1,4-Dimethyl-1,4-diazoniabicyclo-[2.2.2]octane diiodide acetonitrile solvate

Daron E. Janzen; Paul C. Ewbank; Kent R. Mann

doi:10.1107/S0108270105028763

1,4-Dimethyl-1,4-diazoniabicyclo-[2.2.2]octane diiodide acetonitrile solvate

Daron E. Janzen
, Paul C. Ewbank
, Kent R. Mann

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In the crystal structure of the title compound, C₈H ₁₈N₂^2-+ 2I^-·CH₃CN, the dication lies on a mirror plane containing the molecular dication threefold axis. The structure displays C-H⋯I interactions between H atoms of the 1,4-dimethyl-1,4-diazoniabicyclo[2.2.2]octane dication and the iodide anions. The H⋯I distances are in the range 2.96-3.18 (4) A. The dications pack forming channels along the b axis, which contain the iodide anions and acetonitrile solvent molecules.

Original language	English (US)
Pages (from-to)	o631-o633
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	61
Issue number	11
DOIs	https://doi.org/10.1107/S0108270105028763
State	Published - Nov 2005

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@article{59a08f16d04f4209881f1bdcf28a1849,

title = "1,4-Dimethyl-1,4-diazoniabicyclo-[2.2.2]octane diiodide acetonitrile solvate",

abstract = "In the crystal structure of the title compound, C8H 18N22-+ 2I-·CH3CN, the dication lies on a mirror plane containing the molecular dication threefold axis. The structure displays C-H⋯I interactions between H atoms of the 1,4-dimethyl-1,4-diazoniabicyclo[2.2.2]octane dication and the iodide anions. The H⋯I distances are in the range 2.96-3.18 (4) A. The dications pack forming channels along the b axis, which contain the iodide anions and acetonitrile solvent molecules.",

author = "Janzen, \{Daron E.\} and Ewbank, \{Paul C.\} and Mann, \{Kent R.\}",

year = "2005",

month = nov,

doi = "10.1107/S0108270105028763",

language = "English (US)",

volume = "61",

pages = "o631--o633",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

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TY - JOUR

T1 - 1,4-Dimethyl-1,4-diazoniabicyclo-[2.2.2]octane diiodide acetonitrile solvate

AU - Janzen, Daron E.

AU - Ewbank, Paul C.

AU - Mann, Kent R.

PY - 2005/11

Y1 - 2005/11

N2 - In the crystal structure of the title compound, C8H 18N22-+ 2I-·CH3CN, the dication lies on a mirror plane containing the molecular dication threefold axis. The structure displays C-H⋯I interactions between H atoms of the 1,4-dimethyl-1,4-diazoniabicyclo[2.2.2]octane dication and the iodide anions. The H⋯I distances are in the range 2.96-3.18 (4) A. The dications pack forming channels along the b axis, which contain the iodide anions and acetonitrile solvent molecules.

AB - In the crystal structure of the title compound, C8H 18N22-+ 2I-·CH3CN, the dication lies on a mirror plane containing the molecular dication threefold axis. The structure displays C-H⋯I interactions between H atoms of the 1,4-dimethyl-1,4-diazoniabicyclo[2.2.2]octane dication and the iodide anions. The H⋯I distances are in the range 2.96-3.18 (4) A. The dications pack forming channels along the b axis, which contain the iodide anions and acetonitrile solvent molecules.

UR - https://www.scopus.com/pages/publications/30744475989

UR - https://www.scopus.com/pages/publications/30744475989#tab=citedBy

U2 - 10.1107/S0108270105028763

DO - 10.1107/S0108270105028763

M3 - Article

C2 - 16272595

AN - SCOPUS:30744475989

SN - 0108-2701

VL - 61

SP - o631-o633

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

1,4-Dimethyl-1,4-diazoniabicyclo-[2.2.2]octane diiodide acetonitrile solvate

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