TY - JOUR
T1 - ([2.2.2]Cryptand-κ6O)potassium (η4- cyclooctadiene)bis(η2-pyrene)cobaltate(1-) pentane hemisolvate
AU - Brennessel, William W.
AU - Ellis, John E.
PY - 2012/7
Y1 - 2012/7
N2 - The cation, anion, and solvent in the title compound, [K(C 18H36N2O6)][Co(C8H 12)(C16H10)2]·0.5C 5H12, are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the Cpy/Cpy-Co-C py/Cpy and the Ccod/Ccod-Co-C cod/Ccod planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral.
AB - The cation, anion, and solvent in the title compound, [K(C 18H36N2O6)][Co(C8H 12)(C16H10)2]·0.5C 5H12, are well separated. The pentane solvent molecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the Cpy/Cpy-Co-C py/Cpy and the Ccod/Ccod-Co-C cod/Ccod planes (py is pyrene and cod is cyclooctadiene) is 67.6 (2)°. Thus, the overall geometry of the coordination sphere around cobalt is best described as distorted tetrahedral.
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U2 - 10.1107/S1600536812029078
DO - 10.1107/S1600536812029078
M3 - Article
C2 - 22807709
AN - SCOPUS:84863567173
SN - 1600-5368
VL - 68
SP - m1013-m1014
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -