2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov, Natalia S. Soldatova, Pavel S. Postnikov, Rashid R. Valiev, Akira Yoshimura, Thomas Wirth, Victor N. Nemykin, Viktor Zhdankin

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original languageEnglish (US)
Pages (from-to)7760-7763
Number of pages4
JournalChemical Communications
Volume55
Issue number54
DOIs
StatePublished - 2019

Fingerprint Dive into the research topics of '2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant'. Together they form a unique fingerprint.

  • Cite this

    Yusubov, M. S., Soldatova, N. S., Postnikov, P. S., Valiev, R. R., Yoshimura, A., Wirth, T., Nemykin, V. N., & Zhdankin, V. (2019). 2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant. Chemical Communications, 55(54), 7760-7763. https://doi.org/10.1039/c9cc04203b