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  • Larry Que
2016

Modeling Non-Heme Iron Halogenases: High-Spin Oxoiron(IV)-Halide Complexes That Halogenate C-H Bonds

Puri, M., Biswas, A. N., Fan, R., Guo, Y. & Que, L., Mar 2 2016, In : Journal of the American Chemical Society. 138, 8, p. 2484-2487 4 p.

Research output: Contribution to journalArticle

33 Scopus citations
2013

Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate

Li, F., Van Heuvelen, K. M., Meier, K. K., Münck, E. & Que, L., Jul 17 2013, In : Journal of the American Chemical Society. 135, 28, p. 10198-10201 4 p.

Research output: Contribution to journalArticle

73 Scopus citations

Hydrogen-bonding effects on the reactivity of [X-FeIII-O-Fe IV=O] (X = OH, F) complexes toward C-H bond cleavage

Xue, G., Geng, C., Ye, S., Fiedler, A. T., Neese, F. & Que, L., Apr 1 2013, In : Inorganic chemistry. 52, 7, p. 3976-3984 9 p.

Research output: Contribution to journalArticle

23 Scopus citations
2012

Characterization of an O 2 adduct of an active cobalt-substituted extradiol-cleaving catechol dioxygenase

Fielding, A. J., Lipscomb, J. D. & Que, L., Jan 18 2012, In : Journal of the American Chemical Society. 134, 2, p. 796-799 4 p.

Research output: Contribution to journalArticle

32 Scopus citations
2017

Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand

Ching, W. M., Zhou, A., Klein, J. E. M. N., Fan, R., Knizia, G., Cramer, C. J., Guo, Y. & Que, L., Jan 1 2017, In : Inorganic chemistry. 56, 18, p. 11129-11140 12 p.

Research output: Contribution to journalArticle

14 Scopus citations
2011

Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) Complex: Evidence for an iron(IV)-oxo-hydroxo oxidant from O 2

Paria, S., Que, L. & Paine, T. K., Nov 18 2011, In : Angewandte Chemie - International Edition. 50, 47, p. 11129-11132 4 p.

Research output: Contribution to journalArticle

46 Scopus citations
2012

Protonation of a peroxodiiron(III) complex and conversion to a diiron(III/IV) intermediate: Implications for proton-assisted O-O bond cleavage in nonheme diiron enzymes

Cranswick, M. A., Meier, K. K., Shan, X., Stubna, A., Kaizer, J., Mehn, M. P., Münck, E. & Que, L., Oct 1 2012, In : Inorganic Chemistry. 51, 19, p. 10417-10426 10 p.

Research output: Contribution to journalArticle

33 Scopus citations
2015

Synthetic models of 2-oxoglutarate-dependent oxygenases

Allpress, C. J., Kleespies, S. T. & Que, L., Jan 1 2015, 2-Oxoglutarate-Dependent Oxygenases. Hausinger, R. P. & Schofield, C. J. (eds.). 3 ed. Royal Society of Chemistry, p. 123-148 26 p. (RSC Metallobiology; vol. 2015-January, no. 3).

Research output: Chapter in Book/Report/Conference proceedingChapter

2 Scopus citations
2011

Letter from the editor: Letter from the Editor

Que, L., Jan 2011, In : Journal of Biological Inorganic Chemistry. 16, 1, p. 1 1 p.

Research output: Contribution to journalEditorial

2014

Note from the SBIC President

Que, L., Jun 1 2014, In : Journal of Biological Inorganic Chemistry. 19, 4-5, 1 p.

Research output: Contribution to journalEditorial

2016

HFEPR and Computational Studies on the Electronic Structure of a High-Spin Oxidoiron(IV) Complex in Solution

Bucinsky, L., Rohde, G. T., Que, L., Ozarowski, A., Krzystek, J., Breza, M. & Telser, J., May 2 2016, In : Inorganic Chemistry. 55, 8, p. 3933-3945 13 p.

Research output: Contribution to journalArticle

5 Scopus citations
2012

Evidence for a dual role of an active site histidine in α-Amino-β-carboxymuconate-ε-semialdehyde decarboxylase

Huo, L., Fielding, A. J., Chen, Y., Li, T., Iwaki, H., Hosler, J. P., Chen, L., Hasegawa, Y., Que, L. & Liu, A., Jul 24 2012, In : Biochemistry. 51, 29, p. 5811-5821 11 p.

Research output: Contribution to journalArticle

11 Scopus citations
2016

A Carboxylate Shift Regulates Dioxygen Activation by the Diiron Nonheme β-Hydroxylase CmlA upon Binding of a Substrate-Loaded Nonribosomal Peptide Synthetase

Jasniewski, A. J., Knoot, C., Lipscomb, J. D. & Que, L., Oct 18 2016, In : Biochemistry. 55, 41, p. 5818-5831 14 p.

Research output: Contribution to journalArticle

Open Access
5 Scopus citations
2017

Hydrogen-Atom Transfer Oxidation with H2O2 Catalyzed by [FeII(1,2-bis(2,2′-bipyridyl-6-yl)ethane(H2O)2]2+: Likely Involvement of a (μ-Hydroxo)(μ-1,2-peroxo)diiron(III) Intermediate

Khenkin, A. M., Vedichi, M., Shimon, L. J. W., Cranswick, M. A., Klein, J. E. M. N., Que, L. & Neumann, R., Nov 2017, In : Israel Journal of Chemistry. 57, 10, p. 990-998 9 p.

Research output: Contribution to journalArticle

Open Access
2016

Spectroscopic and Theoretical Study of Spin-Dependent Electron Transfer in an Iron(III) Superoxo Complex

Stout, H. D., Kleespies, S. T., Chiang, C. W., Lee, W. Z., Que, L., Münck, E. & Bominaar, E. L., Jun 6 2016, In : Inorganic Chemistry. 55, 11, p. 5215-5226 12 p.

Research output: Contribution to journalArticle

7 Scopus citations
2013

Hydrocarbon Oxidations Catalyzed by Bio-Inspired Nonheme Iron and Copper Catalysts

Oloo, W. N. & Que, L., Aug 1 2013, Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications. Elsevier Ltd, Vol. 6. p. 763-778 16 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

11 Scopus citations
2012

A mononuclear carboxylate-rich oxoiron(iv) complex: A structural and functional mimic of TauD intermediate 'J'

McDonald, A. R., Guo, Y., Vu, V. V., Bominaar, E. L., Münck, E. & Que, L., May 1 2012, In : Chemical Science. 3, 5, p. 1680-1693 14 p.

Research output: Contribution to journalArticle

32 Scopus citations
2020

Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV 2(μ-O)2 Core

Banerjee, S., Draksharapu, A., Crossland, P. M., Fan, R., Guo, Y., Swart, M. & Que, L., Jan 1 2020, (Accepted/In press) In : Journal of the American Chemical Society.

Research output: Contribution to journalArticle

2015

Characterization of a heterobimetallic nonheme Fe(III)-O-Cr(III) species formed by O2 activation

Zhou, A., Kleespies, S. T., Van Heuvelen, K. M. & Que, L., Aug 5 2015, In : Chemical Communications. 51, 76, p. 14326-14329 4 p.

Research output: Contribution to journalArticle

9 Scopus citations
2013

Oxidation of water by a nonhaem diiron(iv) complex via proton-coupled electron transfer

Wang, D. & Que, L., Oct 22 2013, In : Chemical Communications. 49, 91, p. 10682-10684 3 p.

Research output: Contribution to journalArticle

18 Scopus citations
2012

Evaluating the identity and diiron core transformations of a (μ-Oxo)diiron(III)complex supported by electron-rich tris(pyridyl-2-methyl) amine ligands

Do, L. H., Xue, G., Que, L. & Lippard, S. J., Feb 20 2012, In : Inorganic chemistry. 51, 4, p. 2393-2402 10 p.

Research output: Contribution to journalArticle

28 Scopus citations
2011

Active-site structure of a β-hydroxylase in antibiotic biosynthesis

Vu, V. V., Makris, T. M., Lipscomb, J. D. & Que, L., May 11 2011, In : Journal of the American Chemical Society. 133, 18, p. 6938-6941 4 p.

Research output: Contribution to journalArticle

14 Scopus citations
2016

Nuclear Resonance Vibrational Spectroscopic Definition of Peroxy Intermediates in Nonheme Iron Sites

Sutherlin, K. D., Liu, L. V., Lee, Y. M., Kwak, Y., Yoda, Y., Saito, M., Kurokuzu, M., Kobayashi, Y., Seto, M., Que, L., Nam, W. & Solomon, E. I., Nov 2 2016, In : Journal of the American Chemical Society. 138, 43, p. 14294-14302 9 p.

Research output: Contribution to journalArticle

Open Access
3 Scopus citations
2011

Iron-catalyzed olefin epoxidation and Cis-dihydroxylation by tetraalkylcyclam complexes: The importance of Cis-labile sites

Feng, Y., England, J. & Que, L., Sep 2 2011, In : ACS Catalysis. 1, 9, p. 1035-1042 8 p.

Research output: Contribution to journalArticle

55 Scopus citations
2015

Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes

Puri, M. & Que, L., Jul 15 2015, In : Accounts of Chemical Research. 48, 8, p. 2443-2452 10 p.

Research output: Contribution to journalArticle

119 Scopus citations
2019

Trapping iron(III)-Oxo species at the boundary of the "oxo Wall": Insights into the nature of the Fe(III)-O bond

Andris, E., Navrátil, R., Jašík, J., Puri, M., Costas, M., Que, L. & Roithovaá, J., Oct 30 2019, In : Journal of the American Chemical Society. 140, 43, p. 14391-14400 10 p.

Research output: Contribution to journalArticle

15 Scopus citations
2011

Characterization of a high-spin non-heme FeIII-OOH intermediate and its quantitative conversion to an FeIV=O complex

Li, F., Meier, K. K., Cranswick, M. A., Chakrabarti, M., Van Heuvelen, K. M., Münck, E. & Que, L., May 18 2011, In : Journal of the American Chemical Society. 133, 19, p. 7256-7259 4 p.

Research output: Contribution to journalArticle

80 Scopus citations
2014

H2O2 activation with biomimetic non-haem iron complexes and AcOH: Connecting the g = 2.7 EPR signal with a visible chromophore

Makhlynets, O. V., Oloo, W. N., Moroz, Y. S., Belaya, I. G., Palluccio, T. D., Filatov, A. S., Müller, P., Cranswick, M. A., Que, L. & Rybak-Akimova, E. V., Jan 21 2014, In : Chemical Communications. 50, 6, p. 645-648 4 p.

Research output: Contribution to journalArticle

39 Scopus citations
2012

One-electron oxidation of an oxoiron(IV) complex to form an [O=Fe V=NR]+ center

Van Heuvelen, K. M., Fiedler, A. T., Shan, X., De Hont, R. F., Meier, K. K., Bominaar, E. L., Mun̈ck, E. & Que, L., Jul 24 2012, In : Proceedings of the National Academy of Sciences of the United States of America. 109, 30, p. 11933-11938 6 p.

Research output: Contribution to journalArticle

62 Scopus citations
2019

Octahedral iron(iv)-tosylimido complexes exhibiting single electron-oxidation reactivity

Sabenya, G., Gamba, I., Gómez, L., Clémancey, M., Frisch, J. R., Klinker, E. J., Blondin, G., Torelli, S., Que, L., Martin-Diaconescu, V., Latour, J. M., Lloret-Fillol, J. & Costas, M., 2019, In : Chemical Science. 10, 41, p. 9513-9529 17 p.

Research output: Contribution to journalArticle

Open Access
2 Scopus citations
2011

Nuclear resonance vibrational spectroscopy on the FeIV=O S=2 non-heme site in TMG3tren: Experimentally calibrated insights into reactivity

Wong, S. D., Bell, C. B., Liu, L. V., Kwak, Y., England, J., Alp, E. E., Zhao, J., Que, L. & Solomon, E. I., Mar 28 2011, In : Angewandte Chemie - International Edition. 50, 14, p. 3215-3218 4 p.

Research output: Contribution to journalArticle

49 Scopus citations
2014
2018

Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes

Jasniewski, A. J. & Que, L., Mar 14 2018, In : Chemical Reviews. 118, 5, p. 2554-2592 39 p.

Research output: Contribution to journalArticle

Open Access
95 Scopus citations

Mimicking Class I b Mn2-Ribonucleotide Reductase: A MnII2 Complex and Its Reaction with Superoxide

Magherusan, A. M., Zhou, A., Farquhar, E. R., García-Melchor, M., Twamley, B., Que, L. & McDonald, A. R., Jan 22 2018, In : Angewandte Chemie - International Edition. 57, 4, p. 918-922 5 p.

Research output: Contribution to journalArticle

Open Access
9 Scopus citations
2012

π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity

Srnec, M., Wong, S. D., England, J., Que, L. & Solomon, E. I., Sep 4 2012, In : Proceedings of the National Academy of Sciences of the United States of America. 109, 36, p. 14326-14331 6 p.

Research output: Contribution to journalArticle

54 Scopus citations
2020

Bio-inspired Nonheme Iron Oxidation Catalysis: Involvement of Oxoiron(V) Oxidants in Cleaving Strong C−H Bonds

Kal, S., Xu, S. & Que, L., May 4 2020, In : Angewandte Chemie - International Edition. 59, 19, p. 7332-7349 18 p.

Research output: Contribution to journalReview article

5 Scopus citations
2015

Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation

Codolà, Z., Gómez, L., Kleespies, S. T., Que, L., Costas, M. & Lloret-Fillol, J., Jan 22 2015, In : Nature communications. 6, 5865.

Research output: Contribution to journalArticle

71 Scopus citations
2011

Theoretical study of the mechanism of oxoiron(IV) formation from H 2O2 and a nonheme iron(II) complex: O-O cleavage involving proton-coupled electron transfer

Hirao, H., Li, F., Que, L. & Morokuma, K., Jul 18 2011, In : Inorganic Chemistry. 50, 14, p. 6637-6648 12 p.

Research output: Contribution to journalArticle

38 Scopus citations
2017
7 Scopus citations
2011

A hyperactive cobalt-substituted extradiol-cleaving catechol dioxygenase

Fielding, A. J., Kovaleva, E. G., Farquhar, E. R., Lipscomb, J. D. & Que, L., Feb 1 2011, In : Journal of Biological Inorganic Chemistry. 16, 2, p. 341-355 15 p.

Research output: Contribution to journalArticle

60 Scopus citations

In vivo self-hydroxylation of an iron-substituted manganese-dependent extradiol cleaving catechol dioxygenase

Farquhar, E. R., Emerson, J. P., Koehntop, K. D., Reynolds, M. F., Trmčić, M. & Que, L., Apr 1 2011, In : Journal of Biological Inorganic Chemistry. 16, 4, p. 589-597 9 p.

Research output: Contribution to journalArticle

3 Scopus citations

Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners

England, J., Farquhar, E. R., Guo, Y., Cranswick, M. A., Ray, K., Münck, E. & Que, L., Apr 4 2011, In : Inorganic Chemistry. 50, 7, p. 2885-2896 12 p.

Research output: Contribution to journalArticle

15 Scopus citations
2014

An ultra-stable oxoiron(iv) complex and its blue conjugate base

England, J., Bigelow, J. O., Van Heuvelen, K. M., Farquhar, E. R., Martinho, M., Meier, K. K., Frisch, J. R., Münck, E. & Que, L., Mar 2014, In : Chemical Science. 5, 3, p. 1204-1215 12 p.

Research output: Contribution to journalArticle

33 Scopus citations
2012

Structural, EPR, and Mössbauer characterization of (μ-alkoxo)(μ-carboxylato)diiron(II,III) model complexes for the active sites of mixed-valent diiron enzymes

Li, F., Chakrabarti, M., Dong, Y., Kauffmann, K., Bominaar, E. L., Münck, E. & Que, L., Mar 5 2012, In : Inorganic Chemistry. 51, 5, p. 2917-2929 13 p.

Research output: Contribution to journalArticle

17 Scopus citations

Characterization of a thiolato iron(III) peroxy dianion complex

McDonald, A. R., Van Heuvelen, K. M., Guo, Y., Li, F., Bominaar, E. L., Münck, E. & Que, L., Sep 3 2012, In : Angewandte Chemie - International Edition. 51, 36, p. 9132-9136 5 p.

Research output: Contribution to journalArticle

13 Scopus citations
2015

C-H bond cleavage by bioinspired nonheme oxoiron(IV) complexes, including hydroxylation of n-butane

Kleespies, S. T., Oloo, W. N., Mukherjee, A. & Que, L., Jun 1 2015, In : Inorganic Chemistry. 54, 11, p. 5053-5064 12 p.

Research output: Contribution to journalReview article

31 Scopus citations
2012

Editorial overview

Armstrong, F. & Que, L., Apr 1 2012, In : Current opinion in chemical biology. 16, 1-2, p. 1-2 2 p.

Research output: Contribution to journalEditorial

1 Scopus citations
2015

An unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway

Makris, T. M., Vu, V. V., Meier, K. K., Komor, A. J., Rivard, B. S., Münck, E., Que, L. & Lipscomb, J. D., Feb 4 2015, In : Journal of the American Chemical Society. 137, 4, p. 1608-1617 10 p.

Research output: Contribution to journalArticle

36 Scopus citations
2018

Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases

Zhou, A., Crossland, P. M., Draksharapu, A., Jasniewski, A. J., Kleespies, S. T. & Que, L., Jan 1 2018, In : Journal of Biological Inorganic Chemistry. 23, 1, p. 155-165 11 p.

Research output: Contribution to journalArticle

Open Access
3 Scopus citations