., Engstrom, L. M., Vu, V. V., Park, M. H. & Que, L., Sep 1 2016, In : Journal of Biological Inorganic Chemistry. 21, 5-6, p. 605-618 14 p.

Research output: Contribution to journalArticle

Open Access
10 Scopus citations