2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant

Mekhman S. Yusubov, Natalia S. Soldatova, Pavel S. Postnikov, Rashid R. Valiev, Akira Yoshimura, Thomas Wirth, Victor N. Nemykin, Viktor Zhdankin

Research output: Contribution to journalArticle

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Original languageEnglish (US)
Pages (from-to)7760-7763
Number of pages4
JournalChemical Communications
Volume55
Issue number54
DOIs
StatePublished - Jan 1 2019

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Iodine
Oxidants
Derivatives
Acids
X ray crystallography
Hydrocarbons
Single crystals
Oxidation
2-iodoxybenzoic acid
trifluoromethanesulfonic acid

PubMed: MeSH publication types

  • Journal Article

Cite this

2-Iodoxybenzoic acid ditriflate : The most powerful hypervalent iodine(v) oxidant. / Yusubov, Mekhman S.; Soldatova, Natalia S.; Postnikov, Pavel S.; Valiev, Rashid R.; Yoshimura, Akira; Wirth, Thomas; Nemykin, Victor N.; Zhdankin, Viktor.

In: Chemical Communications, Vol. 55, No. 54, 01.01.2019, p. 7760-7763.

Research output: Contribution to journalArticle

Yusubov, MS, Soldatova, NS, Postnikov, PS, Valiev, RR, Yoshimura, A, Wirth, T, Nemykin, VN & Zhdankin, V 2019, '2-Iodoxybenzoic acid ditriflate: The most powerful hypervalent iodine(v) oxidant', Chemical Communications, vol. 55, no. 54, pp. 7760-7763. https://doi.org/10.1039/c9cc04203b
Yusubov, Mekhman S. ; Soldatova, Natalia S. ; Postnikov, Pavel S. ; Valiev, Rashid R. ; Yoshimura, Akira ; Wirth, Thomas ; Nemykin, Victor N. ; Zhdankin, Viktor. / 2-Iodoxybenzoic acid ditriflate : The most powerful hypervalent iodine(v) oxidant. In: Chemical Communications. 2019 ; Vol. 55, No. 54. pp. 7760-7763.
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