([2.2.2]Cryptand-κ6O)potassium (η4- cyclooctadiene)bis(η2-pyrene)cobaltate(1-) pentane hemisolvate

William W. Brennessel; John E. Ellis

doi:10.1107/S1600536812029078

([2.2.2]Cryptand-κ⁶O)potassium (η⁴- cyclooctadiene)bis(η²-pyrene)cobaltate(1-) pentane hemisolvate

William W. Brennessel
, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The cation, anion, and solvent in the title compound, [K(C ₁₈H₃₆N₂O₆)][Co(C₈H ₁₂)(C₁₆H₁₀)₂]·0.5C ₅H₁₂, are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the C_py/C_py-Co-C _py/C_py and the C_cod/C_cod-Co-C _cod/C_cod planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral.

Original language	English (US)
Pages (from-to)	m1013-m1014
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	7
DOIs	https://doi.org/10.1107/S1600536812029078
State	Published - Jul 2012

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10.1107/S1600536812029078

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@article{70624cf78743497f9501cda5f01d98ae,

title = "([2.2.2]Cryptand-κ6O)potassium (η4- cyclooctadiene)bis(η2-pyrene)cobaltate(1-) pentane hemisolvate",

abstract = "The cation, anion, and solvent in the title compound, [K(C 18H36N2O6)][Co(C8H 12)(C16H10)2]·0.5C 5H12, are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the Cpy/Cpy-Co-C py/Cpy and the Ccod/Ccod-Co-C cod/Ccod planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral.",

author = "Brennessel, \{William W.\} and Ellis, \{John E.\}",

year = "2012",

month = jul,

doi = "10.1107/S1600536812029078",

language = "English (US)",

volume = "68",

pages = "m1013--m1014",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

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TY - JOUR

T1 - ([2.2.2]Cryptand-κ6O)potassium (η4- cyclooctadiene)bis(η2-pyrene)cobaltate(1-) pentane hemisolvate

AU - Brennessel, William W.

AU - Ellis, John E.

PY - 2012/7

Y1 - 2012/7

N2 - The cation, anion, and solvent in the title compound, [K(C 18H36N2O6)][Co(C8H 12)(C16H10)2]·0.5C 5H12, are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the Cpy/Cpy-Co-C py/Cpy and the Ccod/Ccod-Co-C cod/Ccod planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral.

AB - The cation, anion, and solvent in the title compound, [K(C 18H36N2O6)][Co(C8H 12)(C16H10)2]·0.5C 5H12, are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the Cpy/Cpy-Co-C py/Cpy and the Ccod/Ccod-Co-C cod/Ccod planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral.

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U2 - 10.1107/S1600536812029078

DO - 10.1107/S1600536812029078

M3 - Article

C2 - 22807709

AN - SCOPUS:84863567173

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VL - 68

SP - m1013-m1014

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

([2.2.2]Cryptand-κ⁶O)potassium (η⁴- cyclooctadiene)bis(η²-pyrene)cobaltate(1-) pentane hemisolvate

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