6-Bromo-N-(6-bromopyridin-2-yl)-N-[4-(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)phenyl]pyridin-2-amine

Lauren A. Mitchell; Bradley J. Holliday

doi:10.1107/S1600536814013191

6-Bromo-N-(6-bromopyridin-2-yl)-N-[4-(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)phenyl]pyridin-2-amine

Lauren A. Mitchell
, Bradley J. Holliday

Research output: Contribution to journal › Article › peer-review

Abstract

In the title molecule, C₂₂H₁₅Br₂N ₃O₂S, the central benzene ring forms dihedral angles of 12.39 (17), 56.66 (17) and 74.71 (19)-, respectively, with the mean planes of the thiophene and two pyridine rings. The dioxane ring is in a halfchair conformation. An intramolecular C-H⋯O hydrogen forms an S(6) ring. The amine N atom is sp2-hybridized.

Original language	English (US)
Pages (from-to)	o797
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	7
DOIs	https://doi.org/10.1107/S1600536814013191
State	Published - Jul 2014
Externally published	Yes

Keywords

Data-to-parameter ratio = 13.0
Mean-(C-C) = 0.008 Å
R factor = 0.051
Single-crystal X-ray study
T = 100 K
WR factor = 0.128

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10.1107/S1600536814013191

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title = "6-Bromo-N-(6-bromopyridin-2-yl)-N-[4-(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)phenyl]pyridin-2-amine",

abstract = "In the title molecule, C22H15Br2N 3O2S, the central benzene ring forms dihedral angles of 12.39 (17), 56.66 (17) and 74.71 (19)-, respectively, with the mean planes of the thiophene and two pyridine rings. The dioxane ring is in a halfchair conformation. An intramolecular C-H⋯O hydrogen forms an S(6) ring. The amine N atom is sp2-hybridized.",

keywords = "Data-to-parameter ratio = 13.0, Mean-(C-C) = 0.008 {\AA}, R factor = 0.051, Single-crystal X-ray study, T = 100 K, WR factor = 0.128",

author = "Mitchell, \{Lauren A.\} and Holliday, \{Bradley J.\}",

year = "2014",

month = jul,

doi = "10.1107/S1600536814013191",

language = "English (US)",

volume = "70",

pages = "o797",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - 6-Bromo-N-(6-bromopyridin-2-yl)-N-[4-(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)phenyl]pyridin-2-amine

AU - Mitchell, Lauren A.

AU - Holliday, Bradley J.

PY - 2014/7

Y1 - 2014/7

N2 - In the title molecule, C22H15Br2N 3O2S, the central benzene ring forms dihedral angles of 12.39 (17), 56.66 (17) and 74.71 (19)-, respectively, with the mean planes of the thiophene and two pyridine rings. The dioxane ring is in a halfchair conformation. An intramolecular C-H⋯O hydrogen forms an S(6) ring. The amine N atom is sp2-hybridized.

AB - In the title molecule, C22H15Br2N 3O2S, the central benzene ring forms dihedral angles of 12.39 (17), 56.66 (17) and 74.71 (19)-, respectively, with the mean planes of the thiophene and two pyridine rings. The dioxane ring is in a halfchair conformation. An intramolecular C-H⋯O hydrogen forms an S(6) ring. The amine N atom is sp2-hybridized.

KW - Data-to-parameter ratio = 13.0

KW - Mean-(C-C) = 0.008 Å

KW - R factor = 0.051

KW - Single-crystal X-ray study

KW - T = 100 K

KW - WR factor = 0.128

UR - https://www.scopus.com/pages/publications/84904197698

UR - https://www.scopus.com/pages/publications/84904197698#tab=citedBy

U2 - 10.1107/S1600536814013191

DO - 10.1107/S1600536814013191

M3 - Article

AN - SCOPUS:84904197698

SN - 1600-5368

VL - 70

SP - o797

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

6-Bromo-N-(6-bromopyridin-2-yl)-N-[4-(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)phenyl]pyridin-2-amine

Abstract

Keywords

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