Abstract
2-Iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenol ethers and isolated as chemically stable, microcrystalline products. Single-crystal X-ray diffraction analysis of 1-iodyl-2-isopropoxybenzene 8c and 1-iodyl-2-butoxybenzene 8d revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO2 groups of different molecules. 2-Iodylphenol ethers can selectively oxidize sulfides to sulfoxides and alcohols to the respective aldehydes or ketones.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8452-8458 |
| Number of pages | 7 |
| Journal | Journal of Organic Chemistry |
| Volume | 71 |
| Issue number | 22 |
| DOIs | |
| State | Published - Oct 27 2006 |
Fingerprint Dive into the research topics of '2-Iodylphenol ethers: Preparation, X-ray crystal structure, and reactivity of new hypervalent iodine(V) oxidizing reagents'. Together they form a unique fingerprint.
Cite this
Koposov, A. Y., Karimov, R. R., Geraskin, I. M., Nemykin, V. N., & Zhdankin, V. (2006). 2-Iodylphenol ethers: Preparation, X-ray crystal structure, and reactivity of new hypervalent iodine(V) oxidizing reagents. Journal of Organic Chemistry, 71(22), 8452-8458. https://doi.org/10.1021/jo0614947