2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents

Alexey Y. Koposov; Dmitry N. Litvinov; Viktor Zhdankin

doi:10.1016/j.tetlet.2004.02.053

2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents

Alexey Y. Koposov, Dmitry N. Litvinov, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article

37 Scopus citations

Abstract

Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

Original language	English (US)
Pages (from-to)	2719-2721
Number of pages	3
Journal	Tetrahedron Letters
Volume	45
Issue number	13
DOIs	https://doi.org/10.1016/j.tetlet.2004.02.053
State	Published - Mar 22 2004

Keywords

Benziodoxole
Hypervalent iodine
IBX
Oxidation

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title = "2-Iodoxybenzenesulfamides: New pseudobenziodoxole-based hypervalent iodine reagents",

abstract = "Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.",

keywords = "Benziodoxole, Hypervalent iodine, IBX, Oxidation",

author = "Koposov, {Alexey Y.} and Litvinov, {Dmitry N.} and Viktor Zhdankin",

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T1 - 2-Iodoxybenzenesulfamides

T2 - New pseudobenziodoxole-based hypervalent iodine reagents

AU - Koposov, Alexey Y.

AU - Litvinov, Dmitry N.

AU - Zhdankin, Viktor

PY - 2004/3/22

Y1 - 2004/3/22

N2 - Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

AB - Amides of 2-iodoxybenzenesulfonic acid were prepared by the dioxirane oxidation of the corresponding 2-iodobenzenesulfamides and isolated as stable, microcrystalline products. These new representatives of the pseudocyclic hypervalent iodine compounds can selectively oxidize benzyl alcohols to aldehydes.

KW - Benziodoxole

KW - Hypervalent iodine

KW - IBX

KW - Oxidation

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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