2-Iodoxybenzoic acid ditriflate

The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov, Natalia S. Soldatova, Pavel S. Postnikov, Rashid R. Valiev, Akira Yoshimura, Thomas Wirth, Victor N. Nemykin, Viktor Zhdankin

Research output: Contribution to journalArticle

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original languageEnglish (US)
Pages (from-to)7760-7763
Number of pages4
JournalChemical Communications
Volume55
Issue number54
DOIs
StatePublished - Jan 1 2019

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Iodine
Oxidants
Derivatives
Acids
X ray crystallography
Hydrocarbons
Single crystals
Oxidation
2-iodoxybenzoic acid
trifluoromethanesulfonic acid

PubMed: MeSH publication types

  • Journal Article

Cite this

Yusubov, M. S., Soldatova, N. S., Postnikov, P. S., Valiev, R. R., Yoshimura, A., Wirth, T., ... Zhdankin, V. (2019). 2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant. Chemical Communications, 55(54), 7760-7763. https://doi.org/10.1039/c9cc04203b

2-Iodoxybenzoic acid ditriflate : The most powerful hypervalent iodine(v) oxidant. / Yusubov, Mekhman S.; Soldatova, Natalia S.; Postnikov, Pavel S.; Valiev, Rashid R.; Yoshimura, Akira; Wirth, Thomas; Nemykin, Victor N.; Zhdankin, Viktor.

In: Chemical Communications, Vol. 55, No. 54, 01.01.2019, p. 7760-7763.

Research output: Contribution to journalArticle

Yusubov, MS, Soldatova, NS, Postnikov, PS, Valiev, RR, Yoshimura, A, Wirth, T, Nemykin, VN & Zhdankin, V 2019, '2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant', Chemical Communications, vol. 55, no. 54, pp. 7760-7763. https://doi.org/10.1039/c9cc04203b
Yusubov MS, Soldatova NS, Postnikov PS, Valiev RR, Yoshimura A, Wirth T et al. 2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant. Chemical Communications. 2019 Jan 1;55(54):7760-7763. https://doi.org/10.1039/c9cc04203b
Yusubov, Mekhman S. ; Soldatova, Natalia S. ; Postnikov, Pavel S. ; Valiev, Rashid R. ; Yoshimura, Akira ; Wirth, Thomas ; Nemykin, Victor N. ; Zhdankin, Viktor. / 2-Iodoxybenzoic acid ditriflate : The most powerful hypervalent iodine(v) oxidant. In: Chemical Communications. 2019 ; Vol. 55, No. 54. pp. 7760-7763.
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