2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents

Alexey Y. Koposov, Dmitry N. Litvinov, Viktor Zhdankin

Research output: Contribution to journalArticle

37 Scopus citations

Abstract

Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

Original languageEnglish (US)
Pages (from-to)2719-2721
Number of pages3
JournalTetrahedron Letters
Volume45
Issue number13
DOIs
StatePublished - Mar 22 2004

Keywords

  • Benziodoxole
  • Hypervalent iodine
  • IBX
  • Oxidation

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