2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov, Natalia S. Soldatova, Pavel S. Postnikov, Rashid R. Valiev, Akira Yoshimura, Thomas Wirth, Victor N. Nemykin, Viktor Zhdankin

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original languageEnglish (US)
Pages (from-to)7760-7763
Number of pages4
JournalChemical Communications
Volume55
Issue number54
DOIs
StatePublished - 2019

Bibliographical note

Funding Information:
This work was supported by research grants from the NSF (CHE-1759798), the Royal Society (IE160304), and the NSERC. M. S. Y. and A. Y. are also thankful to the Russian Science Foundation (RSF-16-13-10081-P).

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

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