2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents

Alexey Y. Koposov, Dmitry N. Litvinov, Viktor Zhdankin

Research output: Contribution to journalArticlepeer-review

42 Scopus citations


Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

Original languageEnglish (US)
Pages (from-to)2719-2721
Number of pages3
JournalTetrahedron Letters
Issue number13
StatePublished - Mar 22 2004

Bibliographical note

Funding Information:
This work was supported by a research grant from the National Institutes of Health (R15 GM065148-01).


  • Benziodoxole
  • Hypervalent iodine
  • IBX
  • Oxidation


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