2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents

Alexey Y. Koposov; Dmitry N. Litvinov; Viktor Zhdankin

doi:10.1016/j.tetlet.2004.02.053

2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents

Alexey Y. Koposov, Dmitry N. Litvinov, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

Original language	English (US)
Pages (from-to)	2719-2721
Number of pages	3
Journal	Tetrahedron Letters
Volume	45
Issue number	13
DOIs	https://doi.org/10.1016/j.tetlet.2004.02.053
State	Published - Mar 22 2004

Bibliographical note

Funding Information:
This work was supported by a research grant from the National Institutes of Health (R15 GM065148-01).

Keywords

Benziodoxole
Hypervalent iodine
IBX
Oxidation

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10.1016/j.tetlet.2004.02.053

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title = "2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents",

abstract = "Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.",

keywords = "Benziodoxole, Hypervalent iodine, IBX, Oxidation",

author = "Koposov, {Alexey Y.} and Litvinov, {Dmitry N.} and Viktor Zhdankin",

note = "Funding Information: This work was supported by a research grant from the National Institutes of Health (R15 GM065148-01). ",

year = "2004",

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doi = "10.1016/j.tetlet.2004.02.053",

language = "English (US)",

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TY - JOUR

T1 - 2-Iodoxybenzenesulfamides

T2 - New pseudobenziodoxole-based hypervalent iodine reagents

AU - Koposov, Alexey Y.

AU - Litvinov, Dmitry N.

AU - Zhdankin, Viktor

N1 - Funding Information: This work was supported by a research grant from the National Institutes of Health (R15 GM065148-01).

PY - 2004/3/22

Y1 - 2004/3/22

N2 - Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

AB - Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

KW - Benziodoxole

KW - Hypervalent iodine

KW - IBX

KW - Oxidation

UR - http://www.scopus.com/inward/record.url?scp=1542358711&partnerID=8YFLogxK

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DO - 10.1016/j.tetlet.2004.02.053

M3 - Article

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VL - 45

SP - 2719

EP - 2721

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 13

ER -

2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents

Abstract

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Keywords

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