2-Iodoxybenzoic acid organosulfonates: Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

Mekhman S. Yusubov; Dmitrii Yu Svitich; Akira Yoshimura; Victor N. Nemykin; Viktor Zhdankin

doi:10.1039/c3cc47090c

2-Iodoxybenzoic acid organosulfonates: Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(_v) oxidants

Mekhman S. Yusubov, Dmitrii Yu Svitich, Akira Yoshimura, Victor N. Nemykin, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

New powerful hypervalent iodine(_v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.

Original language	English (US)
Pages (from-to)	11269-11271
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	96
DOIs	https://doi.org/10.1039/c3cc47090c
State	Published - Nov 7 2013

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abstract = "New powerful hypervalent iodine(v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.",

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T2 - Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

AU - Yusubov, Mekhman S.

AU - Svitich, Dmitrii Yu

AU - Yoshimura, Akira

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor

PY - 2013/11/7

Y1 - 2013/11/7

N2 - New powerful hypervalent iodine(v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.

AB - New powerful hypervalent iodine(v) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.

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2-Iodoxybenzoic acid organosulfonates: Preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(_v) oxidants

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