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Author

  • Larry Que
2011

Active-site structure of a β-hydroxylase in antibiotic biosynthesis

Vu, V. V., Makris, T. M., Lipscomb, J. D. & Que, L., May 11 2011, In : Journal of the American Chemical Society. 133, 18, p. 6938-6941 4 p.

Research output: Contribution to journalArticle

14 Scopus citations

A hyperactive cobalt-substituted extradiol-cleaving catechol dioxygenase

Fielding, A. J., Kovaleva, E. G., Farquhar, E. R., Lipscomb, J. D. & Que, L., Feb 1 2011, In : Journal of Biological Inorganic Chemistry. 16, 2, p. 341-355 15 p.

Research output: Contribution to journalArticle

60 Scopus citations

A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site

England, J., Guo, Y., Van Heuvelen, K. M., Cranswick, M. A., Rohde, G. T., Bominaar, E. L., Münck, E. & Que, L., Aug 10 2011, In : Journal of the American Chemical Society. 133, 31, p. 11880-11883 4 p.

Research output: Contribution to journalArticle

77 Scopus citations

Characterization of a high-spin non-heme FeIII-OOH intermediate and its quantitative conversion to an FeIV=O complex

Li, F., Meier, K. K., Cranswick, M. A., Chakrabarti, M., Van Heuvelen, K. M., Münck, E. & Que, L., May 18 2011, In : Journal of the American Chemical Society. 133, 19, p. 7256-7259 4 p.

Research output: Contribution to journalArticle

79 Scopus citations

Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners

England, J., Farquhar, E. R., Guo, Y., Cranswick, M. A., Ray, K., Münck, E. & Que, L., Apr 4 2011, In : Inorganic Chemistry. 50, 7, p. 2885-2896 12 p.

Research output: Contribution to journalArticle

15 Scopus citations

In vivo self-hydroxylation of an iron-substituted manganese-dependent extradiol cleaving catechol dioxygenase

Farquhar, E. R., Emerson, J. P., Koehntop, K. D., Reynolds, M. F., Trmčić, M. & Que, L., Apr 1 2011, In : Journal of Biological Inorganic Chemistry. 16, 4, p. 589-597 9 p.

Research output: Contribution to journalArticle

3 Scopus citations

Iron-catalyzed olefin epoxidation and Cis-dihydroxylation by tetraalkylcyclam complexes: The importance of Cis-labile sites

Feng, Y., England, J. & Que, L., Sep 2 2011, In : ACS Catalysis. 1, 9, p. 1035-1042 8 p.

Research output: Contribution to journalArticle

55 Scopus citations

Iron-oxo complexes: Elusive iron(V) species identified

McDonald, A. R. & Que, L., Oct 1 2011, In : Nature Chemistry. 3, 10, p. 761-762 2 p.

Research output: Contribution to journalShort survey

22 Scopus citations

Letter from the editor: Letter from the Editor

Que, L., Jan 2011, In : Journal of Biological Inorganic Chemistry. 16, 1, p. 1 1 p.

Research output: Contribution to journalEditorial

Modeling the cis-Oxo-Labile binding site motif of non-heme iron oxygenases: Water exchange and oxidation reactivity of a non-heme iron(IV)-Oxo compound bearing a tripodal tetradentate ligand

Company, A., Prat, I., Frisch, J. R., Mas-Ballesté, D. R., Güell, M., Juhász, G., Ribas, X., Münck, D. E., Luis, J. M., Que, L. & Costas, M., Feb 1 2011, In : Chemistry - A European Journal. 17, 5, p. 1622-1634 13 p.

Research output: Contribution to journalArticle

82 Scopus citations

Nuclear resonance vibrational spectroscopy on the FeIV=O S=2 non-heme site in TMG3tren: Experimentally calibrated insights into reactivity

Wong, S. D., Bell, C. B., Liu, L. V., Kwak, Y., England, J., Alp, E. E., Zhao, J., Que, L. & Solomon, E. I., Mar 28 2011, In : Angewandte Chemie - International Edition. 50, 14, p. 3215-3218 4 p.

Research output: Contribution to journalArticle

48 Scopus citations

Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) Complex: Evidence for an iron(IV)-oxo-hydroxo oxidant from O 2

Paria, S., Que, L. & Paine, T. K., Nov 18 2011, In : Angewandte Chemie - International Edition. 50, 47, p. 11129-11132 4 p.

Research output: Contribution to journalArticle

46 Scopus citations

Prediction of high-valent iron K-edge absorption spectra by time-dependent Density Functional Theory

Chandrasekaran, P., Stieber, S. C. E., Collins, T. J., Que, L., Neese, F. & Debeer, S., Nov 14 2011, In : Dalton Transactions. 40, 42, p. 11070-11079 10 p.

Research output: Contribution to journalArticle

68 Scopus citations

Substrate-triggered activation of a synthetic [Fe 2(μ-O) 2] diamond core for C-H bond cleavage

Xue, G., Pokutsa, A. & Que, L., Oct 19 2011, In : Journal of the American Chemical Society. 133, 41, p. 16657-16667 11 p.

Research output: Contribution to journalArticle

40 Scopus citations

Theoretical study of the mechanism of oxoiron(IV) formation from H 2O2 and a nonheme iron(II) complex: O-O cleavage involving proton-coupled electron transfer

Hirao, H., Li, F., Que, L. & Morokuma, K., Jul 18 2011, In : Inorganic Chemistry. 50, 14, p. 6637-6648 12 p.

Research output: Contribution to journalArticle

37 Scopus citations
2012

1H-ENDOR evidence for a hydrogen-bonding interaction that modulates the reactivity of a nonheme Fe IV=O unit

Shanmugam, M., Xue, G., Que, L. & Hoffman, B. M., Oct 1 2012, In : Inorganic chemistry. 51, 19, p. 10080-10082 3 p.

Research output: Contribution to journalArticle

9 Scopus citations

A mononuclear carboxylate-rich oxoiron(iv) complex: A structural and functional mimic of TauD intermediate 'J'

McDonald, A. R., Guo, Y., Vu, V. V., Bominaar, E. L., Münck, E. & Que, L., May 1 2012, In : Chemical Science. 3, 5, p. 1680-1693 14 p.

Research output: Contribution to journalArticle

32 Scopus citations

Characterization of an O 2 adduct of an active cobalt-substituted extradiol-cleaving catechol dioxygenase

Fielding, A. J., Lipscomb, J. D. & Que, L., Jan 18 2012, In : Journal of the American Chemical Society. 134, 2, p. 796-799 4 p.

Research output: Contribution to journalArticle

32 Scopus citations

Characterization of a thiolato iron(III) peroxy dianion complex

McDonald, A. R., Van Heuvelen, K. M., Guo, Y., Li, F., Bominaar, E. L., Münck, E. & Que, L., Sep 3 2012, In : Angewandte Chemie - International Edition. 51, 36, p. 9132-9136 5 p.

Research output: Contribution to journalArticle

13 Scopus citations

Editorial overview

Armstrong, F. & Que, L., Apr 1 2012, In : Current Opinion in Chemical Biology. 16, 1-2, p. 1-2 2 p.

Research output: Contribution to journalEditorial

Editorial overview

Armstrong, F. & Que, L., Apr 1 2012, In : Current opinion in chemical biology. 16, 1-2, p. 1-2 2 p.

Research output: Contribution to journalEditorial

1 Scopus citations

Evaluating the identity and diiron core transformations of a (μ-Oxo)diiron(III)complex supported by electron-rich tris(pyridyl-2-methyl) amine ligands

Do, L. H., Xue, G., Que, L. & Lippard, S. J., Feb 20 2012, In : Inorganic chemistry. 51, 4, p. 2393-2402 10 p.

Research output: Contribution to journalArticle

28 Scopus citations

Evidence for a dual role of an active site histidine in α-Amino-β-carboxymuconate-ε-semialdehyde decarboxylase

Huo, L., Fielding, A. J., Chen, Y., Li, T., Iwaki, H., Hosler, J. P., Chen, L., Hasegawa, Y., Que, L. & Liu, A., Jul 24 2012, In : Biochemistry. 51, 29, p. 5811-5821 11 p.

Research output: Contribution to journalArticle

11 Scopus citations

Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: Proximity and spin-state reactivity rules

Mas-Ballesté, R., McDonald, A. R., Reed, D., Usharani, D., Schyman, P., Milko, P., Shaik, S. & Que, L., Sep 10 2012, In : Chemistry - A European Journal. 18, 37, p. 11747-11760 14 p.

Research output: Contribution to journalArticle

13 Scopus citations

One-electron oxidation of an oxoiron(IV) complex to form an [O=Fe V=NR]+ center

Van Heuvelen, K. M., Fiedler, A. T., Shan, X., De Hont, R. F., Meier, K. K., Bominaar, E. L., Mun̈ck, E. & Que, L., Jul 24 2012, In : Proceedings of the National Academy of Sciences of the United States of America. 109, 30, p. 11933-11938 6 p.

Research output: Contribution to journalArticle

60 Scopus citations

Protonation of a peroxodiiron(III) complex and conversion to a diiron(III/IV) intermediate: Implications for proton-assisted O-O bond cleavage in nonheme diiron enzymes

Cranswick, M. A., Meier, K. K., Shan, X., Stubna, A., Kaizer, J., Mehn, M. P., Münck, E. & Que, L., Oct 1 2012, In : Inorganic Chemistry. 51, 19, p. 10417-10426 10 p.

Research output: Contribution to journalArticle

33 Scopus citations

Structural, EPR, and Mössbauer characterization of (μ-alkoxo)(μ-carboxylato)diiron(II,III) model complexes for the active sites of mixed-valent diiron enzymes

Li, F., Chakrabarti, M., Dong, Y., Kauffmann, K., Bominaar, E. L., Münck, E. & Que, L., Mar 5 2012, In : Inorganic Chemistry. 51, 5, p. 2917-2929 13 p.

Research output: Contribution to journalArticle

17 Scopus citations

π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity

Srnec, M., Wong, S. D., England, J., Que, L. & Solomon, E. I., Sep 4 2012, In : Proceedings of the National Academy of Sciences of the United States of America. 109, 36, p. 14326-14331 6 p.

Research output: Contribution to journalArticle

53 Scopus citations
2013

An iron(II)[1,3-bis(2'-pyridylimino)isoindoline] complex as a catalyst for substrate oxidation with H2O2 - Evidence for a transient peroxidodiiron(III) species

Pap, J. S., Cranswick, M. A., Balogh-Hergovich, É., Baráth, G., Giorgi, M., Rohde, G. T., Kaizer, J., Speier, G. & Que, L., Oct 31 2013, In : European Journal of Inorganic Chemistry. 22-23, p. 3858-3866 9 p.

Research output: Contribution to journalArticle

28 Scopus citations

Cyclohexene as a substrate probe for the nature of the high-valent iron-oxo oxidant in Fe(TPA)-catalyzed oxidations

Oloo, W. N., Feng, Y., Iyer, S., Parmelee, S., Xue, G. & Que, L., Nov 1 2013, In : New Journal of Chemistry. 37, 11, p. 3411-3415 5 p.

Research output: Contribution to journalArticle

22 Scopus citations

Factors affecting the carboxylate shift upon formation of nonheme diiron-O2 adducts

Frisch, J. R., McDonnell, R., Rybak-Akimova, E. V. & Que, L., Mar 11 2013, In : Inorganic chemistry. 52, 5, p. 2627-2636 10 p.

Research output: Contribution to journalArticle

10 Scopus citations

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

McDonald, A. R. & Que, L., Jan 5 2013, In : Coordination Chemistry Reviews. 257, 2, p. 414-428 15 p.

Research output: Contribution to journalReview article

296 Scopus citations

Hydrocarbon Oxidations Catalyzed by Bio-Inspired Nonheme Iron and Copper Catalysts

Oloo, W. N. & Que, L., Aug 1 2013, Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications. Elsevier Ltd, Vol. 6. p. 763-778 16 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

11 Scopus citations

Hydrogen-bonding effects on the reactivity of [X-FeIII-O-Fe IV=O] (X = OH, F) complexes toward C-H bond cleavage

Xue, G., Geng, C., Ye, S., Fiedler, A. T., Neese, F. & Que, L., Apr 1 2013, In : Inorganic chemistry. 52, 7, p. 3976-3984 9 p.

Research output: Contribution to journalArticle

23 Scopus citations

NO binding to Mn-substituted homoprotocatechuate 2,3-dioxygenase: Relationship to O2 reactivity

Hayden, J. A., Farquhar, E. R., Que, L., Lipscomb, J. D. & Hendrich, M. P., Oct 1 2013, In : Journal of Biological Inorganic Chemistry. 18, 7, p. 717-728 12 p.

Research output: Contribution to journalArticle

6 Scopus citations

Nonheme iron oxidant formed in the presence of H2O2 and acetic acid is the cyclic ferric peracetate complex, not a perferryloxo complex

Wang, Y., Janardanan, D., Usharani, D., Han, K., Que, L. & Shaik, S., Jan 1 2013, In : ACS Catalysis. 3, 6, p. 1334-1341 8 p.

Research output: Contribution to journalArticle

74 Scopus citations

Nonheme oxoiron(iv) complexes of pentadentate N5 ligands: Spectroscopy, electrochemistry, and oxidative reactivity

Wang, D., Ray, K., Collins, M. J., Farquhar, E. R., Frisch, J. R., Gómez, L., Jackson, T. A., Kerscher, M., Waleska, A., Comba, P., Costas, M. & Que, L., Mar 5 2013, In : Chemical Science. 4, 1, p. 282-291 10 p.

Research output: Contribution to journalArticle

96 Scopus citations

Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates

Park, K., Bell, C. B., Liu, L. V., Wang, D., Xue, G., Kwak, Y., Wong, S. D., Light, K. M., Zhao, J., Alp, E. E., Yoda, Y., Saito, M., Kobayashi, Y., Ohta, T., Seto, M., Que, L. & Solomon, E. I., Apr 16 2013, In : Proceedings of the National Academy of Sciences of the United States of America. 110, 16, p. 6275-6280 6 p.

Research output: Contribution to journalArticle

10 Scopus citations

Oxidation of water by a nonhaem diiron(iv) complex via proton-coupled electron transfer

Wang, D. & Que, L., Oct 22 2013, In : Chemical Communications. 49, 91, p. 10682-10684 3 p.

Research output: Contribution to journalArticle

18 Scopus citations

Rate-determining water-assisted O-O bond cleavage of an Fe III-OOH intermediate in a bio-inspired nonheme iron-catalyzed oxidation

Oloo, W. N., Fielding, A. J. & Que, L., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6438-6441 4 p.

Research output: Contribution to journalArticle

76 Scopus citations

Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate

Li, F., Van Heuvelen, K. M., Meier, K. K., Münck, E. & Que, L., Jul 17 2013, In : Journal of the American Chemical Society. 135, 28, p. 10198-10201 4 p.

Research output: Contribution to journalArticle

73 Scopus citations

The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: Bioinspired non-heme iron catalysts containing cis-labile exchangeable sites

Prat, I., Company, A., Postils, V., Ribas, X., Que, L., Luis, J. M. & Costas, M., May 17 2013, In : Chemistry - A European Journal. 19, 21, p. 6724-6738 15 p.

Research output: Contribution to journalArticle

63 Scopus citations
2014

A chameleon catalyst for nonheme iron-promoted olefin oxidation

Iyer, S. R., Javadi, M. M., Feng, Y., Hyun, M. Y., Oloo, W. N., Kim, C. & Que, L., Nov 18 2014, In : Chemical Communications. 50, 89, p. 13777-13780 4 p.

Research output: Contribution to journalArticle

19 Scopus citations

An ultra-stable oxoiron(iv) complex and its blue conjugate base

England, J., Bigelow, J. O., Van Heuvelen, K. M., Farquhar, E. R., Martinho, M., Meier, K. K., Frisch, J. R., Münck, E. & Que, L., Mar 2014, In : Chemical Science. 5, 3, p. 1204-1215 12 p.

Research output: Contribution to journalArticle

32 Scopus citations
29 Scopus citations

Characterization of a paramagnetic mononuclear nonheme iron-superoxo complex

Chiang, C. W., Kleespies, S. T., Stout, H. D., Meier, K. K., Li, P. Y., Bominaar, E. L., Que, L., Münck, E. & Lee, W. Z., Aug 6 2014, In : Journal of the American Chemical Society. 136, 31, p. 10846-10849 4 p.

Research output: Contribution to journalArticle

60 Scopus citations

Dioxygen activation by biomimetic iron complexes of α-keto acids and α-hydroxy acids

Paine, T. K. & Que, L., 2014, Molecular Design in Inorganic Biochemistry. Springer- Verlag, p. 39-56 18 p. (Structure and Bonding; vol. 160).

Research output: Chapter in Book/Report/Conference proceedingChapter

13 Scopus citations

Dioxygen Activation by Biomimetic Iron Complexes of α-Keto Acids and α-Hydroxy Acids

Paine, T. K. & Que, L., Jan 1 2014, Molecular Design in Inorganic Biochemistry. Springer Verlag, p. 39-56 18 p. (Structure and Bonding; vol. 160).

Research output: Chapter in Book/Report/Conference proceedingChapter

H2O2 activation with biomimetic non-haem iron complexes and AcOH: Connecting the g = 2.7 EPR signal with a visible chromophore

Makhlynets, O. V., Oloo, W. N., Moroz, Y. S., Belaya, I. G., Palluccio, T. D., Filatov, A. S., Müller, P., Cranswick, M. A., Que, L. & Rybak-Akimova, E. V., Jan 21 2014, In : Chemical Communications. 50, 6, p. 645-648 4 p.

Research output: Contribution to journalArticle

37 Scopus citations

Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations

Oloo, W. N., Meier, K. K., Wang, Y., Shaik, S., Münck, E. & Que, L., Jan 16 2014, In : Nature communications. 5, 3046.

Research output: Contribution to journalArticle

57 Scopus citations